Dual-Functional Solar-to-Steam Generation and SERS Detection Substrate Based on Plasmonic Nanostructure

Solar-to-steam (STS) generation based on plasmonic materials has attracted significant attention as a green method for producing fresh water. Herein, a simple in situ method is introduced to fabricate Au nanoparticles (AuNPs) on cellulose filter papers as dual-functional substrates for STS generation and surface-enhanced Raman spectroscopy (SERS) sensing. The substrates exhibit 90% of broadband solar absorption between 350 and 1800 nm and achieve an evaporation rate of 0.96 kg center dot m(-2)center dot h(-1) under 1-sun illumination, room temperature of 20 degrees C, and relative humidity of 40%. The STS generation of the substrate is stable during 30 h continuous operation. Enriched SERS hotspots between AuNPs endow the substrates with the ability to detect chemical contamination in water with ppb limits of detection for rhodamine 6G dye and melamine. To demonstrate dual-functional properties, the contaminated water was analyzed with SERS and purified by STS. The purified water was then analyzed with SERS to confirm its purity. The developed substrate can be an improved and suitable candidate for fresh water production and qualification.

Automated summary

A simple in situ method is introduced to fabricate Au nanoparticles on cellulose filter papers as dual-functional substrates for solar-to-steam (STS) generation and surface-enhanced Raman spectroscopy (SERS) sensing. The substrates exhibit high solar absorption and achieve a stable evaporation rate under sunlight illumination. Enriched SERS hotspots between AuNPs endow the substrates with the ability to detect chemical contamination in water, and the purified water can be analyzed using SERS for confirmation.