Journal
MACROMOLECULES
Volume 49, Issue 20, Pages 7709-7717Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.6b01997
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Funding
- Fundamental Research Funds for the Central Nonprofit Research Institution of CAF [CAFYBB2016ZD007]
- National Natural Science Foundation of China [31570579]
- China Scholarship Council [201503270022]
- National Science Foundation [DMR-1252611]
- University of South Carolina Provost Visiting Scholars Program
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1252611] Funding Source: National Science Foundation
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Well-defined polymers derived from biomass feedstock (e.g., soybean oil, rosin acid, and furfural) were successfully prepared by metal-free atom transfer radical polymerization (ATRP). In the presence of photoredox catalysts and UV irradiation, three biomass-based methacrylate monomers were efficiently polymerized with good control over molecular weight and dispersity. NMR. and MALDI-TOF MS confirmed high fidelity of chain end groups originated from initiators. Furthermore, block copolymers from these monomers were also achieved through chain extension by metal-free ATRP.
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