Journal
MATERIALS FOR RENEWABLE AND SUSTAINABLE ENERGY
Volume -, Issue -, Pages -Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s40243-023-00232-9
Keywords
Doped; H-2; a-SiH; N-type; PECVD; Electronic structure
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In this study, we investigated the effect of hydrogen doping on the electronic correlation and power conversion output of solar cells. N-type a-Si:H thin films were grown with various H2-doping levels, and their characteristics were analyzed. The addition of doped-H-2 showed a decrease in optical conductivity and a significant increase in the energy gap of the thin layer. The bond structure also changed from amorphous to nanocrystalline structures. Overall, our findings suggest that H-2 doping can modify the electronic structure and potentially increase the power conversion output of solar cells.
In this work, we report that hydrogen (H-2) doped in n-type a-Si:H thin films strongly influences the electronic correlation in increasing the conversion output power of solar cells. Type n a-Si:H thin films were grown using PECVD on ITO substrates with various H2-doping, to obtain various thin films for solar-cell applications. N-type a-Si:H thin films were prepared, and then characterized using ellipsometric spectroscopy, atomic force microscopy, Fourier transform infrared spectroscopy, and transmission electron microscopy. The addition of doped-H-2 to the thin layer shows a decrease in optical conductivity, while the energy gap in the thin layer shows a significant increase in the a-Si:H-type thin layer. Our results show that H-2 doping plays a very important role in the electronic structure, which is indicated by the significant energy gap difference. On the other hand, the bond structure of each H2-doped thin film showed a change from amorphous to nanocrystalline structures which were evenly distributed in each H-2-doped bonding. Overall, we believe that the addition of doped-H-2 to our findings could help increase the power conversion output of the solar cell due to the modification of the electronic structure.
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