Journal
MATERIALIA
Volume 28, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.mtla.2023.101758
Keywords
Transition metal Al nitrides; ZrAlN7TiN multilayers; Nanocomposites; Wide angle X-ray scattering
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Metastable super-saturated Zr1_xAlxN alloys tend to phase separate into the equilibrium cubic (c) ZrN and wurtzite (w) AlN. Different transformation paths were observed depending on the deposition method and post-deposition annealing. The surface segregation effects and secondary phase transformations were studied using in situ high-energy synchrotron wide-angle X-ray scattering and analytical transmission electron microscopy. The results showed the formation of AlN-ZrN labyrinthine structure and the inhibition of c-AlN formation during transformation.
Metastable super-saturated Zr1_xAlxN alloys tend to phase separate into the equilibrium cubic (c) ZrN and wurtzite (w) AlN due to a deep miscibility gap. Transformation is shown here to follow distinctly different paths depending on if Zr1_xAlxN (x = 0.3 and 0.6) is sputter deposited as a single layer or multi-layered with TiN, and further varied by post-deposition annealing. Using in situ high-energy synchrotron wide-angle X-ray scattering and analytical transmission electron microscopy, surface segregation effects are compared to secondary phase transformations occurring in as-deposited layers during thermal annealing up to 1000 degrees C. For the primary phase transformation from the vapor phase, w-AlN nucleates and an AlN-ZrN labyrinthine structure evolves at elevated deposition temperature with semi-coherent interfaces over several nanometers, where the higher Al content narrows the structure in both single and multilayers. Transformation in thinner alloy layers is governed by epitaxial forces which stabilize single-phase c-Zr0.4Al0.6N, which enables c-Zr0.4Al0.6N/TiN superlattice growth at temperatures as low as 350 degrees C. Regardless of the decomposition route, the formation of c-AlN is impeded and w-AlN instantaneously forms during transformation. In contrast, isostructural decomposition into w-AlN and w-Zr (Al)N occurs in w-Zr0.4Al0.6N alloys during annealing.
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