Microwave Dielectric Properties of CaB2O4-CaSiO3 System for LTCC Applications

A novel composite ceramic with low densification temperature was fabricated using the conventional solid-state method. The XRD and Rietveld refinement results indicated that the two phases of CaB2O4 and CaSiO3 can coexist in all compositions. Furthermore, a phase transition of CaSiO3 ceramic from alpha-phase to beta-phase was observed. A dense ceramic with excellent microwave dielectric properties (epsilon(r)similar to 6.4, Q x f similar to 75,600 GHz, and a negative tau(f)similar to 26.9 ppm/degrees C) was obtained at x = 0.5 when sintered at 925 degrees C at the frequency of 14.2 GHz. A good chemical compatibility between the composite ceramic and Ag electrode was improved by elemental mapping results. A patch antenna was fabricated based on the simulated result. All results indicated that the 0.5 CaB2O4 + 0.5 CaSiO3 ceramic has large application potential in the LTCC field.

Automated summary

A novel composite ceramic with low densification temperature was synthesized using solid-state method, and it was found that CaB2O4 and CaSiO3 phases coexist in all compositions. The CaSiO3 ceramic exhibited a phase transition from alpha-phase to beta-phase. A dense ceramic with excellent microwave dielectric properties was obtained at x = 0.5 when sintered at 925 degrees C and frequency of 14.2 GHz. Chemical compatibility with Ag electrode was improved based on elemental mapping results. The composite ceramic showed great potential for application in the LTCC field.