☆ 4.5 Article

Enhanced Pomegranate-Structured SnO2 Electrocatalysts for the Electrochemical CO2 Reduction to Formate

CHEMELECTROCHEM (2023)

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Carbon Shell on Active Nanocatalyst for Stable Electrocatalysis

Ji Mun Yoo et al.

Summary: Electrocatalysis is essential for renewable energy conversion and fuel production in future energy systems. Various nanostructures have been explored to enhance electrocatalytic activity, but ensuring long-term stability of electrocatalysts is crucial for reliable energy device operation. The challenge lies in achieving both high activity and robust stability simultaneously, as the structure-property relationships affecting activity and stability differ. Introducing functional structural units into catalyst design is essential to achieve electrochemical stability while maintaining high activity.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

Add to Collection
Article Nanoscience & Nanotechnology

Use of Nanoscale Carbon Layers on Ag-Based Gas Diffusion Electrodes to Promote CO Production

Lien Pacquets et al.

Summary: Applying a nanoscale amorphous carbon layer on top of the active catalyst layer can inhibit the hydrogen evolution reaction and stabilize the electrocatalyst in electrochemical CO2 reduction cells. A thickness of 15 nm was found to provide optimal inhibition and stability.

ACS APPLIED NANO MATERIALS (2022)

Add to Collection
Article Chemistry, Physical

Active Surface Structure of SnO2 Catalysts for CO2 Reduction Revealed by Ab Initio Simulations

Clara Salvini et al.

Summary: Using ab initio density functional theory calculations, it was found that the selectivity and reactivity of SnO2 surfaces towards CO2RR can be changed by varying the surface stoichiometry. The SnO2(110) surface is not catalytically active but can be reduced under an applied external bias, leading to the exposure of metal tin layers responsible for formic acid selectivity.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

Add to Collection
Review Chemistry, Multidisciplinary

Recent progress of Bi-based electrocatalysts for electrocatalytic CO2 reduction

Dong Xia et al.

Summary: In order to tackle the issue of carbon dioxide, the applications of unary Bi electrocatalysts and binary BiSn electrocatalysts in CO2RR were studied. These catalysts demonstrate high faradaic efficiencies in producing formic acid, which has significant value in the chemical and pharmaceutical industries. Additionally, the use of solid-state electrolytes shows promise in achieving high-purity formic acid production.

NANOSCALE (2022)

Add to Collection
Review Chemistry, Multidisciplinary

Matching emerging formic acid synthesis processes with application requirements

Barbara Thijs et al.

Summary: This article discusses the concentration requirements of formic acid in the electrochemical production process as a carbon capture and utilization product. It explains how the specifications of electrochemical formic acid production can be matched with the requirements of emerging applications.

GREEN CHEMISTRY (2022)

Add to Collection
Article Nanoscience & Nanotechnology

An industrial perspective on catalysts for low-temperature CO2 electrolysis

Richard I. Masel et al.

Summary: This Perspective discusses the key advances in nanocatalysts that have led to significant progress in the electrochemical conversion of CO2 to useful products, providing benchmarks for comparison and highlighting the need for further research.

NATURE NANOTECHNOLOGY (2021)

Add to Collection
Article Multidisciplinary Sciences

Anomalous collapses of Nares Strait ice arches leads to enhanced export of Arctic sea ice

G. W. K. Moore et al.

Summary: Ice arches at the northern and southern ends of Nares Strait, a key passage in the Arctic, are forming for shorter durations, leading to increased ice transport and accelerating the export of multi-year ice.

NATURE COMMUNICATIONS (2021)

Add to Collection
Article Chemistry, Physical

Sn-Based Electrocatalyst Stability: A Crucial Piece to the Puzzle for the Electrochemical CO2 Reduction toward Formic Acid

Kevin Van Daele et al.

Summary: This article discusses the stability issues related to Sn-based electrocatalysts for the electrochemical reduction of formic acid, providing insights into common degradation mechanisms and emphasizing the importance of selected process conditions and reactor design for achieving stable performance in formic acid production. By studying the chemical and physical phenomena occurring during the electrochemical reduction reaction on the surface and bulk of the Sn-based catalysts, the article aims to elucidate the factors affecting long-term electrocatalytic activity.

