☆ 4.7 Article

Optimal Interfacial Model between the Alloy Surface and Electrolyte Solvation Structure for a Stable Lithium Metal Electrode

ACS APPLIED ENERGY MATERIALS (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries

Zunchun Wu et al.

Summary: This study found that the coordination between Li+ and solvents determines the anodic stability of localized high-concentrated electrolytes (LHCEs) on high-voltage cathodes, which can be finely tuned by ambient diluents. Among the possible diluents, 2H,3H-decafluoropentane (HFC) was found to satisfy the principle of weak but sufficient interactions, which enhances Li+ coordination and offers excellent antioxidant chemistry. The study provides guiding principles for improving the cathodic and anodic stability of electrolytes, benefiting the development of LHCEs and inspiring next-generation lithium batteries formulation.

CHEM (2023)

Add to Collection

Article Chemistry, Multidisciplinary

Interfacial and Interphasial Chemistry of Electrolyte Components to Invoke High-Performance Antimony Anodes and Non-Flammable Lithium-Ion Batteries

Qujiang Sun et al.

Summary: This study thoroughly investigates the functions of electrolyte components in lithium-ion batteries, sheds light on their roles at the molecular scale, and successfully develops a new non-flammable electrolyte.

ADVANCED FUNCTIONAL MATERIALS (2023)

Add to Collection

Article Nanoscience & Nanotechnology

Solvent-Diluent Interaction-Mediated Solvation Structure of Localized High-Concentration Electrolytes

Feihong Ren et al.

Summary: The latest developments in localized high-concentration electrolytes offer insights into stabilizing high-energy-density lithium metal batteries. The amount of diluent has an unexpected effect on the solvation structures of the electrolytes, and a moderately diluted localized high-concentration electrolyte shows the best Coulombic efficiency.

ACS APPLIED MATERIALS & INTERFACES (2022)

Add to Collection

Article Engineering, Chemical

Thermal safety of dendritic lithium against non-aqueous electrolyte in pouch-type lithium metal batteries

Feng-Ni Jiang et al.

Journal of Energy Chemistry (2022)

Add to Collection

Article Chemistry, Multidisciplinary

One-Dimensional Porous Li-Confinable Hosts for High-Rate and Stable Li-Metal Batteries

Dong Woo Kang et al.

Summary: In this study, a one-dimensional porous Li-confinable host with lithiophilic Au (Au@PHCF) is proposed, which can suppress Li top plating, improve Li stripping/plating efficiency, and enhance electrochemical performance. The structural design of the Li-confinable host is crucial for stable operation of promising Li-metal batteries at a practical test level.

ACS NANO (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Stabilizing Lithiophilic Sites Via Bimetallic Oxide Heterointerfaces

Jinting Xu et al.

Summary: Designing metal oxide hosts with multiple lithophilic sites is a promising strategy for stabilizing lithium metal anodes in lithium metal batteries. A heterointerfacing strategy is proposed to stabilize the alloy-type lithiophilic sites of zinc, achieving high coulombic efficiency and long-term stability in practical applications.

ADVANCED MATERIALS INTERFACES (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Thermally Stable Polymer-Rich Solid Electrolyte Interphase for Safe Lithium Metal Pouch Cells

Shi-Jie Yang et al.

Summary: By forming a polymer-rich solid electrolyte interphase on the lithium anode of lithium metal batteries, the safety of the batteries can be improved, reducing the reaction between the electrolyte and the anode/cathode. This results in higher thermal stability and a higher starting temperature for the batteries.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Localized Hydrophobicity in Aqueous Zinc Electrolytes Improves Zinc Metal Reversibility

Peichao Zou et al.

Summary: In this study, a new solution structure of aqueous electrolyte was reported, which achieved a hydrophobic anode-electrolyte interface by adding a suitable diluent, and reduced passivation layer formation through the hydroxyl-ion-scavenging functionality, improving the reversibility and lifetime of zinc metal batteries.

