4.6 Article

1-Methyl-4-R-1,2,4-triazolium (R =-CH2CH2OCH3,-CH2COOCH2CH3)-Based Ionic Liquids as Plasticizers for Solid Propellants

Journal

ACS OMEGA
Volume 8, Issue 19, Pages 16738-16747

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.3c00256

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This paper synthesized and characterized a series of energetic ionic liquid plasticizers. The results showed that these compounds, particularly the ester-functionalized cations, were suitable as plasticizers for hydroxyl-terminated polybutadiene (HTPB) curing systems, improving the tensile strength and elongation at break. The ester-functionalized ionic liquids also reduced the glass transition temperature of HTPB elastomers, and the storage modulus varied depending on the anions present. The crosslink densities of HTPB/TDI/2a and HTPB/TDI/2b plasticized by ester-functionalized ionic liquids were larger.
In this paper, a series of energetic ionic liquid plasticizers of 1-methyl-4-methoxyethyl-1,2,4-triazolium chloride (1), 1methyl-4-methoxyethyl-1,2,4-triazolium bis(trifluoromethylsulfonyl)imide (1a), 1-methyl-4-methoxyethyl-1,2,4-triazolium nitrate (1b), 1-methyl-4-ethyl acetate-1,2,4-triazolium chloride (2), 1-methyl-4-ethyl acetate-1,2,4-triazolium bis(trifluoromethylsulfonyl)imide (2a), and 1-methyl-4-ethyl acetate-1,2,4-triazolium nitrate (2b) were synthesized and characterized. The results show that compounds 1a, 1b, 2a, and 2b have lower melting points (Tm, -72.60 to -32.67 degrees C) and good thermal stability (Td, 161-348 degrees C) and are suitable as plasticizers for hydroxyl-terminated polybutadiene (HTPB) curing systems. Among these four ionic liquids, esterfunctionalized cations can help to improve the tensile strength (2a, 0.943 MPa; 2b, 1.113 MPa) of the cured system, while etherfunctionalized cations are more beneficial to improve elongation at break (1a, 522.90%; 1b, 484.45%). Ester-functionalized ionic liquids are more beneficial to reduce the glass transition temperature of HTPB elastomers. The storage modulus of HTPB elastomers containing NO3- is higher, while that of HTPB elastomers containing NTf2- is lower. The crosslink densities of HTPB/TDI/2a and HTPB/TDI/2b plasticized by ester-functionalized ionic liquids are larger, which are 9369 and 9616 mol/m3, respectively. There are hydrogen bond interactions between the ionic liquid and the HTPB elastomer, and these interactions changed the distribution of the hard and soft segments in the polymer molecules.

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