ACS ENERGY LETTERS (2021)

Add to Collection
Article Chemistry, Physical

Electrochemical reduction of SnO2 to Sn from the Bottom: In-Situ formation of SnO2/Sn heterostructure for highly efficient electrochemical reduction of carbon dioxide to formate

Shunlian Ning et al.

Summary: The design and engineering of low-cost, high-performance catalysts for electrochemical CO2 reduction (CO2R) is crucial. SnO2 nanoparticles grown on carbon cloth (SnO2/CF) demonstrated excellent electrocatalytic activity towards CO2R forming SnO2/Sn Mott-Schottky heterojunctions, resulting in high faradaic efficiency and current density for formate production. Density functional theory calculations indicate that the SnO2/Sn heterostructures decreased the energy barrier for formate formation, leading to high activity and selectivity for formate production. This study provides insights into the evolution dynamics of SnO2 catalysts under CO2R conditions and the active component of SnO2 in CO2R.

JOURNAL OF CATALYSIS (2021)

Add to Collection
Article Engineering, Environmental

Scarce mineral resources: Extraction, consumption and limits of sustainability

Theo Henckens

Summary: This article explores the balance between reducing the extraction rate of geologically scarce mineral resources and increasing their service level, finding that stringent resource-saving measures can extend the sustainable use time of these resources and improve the global service level.

RESOURCES CONSERVATION AND RECYCLING (2021)

Add to Collection
Review Electrochemistry

Electroreduction of Carbon Dioxide into Formate: A Comprehensive Review

Shaima A. Al-Tamreh et al.

Summary: Conversion of carbon dioxide into valuable products through electrochemical methods using active catalysts and electrical energy is a technique gaining attention for mitigating global warming. Future research should focus on developing novel, selective catalysts to improve product yield and reduce energy consumption.

CHEMELECTROCHEM (2021)

Add to Collection
Article Chemistry, Physical

Defect evolution of hierarchical SnO2 aggregates for boosting CO2 electrocatalytic reduction

Xueying Cao et al.

Summary: Efficient conversion of CO2 into high-value added products via electrocatalytic reduction requires rational regulation of surface defects and interfacial structure of electrocatalysts. A feasible strategy to manipulate oxygen vacancies and interfacial boundaries on hierarchical tin oxide aggregates has been presented, showing enhanced performance in CO2 reduction efficiency. Synergistic effect of residual oxygen vacancies and interfacial structure is crucial for energy favorable reduction of carbon dioxide, leading to improved selectivity for formate generation.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Add to Collection
Review Chemistry, Multidisciplinary

Stability and Degradation Mechanisms of Copper-Based Catalysts for Electrochemical CO2 Reduction

Stefan Popovic et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection
Article Nanoscience & Nanotechnology

P-block metal-based (Sn, In, Bi, Pb) electrocatalysts for selective reduction of CO2 to formate

Zhenni Yang et al.

APL MATERIALS (2020)

Add to Collection
Article Chemistry, Physical

Production of formate by CO2 electrochemical reduction and its application in energy storage

Hang Xiang et al.

SUSTAINABLE ENERGY & FUELS (2020)

Add to Collection
Review Chemistry, Multidisciplinary

Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO2 utilization

R. Gary Grim et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Add to Collection
Review Chemistry, Multidisciplinary

Electrochemical CO2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

Md Golam Kibria et al.

ADVANCED MATERIALS (2019)

Add to Collection
Article Chemistry, Multidisciplinary

Electrodeposition of Tin-Based Electrocatalysts with Different Surface Tin Species Distributions for Electrochemical Reduction of CO2 to HCOOH

Xiaowei An et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Add to Collection
Article Chemistry, Multidisciplinary

SO2-Induced Selectivity Change in CO2 Electroreduction

Wesley Luc et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection
Review Nanoscience & Nanotechnology

Advances in Sn-Based Catalysts for Electrochemical CO2 Reduction

Shulin Zhao et al.

NANO-MICRO LETTERS (2019)

Add to Collection
Article Chemistry, Physical

On the Mechanism of Carbon Dioxide Reduction on Sn-Based Electrodes: Insights into the Role of Oxide Surfaces

Giane B. Damas et al.

CATALYSTS (2019)

Add to Collection
Review Energy & Fuels

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

Yuvraj Y. Birdja et al.