NANO LETTERS (2022)

Add to Collection

Article Chemistry, Physical

Dipole-Dipole Interaction Induced Electrolyte Interfacial Model To Stabilize Antimony Anode for High-Safety Lithium-Ion Batteries

Qujiang Sun et al.

Summary: This study reveals the mechanism of solvent molecular interaction on battery performance, designs a new electrolyte to stabilize alloying anodes, and demonstrates the impact of different solvation structures on electrochemical properties, achieving superior battery performances.

ACS ENERGY LETTERS (2022)

Add to Collection

Article Energy & Fuels

Constructing stable lithium metal anodes using a lithium adsorbent with a high Mn3+/Mn4+ ratio

Yue Zhao et al.

Summary: This study presents a novel approach for constructing highly stable lithium metal anodes for LMBs using a protonated Li manganese oxide as a lithium adsorbent. The adsorbent not only provides an ultralow lithium nucleation overpotential but also improves lithium transfer kinetics, resulting in dendrite-free and stable lithium metal anodes with improved electrochemical performance. The findings demonstrate the potential for safe and long-lasting LMBs.

ENERGY MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Dendrite-accelerated thermal runaway mechanisms of lithium metal pouch batteries

Xiang-Qun Xu et al.

Summary: This study quantitatively investigates the thermal runaway behaviors of a lithium metal pouch cell throughout its life cycle, and discovers that suppressing dendrite growth and reducing the reactivity between the lithium metal anode and electrolyte at high temperature are effective strategies to enhance the safety performance of lithium metal batteries.

SUSMAT (2022)

Add to Collection

Article Materials Science, Multidisciplinary

Discerning Roles of Interfacial Model and Solid Electrolyte Interphase Layer for Stabilizing Antimony Anode in Lithium-Ion Batteries

Qujiang Sun et al.

Summary: Electrolyte solvation chemistry plays a crucial role in the performance of metal-ion batteries. This study designs a new electrolyte and unravels the effects of solvation chemistry and the solid electrolyte interphase (SEI) on electrode performances. The results show that both the solvation structure-derived interfacial model and the SEI layer are necessary to stabilize the electrode, and a high-performance antimony (Sb) anode for lithium-ion batteries is achieved.

ACS MATERIALS LETTERS (2022)

Add to Collection

Article Chemistry, Physical

Unveiling the Origin of Alloy-Seeded and Nondendritic Growth of Zn for Rechargeable Aqueous Zn Batteries

Yamin Zhang et al.

Summary: Rechargeable aqueous zinc anodes are attracting attention for their safety, low cost, and high theoretical volumetric capacity. Zinc anodes in aqueous electrolytes often suffer from dendritic metal deposition, with the regulation of Zn using Zn-alloying metals as a reported solution. By introducing Ag on Zn anodes, uniform Zn deposition was achieved, leading to improved cycling performance. This alloy-seeding design principle could potentially enhance the rechargeability of other metal anodes.

ACS ENERGY LETTERS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

An artificial hybrid interphase for an ultrahigh-rate and practical lithium metal anode

Anjun Hu et al.

Summary: An artificial hybrid SEI layer composed of lithium-antimony alloy and lithium fluoride was constructed to reduce electron tunneling between the Li anode and SEI, resulting in uniform Li deposition and stable Li plating/stripping behaviors at an ultrahigh rate. This work uncovers the internal mechanism of Li+ transport within the SEI component, providing a pathway to stabilize the Li anode under practical high-rate conditions.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Add to Collection

Article Chemistry, Physical

A Framework with Enriched Fluorinated Sites for Stable Li Metal Cycling

Muqin Wang et al.

Summary: In this study, the authors demonstrate the effect of a three-dimensional (3D) framework with enriched fluorinated sites for Li metal protection to improve the performance of Li metal anodes. Stable Li plating/stripping and improved full cell performance are achieved through this optimized interfacial design, showing new insights into protecting Li metal anodes in high-energy-density batteries.

