4.6 Article

Operando Laboratory X-ray Absorption Spectroscopy and UV-Vis Study of Pt/TiO2 Photocatalysts during Photodeposition and Hydrogen Evolution Reactions

Journal

CATALYSTS
Volume 13, Issue 2, Pages -

Publisher

MDPI
DOI: 10.3390/catal13020414

Keywords

operando spectroscopy; XANES; photocatalysis; platinum catalyst; UV-Vis; HER; photodeposition

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Photocatalytic hydrogen production is a promising alternative energy route. In this study, operando spectroscopy was used to understand the structure-activity relationships of a catalytic system during the photodeposition of Pt on TiO2 and photostimulated H-2 production. XAS showed an increase in Pt fluorescence correlated with H-2 production, and the final Pt/TiO2 catalyst contained Pt(0) particles. UV-Vis spectroscopy revealed the disappearance of electronic features corresponding to Pt4+ species in the presence of formic acid, resulting in the presence of Pt(0) particles.
Photocatalytic hydrogen (H-2) production is a promising route for alternative energetics. Understanding structure-activity relationships is a crucial step towards the rational design of photocatalysts, which requires the application of operando spectroscopy under relevant working conditions. We performed an operando investigation on a catalytic system during the photodeposition of Pt on TiO2 and photostimulated H-2 production, using simultaneous laboratory X-ray absorption spectroscopy (XAS), UV-Vis spectroscopy, and mass spectrometry. XAS showed a progressive increase in Pt fluorescence for Pt deposited on TiO2 for over an hour, which is correlated with the signal of the produced H-2. The final Pt/TiO2 catalyst contained Pt(0) particles. The electronic features corresponding to the Pt4+ species in the UV-Vis spectrum of the solution disappear as soon as UV radiation is applied in the presence of formic acid, which acts as a hole scavenger, resulting in the presence of Pt(0) particles in solution.

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