4.6 Article

Moderately concentrated electrolyte enabling high-performance lithium metal batteries with a wide working temperature range

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Ultrathin and High-Modulus LiBO2 Layer Highly Elevates the Interfacial Dynamics and Stability of Lithium Anode under Wide Temperature Range

Song Li et al.

Summary: Constructing an ultrathin LiBO2 layer on Li anode can effectively suppress dendrite growth at subambient temperature and side reactions at high temperature in lithium metal batteries, leading to improved cycling life and performance of the batteries.

SMALL (2022)

Article Chemistry, Physical

Li+ Ion Transport at the Lithium Metal Anode: A Fundamental Picture and Future Perspectives

Benjamin P. Williams et al.

Summary: This article introduces several mechanisms that define the transport of ions through the solid-electrolyte interphase (SEI), and builds on these mechanisms with examples of their application in real battery systems. The aim is to provide a foundation of structure-property relationships for the rational design of stable SEIs that efficiently transport Li+ ions.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

Article Chemistry, Multidisciplinary

Low Concentration Electrolyte Enabling Cryogenic Lithium-Sulfur Batteries

Fulu Chu et al.

Summary: This study demonstrates that using a low concentration electrolyte can accelerate lithium-sulfur conversion reactions at low temperatures, leading to higher capacity utilization and more stable cycle performance. The interfacial analysis and battery tests show that the low concentration electrolyte can construct a more effective surface layer and suppress shuttle effects of polysulfides.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Ethylene-Carbonate-Free Electrolytes for Rechargeable Li-Ion Pouch Cells at Sub-Freezing Temperatures

Yu-Xing Yao et al.

Summary: Current Li-ion batteries face challenges at sub-freezing temperatures, but a new EC-free electrolyte shows promising low-temperature performance, enhancing capacity retention and reducing Li plating during charging.

ADVANCED MATERIALS (2022)

Article Chemistry, Physical

Probing the Functionality of LiFSI Structural Derivatives as Additives for Li Metal Anodes

Kyle S. Jiang et al.

Summary: This study investigates the correlation between the structural features of sulfonyl/sulfamoyl fluoride additives and the cycle performance of lithium-ion batteries. The results show that, in addition to coordination, the reactivity of the solvent and the structural features of the additives strongly regulate the cycling efficiency.

ACS ENERGY LETTERS (2022)

Article Chemistry, Multidisciplinary

Inhibiting Solvent Co-Intercalation in a Graphite Anode by a Localized High-Concentration Electrolyte in Fast-Charging Batteries

Li-Li Jiang et al.

Summary: By utilizing a localized high-concentration electrolyte, a uniform and robust solid electrolyte interphase can be achieved on the graphite surface, leading to fast-charging performance and excellent cycling stability of lithium-ion batteries.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Recent Progress in Understanding Solid Electrolyte Interphase on Lithium Metal Anodes

Haiping Wu et al.

Summary: The structure, properties, and influencing factors of SEI play a crucial role in the performance of lithium metal batteries. Efficient strategies for tailoring SEI involve understanding the composition, models, and properties of SEI, as well as the correlations between electrolyte components and SEI. Future directions include in-operando techniques, multi-modality approaches for SEI characterization, and artificial intelligence assisted understanding of SEI properties.

ADVANCED ENERGY MATERIALS (2021)

Article Materials Science, Multidisciplinary

Strategies for fabrication, confinement and performance boost of Li2S in lithium- sulfur, silicon-sulfur & related batteries

Shunrui Luo et al.

Summary: This review discusses various approaches for producing Li2S-based nano- and micron-scale composite particles and standalone electrodes aiming to overcoming challenges. Additionally, strategies for electrolyte optimizations are also discussed. The perspective on the gaps between research demonstrations and mass-market commercialization requirements is shared.

MATERIALS TODAY (2021)

Article Chemistry, Multidisciplinary

Competitive Solvation Enhanced Stability of Lithium Metal Anode in Dual-Salt Electrolyte

Simeng Zhang et al.

Summary: The introduction of consumptive LiNO3 as a cosalt in the LiPF6-LiNO3 dual-salt electrolyte can enhance the cycling stability of lithium plating/stripping, preventing lithium residue and dendrite formation. Competitive solvation facilitates the formation of a Li3N-rich SEI film, improving the cycling performance of the battery.

NANO LETTERS (2021)

Article Chemistry, Applied

A robust interface enabled by electrospun membrane with optimal resistance in lithium metal batteries

Chen Dong et al.

Summary: By spinning soft polymer associated with few MoO3 into fibers, a robust and stable interface was achieved, allowing for optimization of the mechanical performance of the interface by adjusting parameters.

JOURNAL OF ENERGY CHEMISTRY (2021)

Article Nanoscience & Nanotechnology

Flame-Retardant and Polysulfide-Suppressed Ether-Based Electrolytes for High-Temperature Li-S Batteries

Mengxue He et al.

