Journal
CHEMELECTROCHEM
Volume 10, Issue 8, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.202300018
Keywords
Glyceric acid; Energy conversion; Oxidation; Solketal oxidation; Water splitting
Categories
Ask authors/readers for more resources
In this work, the electrooxidation of solketal (SOR), acetal-protected glycerol, is explored over Cu-Co hydroxycarbonates to promote the formation of glycerol-derived C3 products and to limit Cu leaching from the catalyst. The competition between oxygen evolution reaction (OER) and SOR was evaluated, and the solketal de-acetalization as a function of potential was studied. The solketal/OH- ratio was found to affect the reaction selectivity.
The glycerol oxidation reaction (GOR) has high potential in substituting the oxygen evolution reaction (OER) in electrochemical water splitting, enabling the synthesis of value-added organic products. The Cu-rich Cu-Co hydroxycarbonates show high activity in GOR and promote formate production but undergo severe Cu leaching in the presence of deprotonated glycerol. In this work, the electrooxidation of solketal (SOR), acetal-protected glycerol, is explored over a series of Cu-Co hydroxycarbonates, to promote the formation of glycerol-derived C3 products, such as glyceric acid, with faradaic efficiencies of around 70 %, and to limit the Cu leaching from the catalyst. The competition between OER and SOR was evaluated using rotating disk electrodes and differential electrochemical mass spectrometry. Insights into the solketal de-acetalization as a function of potential are obtained using in situ spectroscopic methods. The solketal/OH- ratio influences the reaction selectivity, with oxalate production increasing when 7 m KOH is used instead of 1 m KOH.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available