ACTA PHYSICO-CHIMICA SINICA (2021)

Add to Collection

Article Chemistry, Physical

Countersolvent Electrolytes for Lithium-Metal Batteries

Nan Piao et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Article Chemistry, Physical

Electrolyte Engineering Enables High Stability and Capacity Alloying Anodes for Sodium and Potassium Ion Batteries

Lin Zhou et al.

ACS ENERGY LETTERS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Solid-Solution-Based Metal Alloy Phase for Highly Reversible Lithium Metal Anode

Song Jin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Physical

Dendrite-free lithium metal anode with lithiophilic interphase from hierarchical frameworks by tuned nucleation

Zheng Luo et al.

ENERGY STORAGE MATERIALS (2020)

Add to Collection

Article Multidisciplinary Sciences

Role of inner solvation sheath within salt-solvent complexes in tailoring electrode/electrolyte interphases for lithium metal batteries

Xiaodi Ren et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2020)

Add to Collection

Article Multidisciplinary Sciences

Immunizing lithium metal anodes against dendrite growth using protein molecules to achieve high energy batteries

Tianyi Wang et al.

NATURE COMMUNICATIONS (2020)

Add to Collection

Article Chemistry, Physical

Lithiophilic 3D Porous CuZn Current Collector for Stable Lithium Metal Batteries

Duo Zhang et al.

ACS ENERGY LETTERS (2020)

Add to Collection

Review Chemistry, Physical

Scientific Challenges for the Implementation of Zn-Ion Batteries

Lauren E. Blanc et al.

JOULE (2020)

Add to Collection

Article Chemistry, Physical

The Thermal Stability of Lithium Solid Electrolytes with Metallic Lithium

Rusong Chen et al.

JOULE (2020)

Add to Collection

Article Chemistry, Physical

Enhanced Stability of Li Metal Anodes by Synergetic Control of Nucleation and the Solid Electrolyte Interphase

Zhe Peng et al.

ADVANCED ENERGY MATERIALS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Chemical Energy Release Driven Lithiophilic Layer on 1 m2 Commercial Brass Mesh toward Highly Stable Lithium Metal Batteries

Shaobo Huang et al.

NANO LETTERS (2019)

Add to Collection

Article Chemistry, Physical

Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions

Xiaodi Ren et al.

JOULE (2019)

Add to Collection

Article Chemistry, Multidisciplinary

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes

Shuru Chen et al.

ADVANCED MATERIALS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Uniform Lithium Nucleation/Growth Induced by Lightweight Nitrogen-Doped Graphitic Carbon Foams for High-Performance Lithium Metal Anodes

Lin Liu et al.

ADVANCED MATERIALS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Before Li Ion Batteries

Martin Winter et al.

CHEMICAL REVIEWS (2018)

Add to Collection

Review Nanoscience & Nanotechnology

Reviving the lithium metal anode for high-energy batteries

Dingchang Lin et al.

NATURE NANOTECHNOLOGY (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

3D Porous Cu Current Collector/Li-Metal Composite Anode for Stable Lithium-Metal Batteries

Qi Li et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

Add to Collection

Article Nanoscience & Nanotechnology

Li2O-Reinforced Cu Nanoclusters as Porous Structure for Dendrite-Free and Long-Lifespan Lithium Metal Anode

Zhenggang Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Add to Collection

Article Chemistry, Physical

Volumetric variation confinement: surface protective structure for high cyclic stability of lithium metal electrodes

Zhe Peng et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

Add to Collection

Article Energy & Fuels

Reversible aqueous zinc/manganese oxide energy storage from conversion reactions

Huilin Pan et al.

NATURE ENERGY (2016)

Add to Collection

Article Chemistry, Physical

In Situ Formation of Protective Coatings on Sulfur Cathodes in Lithium Batteries with LiFSI-Based Organic Electrolytes

Hyea Kim et al.

ADVANCED ENERGY MATERIALS (2015)

Add to Collection

Article Materials Science, Ceramics

Self-Diffusion in Solid Lithium

E. Dologlou

GLASS PHYSICS AND CHEMISTRY (2010)

Add to Collection

© Peeref 2019-2024. All rights reserved.