Summary: A novel electrolyte with polysulfide-suppressed and flame-retardant properties has been proposed, addressing the safety issues of traditional ether-based solvents at high temperatures and improving the electrochemical performance of Li-S batteries. The introduction of an inert diluent and the formation of a LiF-rich protective layer efficiently suppress Li dendrites and mitigate the shuttle effect, leading to greatly improved high-temperature performance. The enhanced safety and practical prospect make this electrolyte a promising option for safe Li-S batteries.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Stable Anion-Derived Solid Electrolyte Interphase in Lithium Metal Batteries

Tao Li et al.

Summary: By regulating the electrolyte structure of anions using TPFPB anion acceptors, a stable anion-derived SEI was constructed to improve the stability and cycling performance of lithium metal batteries under practical conditions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

A Multifunctional Dual-Salt Localized High-Concentration Electrolyte for Fast Dynamic High-Voltage Lithium Battery in Wide Temperature Range

Shuangshuang Lin et al.

Summary: This study introduces a multifunctional high-concentration electrolyte containing fluorocarbonate, which shows excellent performance under high voltage and low temperature conditions, providing a new approach for designing high-performance lithium batteries.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

High-Performance Lithium Metal Batteries with a Wide Operating Temperature Range in Carbonate Electrolyte by Manipulating Interfacial Chemistry

Peitao Xiao et al.

Summary: In this study, a new solvent TPPO was introduced to improve the carbonate electrolyte and achieve stable cycling performance of lithium metal batteries. The interaction between TPPO and Li+ can prevent the formation of lithium dendrites and suppress electrolyte decomposition, enabling high stability over a wide temperature range (-15 to 70 degrees Celsius).

ACS ENERGY LETTERS (2021)

Article Chemistry, Physical

Cocktail therapy towards high temperature/high voltage lithium metal battery via solvation sheath structure tuning

Tianle Zheng et al.

Summary: By manipulating the solvation structure in the ADFN electrolyte solution, a stable SEI layer rich in inorganic species was generated to inhibit the continuous consumption of electrolyte solvent and suppress lithium dendrite growth. This innovative strategy provides fundamental insights into ADN solvation and offers a simple way to optimize Li-ion electrolyte for wide-temperature and high voltage applications, leading to improved cyclic stability and electrochemical performance.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Multidisciplinary

Cycling a Lithium Metal Anode at 90 °C in a Liquid Electrolyte

Li-Peng Hou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Nanoscience & Nanotechnology

Boosting Lithium Storage in Free-Standing Black Phosphorus Anode via Multifunction of Nanocellulose

Renheng Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Review Chemistry, Applied

Lithium metal anodes: Present and future

Renheng Wang et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Liquefied gas electrolytes for wide-temperature lithium metal batteries

Yangyuchen Yang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

FSI-inspired solvent and full fluorosulfonyl electrolyte for 4 V class lithium-metal batteries

Weijiang Xue et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Physical

Lithium Diffusion Mechanism through Solid-Electrolyte Interphase in Rechargeable Lithium Batteries

Ajaykrishna Ramasubramanian et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

Article Chemistry, Physical

High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries

Xiaodi Ren et al.

ACS ENERGY LETTERS (2019)

Review Energy & Fuels

Advances and issues in developing salt-concentrated battery electrolytes

Yuki Yamada et al.

NATURE ENERGY (2019)

Article Energy & Fuels

Fire-extinguishing organic electrolytes for safe batteries

Jianhui Wang et al.

NATURE ENERGY (2018)

Article Chemistry, Multidisciplinary

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes

Shuru Chen et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Multidisciplinary

Dual-Layered Film Protected Lithium Metal Anode to Enable Dendrite-Free Lithium Deposition

Chong Yan et al.

ADVANCED MATERIALS (2018)

Review Chemistry, Multidisciplinary

Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives

Heng Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Multidisciplinary Sciences

Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries

Liumin Suo et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

Article Chemistry, Multidisciplinary

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries

Xiulin Fan et al.

Article Chemistry, Physical

2D Materials for Lithium/Sodium Metal Anodes

Chanyuan Zhang et al.

ADVANCED ENERGY MATERIALS (2018)

Article Chemistry, Multidisciplinary

Columnar Lithium Metal Anodes

Xue-Qiang Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Multidisciplinary

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Multidisciplinary

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries

Xue-Qiang Zhang et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

Review Electrochemistry

Review-Superconcentrated Electrolytes for Lithium Batteries

Yuki Yamada et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

Article Materials Science, Multidisciplinary

Li-ion battery materials: present and future

Naoki Nitta et al.

MATERIALS TODAY (2015)

Article Multidisciplinary Sciences

Water-in-salt electrolyte enables high-voltage aqueous lithium-ion chemistries

Liumin Suo et al.

SCIENCE (2015)

Article Multidisciplinary Sciences

High rate and stable cycling of lithium metal anode

Jiangfeng Qian et al.

NATURE COMMUNICATIONS (2015)

Review Chemistry, Multidisciplinary

Lithium metal anodes for rechargeable batteries

Wu Xu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Article Chemistry, Multidisciplinary

Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries

Yuki Yamada et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Electrochemistry

Rechargeable batteries: challenges old and new

John B. Goodenough

JOURNAL OF SOLID STATE ELECTROCHEMISTRY (2012)

Article Chemistry, Physical

A lithium superionic conductor

Noriaki Kamaya et al.

NATURE MATERIALS (2011)