4.7 Review

Light Soaking Effects in Perovskite Solar Cells: Mechanism, Impacts, and Elimination

Journal

ACS APPLIED ENERGY MATERIALS
Volume -, Issue -, Pages -

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsaem.2c04120

Keywords

light-soaking effects; perovskite solar cells; mechanism; elimination; stability

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Perovskite solar cells (PSCs) have potential for photovoltaic applications due to their simple fabrication process, low material cost, and high power conversion efficiencies. However, the instability and poor reliability of PSCs, particularly the light-soaking effect (LSE), hinder their practical use. This review explores the transient behaviors and physical mechanisms behind the LSE, as well as effective approaches to mitigate or eliminate this effect. The study provides insights into the LSE physics and guidance for improving the photostability of PSCs.
Perovskites solar cells (PSCs) have been recognized as one of the most prospective photovoltaic technologies for their combined properties of simple fabrication process, low material cost, and remarkable power conversion efficiencies of over 25%. However, the instability and poor reliability of PSCs remain the major obstacles to their practical applications. Specifically, light-soaking effect (LSE), which refers to the fluctuations of photovoltaic parameters under light exposure, represents a critical factor limiting the accuracy and stability of device power output. However, great challenges still remain in understanding and modulating the LSE in PSCs. In this review, we discuss different transient behaviors associated with LSE, and summarize various physical mechanisms (such as light-induced ions migration, trap defect passivation, lattice expansion, and charge carrier accumulation) behind the LSE together with their impacts to the device performance. Moreover, we systematically review the recent advances in developing effective approaches and strategies to mitigate or eliminate the LSE in PSCs, including interfacial modification, material doping, and surface passivation. Finally, a perspective and outlook toward LSE-free PSCs are further provided. This review offers a deeper opinion of the LSE physics with further guidance on ways to optimize the photostability of PSCs.

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