4.6 Article

Semitransparent Solar Cells Employing n-Type Graphene on LaVO3

Journal

ACS OMEGA
Volume 8, Issue 21, Pages 18695-18701

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.3c00598

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In order to effectively utilize solar energy, it is necessary to have semitransparent solar cells in various fields. This study reports on semitransparent solar cells based on triethylenetetramine(TETA)-doped graphene (Gr) transparent conductive electrode (TCE)-based LaVO(3). By optimizing the Gr TCE with different TETA concentrations, the highest efficiency of 1.45% and average visible transmittance of 62% were achieved at the TETA concentration of 0.2 mM. The TETA-Gr/LaVO3 structure not only harvests solar energy but also exhibits translucency. The addition of an Al reflective mirror further increases the power conversion efficiency (PCE) to 1.99%.
To effectively utilize solar energy, semitransparentsolar cellsare essential in various fields such as building-integrated solarpower generation and portable solar chargers. We report triethylenetetramine(TETA)-doped graphene (Gr) transparent conductive electrode (TCE)-basedLaVO(3) semitransparent solar cells. To optimize the Gr TCE,we varied the TETA molar concentration (n (D)) from 0.1 to 0.3 mM. TETA-doped Gr (TETA-Gr)/LaVO3 semitransparentsolar cells exhibit the highest 1.45% efficiency and 62% average visibletransmittance at n (D) = 0.2 mM. These resultsindicate that the TETA-Gr/LaVO3 structure not only harvestssolar energy in the ultraviolet-visible region but also exhibitstranslucency, thanks to the thin film. Thanks to its translucent properties,we improved the power conversion efficiency (PCE) to 1.99% by addingan Al reflective mirror to the semitransparent cells. Finally, thedevice's PCE loss is only within 3% for 3000 h in air, suggestinggood durability.

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