Journal
CHEMCATCHEM
Volume 7, Issue 6, Pages 911-915Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201403026
Keywords
fuel cells; graphene; methanol tolerance; oxygen reduction reaction; tantalum
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Funding
- Mobility project Italy-Quebec (Canada) [QU13MO7]
- European Community [278054]
- Fonds de Recherche du Quebec Nature et Technologies (FRQNT) (Quebec, Canada)
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For the oxygen reduction reaction (ORR) in acidic medium, a good combination of an active and stable catalyst highly dispersed on a conductive and durable support is required. Moreover, for direct methanol fuel-cell applications, a suitable tolerance to methanol poisoning is also necessary. In this communication, we report on a new graphene-supported sodium tantalate (Na2Ta8O21-x) electrocatalyst obtained at high temperature and characterized by significant substoichiometry. The synthesis includes the precipitation of tantalum oxide on a high surface area graphene and subsequent thermal treatment at 900 degrees C. A novel sodium tantalate phase with oxygen vacancies is thereafter obtained. This catalyst formulation shows promising activity towards the ORR especially in the presence of a high methanol concentration, as evidenced by a high tolerance to methanol poisoning. Accelerated stress tests and chemical leaching experiments also show the remarkable stability of the catalyst. This material presents good perspectives for application in cost-effective fuel cells.
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