Study on Chain Extension Blending Modification and Foaming Behavior of Thermoplastic Elastomer

In order to improve the melt foaming properties of thermoplastic polyamide elastomers and reduce the shrinkage rate of foamed materials, acid anhydride chain extenders SMA (styrene maleic anhydride copolymer) are used in this paper to in situ reactive blending thermoplastic polyamide elastomers (TPAE) and polyamide 6 (PA6). The rheological and crystalline properties of the modified samples were characterized by a rotational rheometer and differential scanning calorimeter, and the melt batch foaming experiment with CO2 as the foaming agent was carried out. The results showed that the melting enthalpy of modified TPAE reduced with the addition of content of PA6, which implied that the crystallinity of the hard phase of the system was depressed. Nevertheless, the reduction of crystallinity was beneficial to improve the penetration of gas and reduce the effect of the pressure difference inside and outside the cell on foam shrinkage. Additionally, the microcross-linked structure formed with the increase of PA6 content enhanced the storage modulus of modified TPAE, which could accelerate recovery of strain. The foaming temperature zone and recovery performance of all modified TPAE samples were significantly improved. The overall shrinkage rate was reduced to less than 10%, the maximum expansion ratio could reach 11-13 times with a more complete and uniform cell structure, and the resilience was improved by about 12%.

Automated summary

In this study, acid anhydride chain extenders SMA were used to improve the melt foaming properties and reduce the shrinkage rate of thermoplastic polyamide elastomers (TPAE) blended with polyamide 6 (PA6). The modified TPAE samples showed reduced melting enthalpy and enhanced gas penetration and foam shrinkage reduction. Additionally, the microcross-linked structure formed with increased PA6 content improved the storage modulus and strain recovery of the modified TPAE. The foaming temperature zone and recovery performance of all modified TPAE samples were significantly improved, resulting in reduced overall shrinkage rate, increased expansion ratio, more complete cell structure, and improved resilience.