Journal
JOURNAL OF POLYMER SCIENCE
Volume 61, Issue 17, Pages 1995-2001Publisher
WILEY
DOI: 10.1002/pol.20230125
Keywords
polyallenes; structure-property relationships; sustainability; terpenoids
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Synthesizing soft polymers with uncommon structural elements is important for understanding their properties. Terpenoid materials, which have diverse structural groups, could enhance our knowledge of related petrochemically-derived polymers. The behavior of norbornene-based systems in copolymers is well-understood, but it is unclear how other rigid carbocycles behave. Terpenoid polymers with pinene-based comonomers were synthesized and characterized, and it was found that the pinane core promotes ideal behavior similar to norbornene-based systems in statistical copolymers. Block copolymers exhibited tunable thermomechanical properties correlated to the carbocycle composition.
Synthesizing soft polymers with uncommon architectural elements is critical for enhancing our understanding of fundamental structure-property relationships in macromolecules. Terpenoid materials are interesting candidates for addressing this grand challenge, as their constituent monomers can exhibit a diverse array of structural and functional groups. Moreover, these biologically-derived materials can potentially expand the sphere of knowledge surrounding trends in related petrochemically-derived polymers. For example, vinyl-addition copolymers of norbornene and acyclic olefins can exhibit predictable properties (e.g., linear changes in T-g as a function of composition). Due to synthetic limitations, however, it is not well understood if other rigid carbocycles engender similar behavior in a range of copolymers. As numerous terpene scaffolds display rigid motifs (such as pinane systems), terpenoid polymers are uniquely positioned to address this deficiency. Here, we report the synthesis and characterization of terpenoid copolymers (both statistical and block) with systematically tailored compositions of pinene-based comonomers. We found that the pinane core (which is a constitutional isomer of norbornene) appears to promote ideal behavior with regard to bulk thermal properties of statistical copolymers, which mirrors the behavior of norbornene-based systems. We also found that block copolymers exhibited thermomechanical properties that were highly tunable (and apparently correlated to carbocycle composition).
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