4.7 Article

Graphene oxide embedded polyvinylidene fluoride nanofiber membranes with biomimetic polar adsorption function for mask cartridge materials

Journal

COMPOSITES COMMUNICATIONS
Volume 40, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.coco.2023.101627

Keywords

Graphene oxide; Polyvinylidene fluoride; Polydopamine; Air filtration

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A study found that growing biomimetic polydopamine (PDA) flakes on nanofibers is an effective way to develop high-efficiency mask filters for daily protection against influenza viruses and airborne particulate matter (PM). The functionalized nanofiber membranes, embedded with graphene oxide (GO) nanosheets, demonstrated high removal efficiency, low air resistance, and good filtration performance even after 72 hours of wear.
Face masks have become an effective tool for daily protection against the spread of influenza viruses and issues with airborne particulate matter (PM). However, developing a functional filter material with consistent intercepting performance to instead existing commercial cartridge materials for masks is still a challenge. In this work, biomimetic polar adsorption polydopamine (PDA) flakes were grown on polyvinylidene fluoride (PVDF) nanofibers embedded with graphene oxide (GO) nanosheets through blending-electrospinning and surface in situ polymerization method for high-efficiency mask filters. Embedding GO and growing PDA significantly decreased the water contact angle from 141.6 degrees to 56.7 degrees and increased tensile strength from 1.99 MPa to 6.30 MPa. Moreover, the functionalized nanofiber membranes exhibited a high removal efficiency (PM0.3-99.37%), a low air resistance (56 Pa), and keep 98.52% interception for PM0.3 after de-static treatment. Notably, it retained more than 92.00% (PM0.3) of its filtration performance after 72 h of wear. Thus, this work reveals that growing PDA flakes on nanofibers is a practical functionalization technique for high-efficiency mask filters.

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