Pencil-like Hollow Carbon Nanotubes Embedded CoP-V4P3 Heterostructures as a Bifunctional Catalyst for Electrocatalytic Overall Water Splitting

Electrocatalytic water splitting is one of the most efficient ways of producing green hydrogen energy. The design of stable, active, and efficient electrocatalysts plays a crucial role in water splitting for achieving efficient energy conversion from electrical to hydrogen energy, aimed at solving the lingering energy crisis. In this work, CNT composites modified with CoP-V4P3 composites (CoVO-10-CNT-450P) were formed by carbonising a pencil-like precursor (Co3V2O8-H2O) and growing carbon nanotubes in situ, followed by in situ phosphorylation on the carbon nanotubes. In the HER electrocatalytic process, an overpotential of only 124 mV was exhibited at a current density of 10 mA cm(-2). In addition, as an OER catalyst, a low overpotential of 280 mV was attained at a current density of 10 mA cm(-2). Moreover, there was no noticeable change in the performance of the catalyst over a 90 h test in a continuous total water splitting experiment. The unique electronic structure and hollow carbon nanotube structure of CoVO-10-CNT-450P effectively increased the catalytic active sites, while also significantly improving the electrocatalytic activity. This work provides theoretical guidance for the design and synthetic route of high-performance non-precious metal electrocatalysts, and actively promotes the commercial application of electrochemical water splitting.

Automated summary

Electrocatalytic water splitting is crucial for efficient energy conversion from electrical to hydrogen energy. In this study, CNT composites modified with CoP-V4P3 composites were synthesized and shown to have excellent electrocatalytic activity in both hydrogen evolution and oxygen evolution reactions. The unique electronic and hollow carbon nanotube structure of the catalyst effectively increased the catalytic active sites and stability. This work provides guidance for the design and synthesis of high-performance non-precious metal electrocatalysts and promotes the commercial application of electrochemical water splitting.