NATURE ENERGY (2019)

Add to Collection
Article Chemistry, Multidisciplinary

Leaching-resistant SnO2/γ-Al2O3 nanocatalyst for stable electrochemical CO2 reduction into formate

Young Eun Kim et al.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2019)

Add to Collection
Article Engineering, Environmental

Influence of flow and pressure distribution inside a gas diffusion electrode on the performance of a flow-by CO2 electrolyzer

Bert De Mot et al.

CHEMICAL ENGINEERING JOURNAL (2019)

Add to Collection
Review Chemistry, Multidisciplinary

Approaches for measuring the surface areas of metal oxide electrocatalysts for determining their intrinsic electrocatalytic activity

Chao Wei et al.

CHEMICAL SOCIETY REVIEWS (2019)

Add to Collection
Article Chemistry, Physical

Pore-structure-directed CO2 electroreduction to formate on SnO2/C catalysts

Yeheng He et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection
Article Chemistry, Physical

Probing the chemical state of tin oxide NP catalysts during CO2 electroreduction: A complementary operando approach

Abhijit Dutta et al.

NANO ENERGY (2018)

Add to Collection
Review Chemistry, Multidisciplinary

Progress toward Commercial Application of Electrochemical Carbon Dioxide Reduction

Chi Chen et al.

CHEM (2018)

Add to Collection
Review Chemistry, Physical

What Should We Make with CO2 and How Can We Make It?

Oleksandr S. Bushuyev et al.

JOULE (2018)

Add to Collection
Article Materials Science, Multidisciplinary

Stable nanoporous Sn/SnO2 composites for efficient electroreduction of CO2 to formate over wide potential range

Siyu Liu et al.

APPLIED MATERIALS TODAY (2018)

Add to Collection
Editorial Material Multidisciplinary Sciences

The irreversible momentum of clean energy

Barack Obama

SCIENCE (2017)

Add to Collection
Article Chemistry, Physical

Formic acid synthesis using CO2 as raw material: Techno-economic and environmental evaluation and market potential

Mar Perez-Fortes et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2016)

Add to Collection
Article Chemistry, Physical

Promotional effect of surface hydroxyls on electrochemical reduction of CO2 over SnOx/Sn electrode

Chaonan Cui et al.

JOURNAL OF CATALYSIS (2016)

Add to Collection
Article Multidisciplinary Sciences

Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction

Fengcai Lei et al.

NATURE COMMUNICATIONS (2016)

Add to Collection
Article Chemistry, Physical

Origin of the performance degradation and implementation of stable tin electrodes for the conversion of CO2 to fuels

Jingjie Wu et al.

NANO ENERGY (2016)

Add to Collection
Article Chemistry, Physical

Role of the oxide layer on Sn electrode in electrochemical reduction of CO2 to formate

Rui Zhang et al.

APPLIED SURFACE SCIENCE (2015)

Add to Collection
Article Electrochemistry

Cu particles decorated pomegranate-structured SnO2@C composites as anode for lithium ion batteries with enhanced performance

WeiWei Wen et al.

ELECTROCHIMICA ACTA (2015)

Add to Collection
Article Chemistry, Multidisciplinary

Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)

Matthias Thommes et al.

PURE AND APPLIED CHEMISTRY (2015)

Add to Collection
Article Chemistry, Multidisciplinary

A DFT study of CO2 electrochemical reduction on Pb(211) and Sn(112)

Chaonan Cui et al.

SCIENCE CHINA-CHEMISTRY (2015)

Add to Collection
Article Chemistry, Physical

Monitoring the Chemical State of Catalysts for CO2 Electroreduction: An In Operando Study

Abhijit Dutta et al.

ACS CATALYSIS (2015)

Add to Collection
Article Chemistry, Physical

Mechanistic Insights into the Reduction of CO2 on Tin Electrodes using in Situ ATR-IR Spectroscopy

Maor F. Baruch et al.

ACS CATALYSIS (2015)

Add to Collection
Article Chemistry, Multidisciplinary

Tin Oxide Dependence of the CO2 Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts

Yihong Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Add to Collection
Article Chemistry, Multidisciplinary

Crystallography Open Database - an open-access collection of crystal structures

Saulius Grazulis et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2009)

Add to Collection
Webinars Posters Questions Hubs Funding Journals Papers Connect Collections Reviewers About Us FAQs Mobile App Privacy Policy Terms of Use
© Peeref 2019-2024. All rights reserved.