Evolution of Mineral-Accessible Surface Area Induced by Geochemical Reactions

Mineral dissolution and precipitation reactions occur in a wide range of porous media systems, driven by deviations from an equilibrium between solid and fluid phases. Reactions occur at mineral surfaces in contact with reactive fluids or accessible mineral surface areas. These mineral surface areas can be determined using a multiscale imaging approach and have been shown to improve the simulation of mineral reaction rates in porous media compared to other estimates of reactive surface area. As reactions progress, mineral surface area evolves, and reactive transport simulations often use a simplified model assuming spherical grains to estimate mineral surface area evolution. This, however, does not depict the evolution of reactive surfaces in porous media systems with varying mineral accessibility. This work aims to quantitatively assess the evolution of accessible mineral surface area in porous media for a multimineralic system undergoing mineral dissolution reactions induced by acid exposure. Before and after the reaction, accessible mineral surface areas are determined from 2D scanning electron microscopy, and 3D X-ray computed tomography imaging of a sandstone sample. The quantified evolution of accessible surface area is compared to the calculated mineral surface area evolution using current approaches. Results show an overall increase in total surface area due to the reaction; however, individual mineral surface areas may increase or decrease. Variation is observed in mineral surface area values measured from imaging and equations used in models. The evolution of mineral surface area is largely impacted by the total surface area as well as the pore connectivity rather than porosity and volume fraction evolution.

Automated summary

This study aims to quantitatively assess the evolution of accessible mineral surface area in porous media for a multimineralic system undergoing mineral dissolution reactions induced by acid exposure. Results show an overall increase in total surface area due to the reaction; however, individual mineral surface areas may increase or decrease. The evolution of mineral surface area is largely impacted by the total surface area as well as the pore connectivity rather than porosity and volume fraction evolution.