4.5 Article

Nitrogen implanted carbon nanosheets derived from Acorus calamus as an efficient electrode for the supercapacitor application

Journal

MOLECULAR CATALYSIS
Volume 538, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.mcat.2023.112978

Keywords

Acorus Calamus; Hydrothermal; Carbonization; Porous structures; Electrochemical double layer capacitance; Supercapacitor

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The biggest challenges in modern society revolve around the production and storage of affordable, clean energy. Recent research has focused on discovering new electrode materials to enhance energy production and storage. In this study, nitrogen-implanted carbon particles were synthesized for the first time from Acorus Calamus for use in symmetric supercapacitors. The carbon particles activated with KOH at 750 degrees C (C-750) under a nitrogen atmosphere exhibited superior structural, textural, morphological, and electrochemical performance. BET analysis confirmed that the C-750 carbon nanoparticles significantly increased the surface area to about 3551.07 m(2)/g. Further analysis revealed a pore size of 3.70 nm and a pore volume of 0.51 cc/g. The high surface area and mesoporous nature of the C-750 sample effectively enhanced the specific capacitance to 354.44 Fg(-1) at 1 Ag-1 using a 6 M KOH electrolytic solution. Additionally, the energy density and power density of the C-750 sample were observed to be approximately 47.2 Whkg(-1) and 16,000 Wkg(-1), respectively.
Modern society's biggest challenges are affordable, clean energy production and storage. Thus, recent research aims at the discovery of novel electrode materials for enhanced energy production and storage. Herein, nitrogen-implanted carbon particles were synthesized for the first time from the Acorus Calamus for the symmetric supercapacitor application. The KOH-activated carbon particles at 750 degrees C (C-750) under a nitrogen atmosphere revealed the better structural, textural, morphological, and electrochemical performance. The BET analysis confirmed that the C-750 carbon nanoparticles tremendously enhanced the surface area of about 3551.07 m(2)/g. Further, the pore size and pore volume were obtained from BJH analysis that showed 3.70 nm and 0.51 cc/g, respectively. The high surface area along with the mesoporous nature of the C-750 sample effectively enhanced the specific capacitance to 354.44 Fg(-1) at 1 Ag-1 using a 6 M KOH electrolytic solution. Further, the enhancement of energy and power density of the C-750 was observed at about 47.2 Whkg(-1) and 16,000 Wkg(-1), respectively.

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