Journal
MATERIALS RESEARCH BULLETIN
Volume 83, Issue -, Pages 474-480Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2016.06.037
Keywords
Batteries; Energy storage; Nanostructures; Electrochemical properties; Thin films
Categories
Funding
- National Natural Science Foundation of China [51502263]
- Fundamental Research Funds for the Central Universities [2015XZZX010-02]
- Program for Innovative Research Team in University of Ministry of Education of China [IRT13037]
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Sulfur is an attractive active material for lithium batteries in terms of its high specific capacity and energy density. Despite main advantages, lithium sulfur (Li-S) batteries still suffer from great challenges with serious capacity decay and awful rate performance due to severe shuttle effect and mass loss of active materials. Herein we report a free-standing carbon-sulfur cathodes by anchoring sulfur into 3D carbon nanorods arrays. Binder-free and integrated characteristics are realized. Sulfur infuses into interspaces among arrays and trapped by the interconnected carbon arrays. The assembled cells exhibit initial discharge specific capacity of 1050 mAh g(-1) at 0.2 C and 892 mAh g(-1) at 2.0 C, companied by an outstanding coulombic efficiency of 98% after 200 cycles at 0.2 C. The obtained S-C cathode also shows excellent rate capacity with low capacity fade. The proposed new S-C architecture may pave the way toward construction of novel S-Li batteries. (C) 2016 Elsevier Ltd. All rights reserved.
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