Journal
CHEMICAL & PHARMACEUTICAL BULLETIN
Volume 63, Issue 9, Pages 649-662Publisher
PHARMACEUTICAL SOC JAPAN
DOI: 10.1248/cpb.c15-00487
Keywords
Bronsted acid; acidity; carbanion; catalyst; triflyl group
Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Japan Society for the Promotion of Science
- Mitsubishi Gas Chemical Co., Ltd.
- Asahi Glass Foundation
- Kurata Memorial Hitachi Science and Technology Foundation
- Hoansha Foundation
- Grants-in-Aid for Scientific Research [26105755] Funding Source: KAKEN
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The bisktrifluoromethyl)sulfonyllmethyl (Tf2CH; Tf=SO2CF3) group is known to be one of the strongest carbon acid functionalities. The acidity of such carbon acids in the gas phase is stronger than that of sulfuric acid. Our recent investigations have demonstrated that this type of carbon acids work as novel acid catalysts. In this paper, recent achievements in carbon acid chemistry by our research group, including synthesis, physicochemical properties, and catalysis, are summarized.
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