Correlations between unconfined compressive strength, sorptivity and pore structures for geopolymer based on SEM and MIP measurements

The objective for this research was to investigated the unconfined compressive strength, sorptivity, pore structures and their correlations of recycled concrete fine powder (RCFP) based geopolymers mixed with different granulated blast furnace slag (GBFS). The unconfined compressive strength and sorptivity tests were utilized to measure the unconfined compressive strength and sorptivity coefficient. The pore structures were analyzed using optical method (SEM) and mercury intrusion method (MIP). The particles (pores) and cracks analysis system (PCAS) and image-pro plus (IPP) software were employed to quantitatively characterize the multi-scale micropores in the SEM images. Furthermore, based on MIP measurement and two fractal theories, the variations in pore structural characteristics were evaluated. The findings demonstrate the incorporation of GBFS effectively reduced the sorptivity coefficient and enhanced the unconfined compressive strength, and this effect grew stronger with increasing content of GBFS. The sorptivity coefficient and 28-day unconfined compressive strength had a strong linear negative connection. According to SEM analysis, increasing GBFS facilitated the generation of that greater number of gelling products by improving the degree of reaction, which led to a refinement of internal pore structure and an increase in structural complexity. Meanwhile, the addition of GBFS and increasing its content could effectively facilitate the conversion of macropores into micropores by filling with gel products, and significantly reduce the porosity, threshold pore size and most probable pore size. The unconfined compressive strength and sorptivity coefficient had good linear relationships with its internal porosity. The pore structures of geopolymers had clear fractal features as a whole. Among the two models, the thermodynamic model was more suitable to evaluate the fractal characteristic of the pores for geopolymer. The unconfined compressive strength rose with increasing surface fractal dimension, while the sorptivity coefficent exhibited an opposite trend.

Automated summary

The objective of this research was to investigate the effects of different granulated blast furnace slag (GBFS) on the unconfined compressive strength, sorptivity, and pore structures of recycled concrete fine powder (RCFP) based geopolymers. Tests were conducted to measure the unconfined compressive strength, sorptivity coefficient, and analyze the pore structures using SEM and MIP methods. The results showed that the incorporation of GBFS effectively reduced the sorptivity coefficient and increased the unconfined compressive strength. SEM analysis revealed that GBFS improved the degree of reaction, leading to a refinement of the internal pore structure. The addition of GBFS also facilitated the conversion of macropores into micropores, reducing porosity and pore size.