Journal
JOURNAL OF ENERGY STORAGE
Volume 61, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.est.2023.106717
Keywords
V-doping; NiV-X/rGO (X = S and Se); MnV2O6.2H2O/rGO; Asymmetric supercapacitor; High energy densities
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Novel vanadium-doped nickel-chalcogenide/reduced graphene oxide cathodes and MnV2O6.2H(2)O/rGO anode were prepared through a solvothermal method. These electrode materials exhibited outstanding capacitive performance, remarkable cycling stability, and exceptional rate performance, showing potential application prospects in high energy density supercapacitors.
Exploring novel electrode materials with rational morphology and structure is crucial for the fabrication of high-performance supercapacitors. In this work, novel vanadium-doped nickel-chalcogenide/reduced graphene oxide cathodes (NiV-S/rGO and NiV-Se/rGO) and MnV2O6.2H(2)O/rGO anode are controllably prepared through a facile solvothermal method. Benefiting from the two-dimensional structure and desirable surface electronic environment, the graphene-supported NiV-X/rGO (X = S and Se) cathodes exhibit outstanding capacitive performance (1734.2 and 1577.2C.g(-1) at 2 A.g(-1)), remarkable cycling stability and exceptional rate performance. Meanwhile, with the encapsulation of graphene protect layers, the MnV2O6.2H(2)O/rGO anode also shows a significantly enhanced specific capacity and superb cycling stability (95.8 % retention after 10,000 cycles). When assembled into asymmetric supercapacitors, the NiV-S/rGO//MnV2O6.2H(2)O/rGO and NiV-Se/rGO//MnV2O6.2H(2)O/rGO devices not only exhibit ultra-high energy densities (82.4 and 60.0 Wh.kg(-1) at a power density of 800.0 W.kg(-1)), but also display superior cycling stabilities (91.5 % and 93.7 % retention after 10,000 cycles). These excellent properties demonstrate their potential application prospect in supercapacitor with high energy densities.
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