Journal
LANGMUIR
Volume 32, Issue 19, Pages 4975-4982Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.6b00995
Keywords
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Funding
- French Research National Agency (ANR) [11-BS08-001]
- French department for high education and research (MESR) [ED 182, 2014-045]
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Binary c-T phase diagrams of organogelators in solvent are frequently simplified to two domains, gel and sol, even when the melting temperatures display two distinct regimes, an increase with T and a plateau. Herein, the c-T phase diagram of an organogelator in solvent is elucidated by rheology, DSC, optical microscopy, and transmitted light intensity measurements. We evidence a miscibility gap between the organogelator and the solvent above a threshold concentration, c(L). In this domain the melting or the formation of the gel becomes a monotectic transformation, which explains why the corresponding temperatures are nonvariant above c(L). As shown by further studies by variable temperature FTIR and NMR, different types of H-bonds drive both the liquid-liquid phase separation and the gelation.
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