Binary Aluminum Alloys from 1-ethyl-3-methylimidazolium-based Ionic Liquids for Cathodic Corrosion Protection

Aluminum cannot provide continuous cathodic corrosion protection under ambient conditions due to the formation of an insulating oxide layer and therefore it should be alloyed. Binary aluminum alloys with Cr, Zn and Sn from AlCl3/1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) containing CrCl2, ZnCl2 or SnCl2 have been deposited and their morphology and composition were investigated using SEM/EDS. The corrosion behavior of alloys with 2-4 wt% Cr, Zn or Sn was investigated using potentiodynamic polarization in 3.5 wt% NaCl solution, neutral salt spray test (NSS) and environmental exposure (EE). Pure aluminum provides excellent corrosion protection of steel in a chloride-containing environment, but not under ambient conditions. AlCr alloys show poor corrosion protection while AlZn alloys provide excellent corrosion protection in the NSS test and superior cathodic protection in the EE test compared to aluminum. AlSn alloys are highly active at even low tin contents and dissolve rapidly in chloride-containing electrolytes. However, a slightly improved cathodic protection in the EE test compared to pure aluminum has been observed. The results prove the necessity of alloying aluminum to achieve effective cathodic corrosion protection under mild atmospheric conditions.

Automated summary

Aluminum needs to be alloyed to achieve effective cathodic corrosion protection under mild atmospheric conditions due to the formation of an insulating oxide layer. Aluminum alloys with Cr, Zn, and Sn have been studied and their corrosion behavior and protection capabilities investigated. Pure aluminum provides excellent corrosion protection in chloride-containing environments, but not under ambient conditions. Alloys with zinc provide superior corrosion protection compared to aluminum, while alloys with tin show high activity and rapid dissolution. Alloying aluminum is necessary to achieve effective cathodic corrosion protection under mild atmospheric conditions.