Journal
MACROMOLECULES
Volume 49, Issue 6, Pages 2224-2227Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.6b00214
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Funding
- Spanish Research Council (CSIC)
- European Social Fund (ESF) through JAE-doc program
- [MAT 2013-42957-R]
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A synthetic approach for the preparation and linkage of functionalized plasticizer molecules to PVC is described. The synthesis of this four-step procedure is economically and ecologically viable because it is based on trichlorotriazine as inexpensive starting material; the reactions can be carried out one-pot with quantitative yields and without need of final purification of the products. The approach is furthermore highly versatile and allows for the preparation of a large number of different plasticizers with properties that may be adjusted to a broad range of applications from highly flexible to semirigid.
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