Journal
ENERGY TECHNOLOGY
Volume 11, Issue 7, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.202300248
Keywords
charge transport layers; FAPbI(3); kesterites; perovskite solar cells; SCAPS-1D
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This study investigates the performance of different kesterite materials as hole transport layers and zinc-based materials as electron transport layers in FAPbI(3)-based perovskite solar cells. A total of 24 structures are modeled and optimized, and the effects on optical absorption, quantum efficiency, electric field, I-V characteristics, and recombination are studied. The CBTS/FAPbI(3)/CdZnS structure is found to have the best performance with a PCE of 28.55%, short-circuit current of 26.8 mA cm(-2), open-circuit voltage of 1.19 V, and fill factor of 88.93%.
Formamidinium lead triiodide (FAPbI(3))-based perovskite solar cells (PSCs) have shown greater structural stability but lower power conversion efficiency (PCE) than other established perovskites. The efficiency of the PSC can be improved by identifying suitable charge transport layers for FAPbI(3), having good conductivity, and wide bandgap. Kesterite materials belonging to the adamantine family of chalcogenides are quaternary compounds with high conductivity and tunable bandgap. They have shown excellent results when employed in thin films and hence have emerged as an alternate option to be used for the hole transport layers (HTL). Similarly, zinc-based materials have remarkable properties in terms of their wide bandgap, inability to oxidize, and abundance, making them a viable option to be explored as electron transport layers (ETL). Herein, six different kesterits are used as HTL to simulate FAPbI(3) PSC with four different zinc-based ETL. Henceforth, a total of 24 structures is modeled and optimized using SCAPS-1D. The effect of these materials on the optical absorption, quantum efficiency, electric field, I-V characteristics, and recombination is studied. Among all the structures, CBTS/FAPbI(3)/CdZnS is found to be the best-performing PSC structure with PCE of 28.55%, short-circuit current of 26.8 mA cm(-2), open-circuit voltage of 1.19 V, and fill factor of 88.93%.
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