Efficiency of Electrochemical Methods of Purification and Control over the Oxide Concentration in Halide Melts: PbCl2

The purification of molten salts from admixtures as well as the effective control of admixture concentration has attracted researchers' interests. In the present paper, the possibility of the electrochemical purification of PbCl2 from PbO and the effective control over the oxide ions concentration in molten PbCl2 is studied at the temperature of 520 degrees C. The PbCl2 melt with the initial addition of 0.5 wt% of PbO was used as a molten salt sample. The method of potentiostatic electrolysis was used to remove the oxide additions from the melt; the linear and square-wave voltammetry dependencies were recorded, and the melt samples were taken for analysis. Based both on the results of the electrochemical measurements and the analysis of oxygen concentration in the electrolyte, we built linear empirical dependencies of the anode peak current of the oxidation of oxygen-containing electroactive anions on the PbO concentration in the studied melt. We demonstrated that the obtained dependencies may be used for direct electrochemical nondestructive in-situ control over the concentration of PbO dissolved in the PbCl2 melt containing up to 0.5 wt% of PbO. The deep electrochemical purification of the chloride PbCl2 melt from molten oxide (up to 0.044 wt% PbO or to 0.007 wt% of oxygen) was achieved by the potentiostatic electrolysis.

Automated summary

This paper studies the possibility of electrochemical purification of PbCl2 from PbO and the effective control of oxide ions concentration in molten PbCl2 at 520°C. Potentiostatic electrolysis was used to remove oxide additions from the melt, and linear and square-wave voltammetry dependencies were recorded. Empirical linear dependencies of the anode peak current on PbO concentration were obtained, which can be used for in-situ control over PbO concentration in the melt. The deep electrochemical purification of PbCl2 melt from molten oxide was achieved.