PGM-Free Electrocatalytic Layer Characterization by Electrochemical Impedance Spectroscopy of an Anion Exchange Membrane Water Electrolyzer with Nafion Ionomer as the Bonding Agent

Low-cost anion exchange membrane (AEM) water electrolysis is a promising technology for producing green high-purity hydrogen using platinum group metal (PGM)-free catalysts. The performance of AEM electrolysis depends on the overall overvoltage, e.g., voltage losses coming from different processes in the water electrolyzer including hydrogen and oxygen evolution, non-faradaic charge transfer resistance, mass transfer limitations, and others. Due to the different relaxation times of these processes, it is possible to unravel them in the frequency domain by electrochemical impedance spectroscopy. This study relates to solving and quantifying contributions to the total polarization resistance of the AEM water electrolyzer, including ohmic and charge transfer resistances in the kinetically controlled mode. The high-frequency contribution is proposed to have non-faradaic nature, and its conceivable nature and mechanism are discussed. The characteristic frequencies of unraveled contributions are provided to be used as benchmark data for commercially available membranes and electrodes.

Automated summary

Low-cost anion exchange membrane (AEM) water electrolysis is a promising technology for producing green high-purity hydrogen using platinum group metal (PGM)-free catalysts. The performance of AEM electrolysis depends on different processes in the water electrolyzer and can be unraveled using electrochemical impedance spectroscopy. This study focuses on solving and quantifying the contributions to the total polarization resistance of the AEM water electrolyzer, including non-faradaic charge transfer resistance and ohmic resistance.