Journal
CHEMCATCHEM
Volume 7, Issue 24, Pages 4050-4058Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201501021
Keywords
diketones; furans; levulinic acid; tandem catalysis; water
Categories
Funding
- IIT Indore
- CSIR, New Delhi [01(2722)/13/EMR-II]
- SERB (DST), New Delhi
- UGC New Delhi
Ask authors/readers for more resources
Efficient tandem catalytic transformations of bioderived furans, such as furfural, 5-hydroxymethylfurfural (5-HMF), and 5-methylfurfural (5-MF), to levulinic acid (LA) and diketones, 1-hydroxyhexane-2,5-dione (1-HHD), 3-hydroxyhexane-2,5-dione (3-HHD), and hexane-2,5-dione (2,5-HD), was achieved by using water-soluble arene-Ru-II complexes, containing ethylenediamine-based ligands, as catalysts in the presence of formic acid. The catalytic conversion of furans depends on the catalyst, ligand, formic acid concentration, reaction temperature, and time. Experimental evidence, including time-resolved (HNMR)-H-1 spectral studies, indicate that the catalytic reaction proceeds first with formyl hydrogenation followed by hydrolytic ring opening of furans. The ruthenium-formic acid tandem catalytic transformation of fructose to diketones and LA was also achieved. Finally, the molecular structures of the four representative arene-Ru-II catalysts were established by single-crystal X-ray diffraction studies.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available