Understanding the effect of MXene in a TMO/MXene hybrid catalyst for the oxygen evolution reaction

Very recently, it has been reported that mixed transition metal oxide (TMO)/MXene catalysts show improved performance over TMO only catalysts for the oxygen evolution reaction (OER). However, the reasoning behind this observation is unknown. In this work mixed Co(OH)(2)/Ti3C2Tx were prepared and characterized for the OER using ex situ and operando spectroscopy techniques in order to initiate the understanding of why mixed TMO/MXene materials show better performances compared to TMO only catalysts. This work shows that the improved electrocatalysis for the composite material compared to the TMO only catalyst is due to the presence of higher Co oxide oxidation states at lower OER overpotentials for the mixed TMO/MXene catalysts. Furthermore, the presence of the MXene allows for a more mechanically robust film during OER, making the film more stable. Finally, our results show that small amounts of MXene are more advantageous for the OER during long-term stability measurements, which is linked to the formation of TiO2. The sensitivity of MXene oxidation ultimately limits TMO/MXene composites under alkaline OER conditions, meaning mass fractions must be carefully considered when designing such a catalyst to minimize the residual TiO2 formed during its lifetime.

Automated summary

Recently, it has been found that mixed transition metal oxide (TMO)/MXene catalysts exhibit better performance in the oxygen evolution reaction (OER) compared to TMO only catalysts. This study investigates the reasons behind this improvement by preparing and characterizing mixed Co(OH)(2)/Ti3C2Tx catalysts for the OER. The results show that the improved electrocatalysis in the composite material is attributed to the presence of higher Co oxide oxidation states and the mechanical stability provided by MXene.