Journal
MACROMOLECULAR REACTION ENGINEERING
Volume 10, Issue 3, Pages 156-179Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mren.201500053
Keywords
chain structure control; late transition metal catalyst; long-chain branching; metallocene catalyst; polyolefin
Categories
Funding
- National Natural Science Foundation of China [21536011, 21420102008, U1462115, 21376211]
- Program for Changjiang Scholars and Innovative Research Team in University in China [IRT0942]
- Chinese State Key Laboratory of Chemical Engineering at Zhejiang University [SKL-ChE-12T05, SKL-ChE-14D01]
- Natural Science and Engineering Research Council (NSERC) of Canada
- Ministry of Education
- 985 Project innovative talent training program at Zhejiang University
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Polyolefins (POs) are the largest polymer product in the world. The innovation in converting commodity olefin monomers to highly value added high-performance POs has been and will continue to be a major theme in both academic research and industry practice. The excellent properties of POs can be achieved through precise engineering of their chain architectures, which largely involves control of the chain branching structures. Long-chain branching is one of the most important parameters in the aspect of various chain branching structures. A huge amount of literatures have been reported to achieve better control of long-chain branched structures over the last two decades. Recently, good effort has been made in reviewing all the major literatures and summarizing the catalytic systems and synthetic strategies for the controlled synthesis of long-chain branched POs. This paper represents the first of the series, that is, controlled synthesis of long-chain branched POs via single catalyst systems.
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