Metal-organic frameworks based single-atom catalysts for advanced fuel cells and rechargeable batteries

Article Chemistry, Multidisciplinary

One Step Synthesis of Ultrathin Carbon Nanoribbons from Metal-Organic Framework Nanorods for Oxygen Reduction and Zinc Air Batteries

Lianli Zou et al.

Summary: In this study, ultrathin carbon nanoribbons (CNRibs) were synthesized via a one-step pyrolysis process, providing an efficient method to fabricate low-dimensional nanomaterials with controllable morphologies and functionalities.

CCS CHEMISTRY (2022)

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Review Chemistry, Multidisciplinary

A Review of Heteroatom Doped Materials for Advanced Lithium-Sulfur Batteries

Jianli Wang et al.

Summary: Lithium sulfur batteries, with high theoretical capacity and energy density, face challenges such as poor conductivity of active sulfur, large volume expansion of cathode, and shuttle effect of lithium polysulfides. Heteroatom doping is proposed to manipulate the electronic structure and improve the performance of sulfur host materials for enhanced cell performance.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Distinct Crystal-Facet-Dependent Behaviors for Single-Atom Palladium-On-Ceria Catalysts: Enhanced Stabilization and Catalytic Properties

Botao Hu et al.

Summary: This study investigates the evolution of Pd species on different crystal facets of CeO2 and discovers vastly different behaviors on the single-atomic dispersion of surface Pd atoms. The findings demonstrate the crucial role of crystal-facet effects in the preparation of metal-atom-on-metal-oxide SACs, and provide insights for the rational design and targeted synthesis of ultrastable and sinter-resistant SACs.

ADVANCED MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Alternate Storage of Opposite Charges in Multisites for High-Energy-Density Al-MOF Batteries

Yuxi Guo et al.

Summary: This study proposes a new mechanism for utilizing active sites in aluminum-metal organic framework batteries, resulting in increased capacity and energy density. By using bipolar ligands and high-density active sites, the researchers were able to achieve higher reversible capacity and energy density in the battery.

ADVANCED MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Preconstructing Asymmetric Interface in Air Cathodes for High-Performance Rechargeable Zn-Air Batteries

Jia-Ning Liu et al.

Summary: A strategy of asymmetric interface preconstruction is proposed to fabricate asymmetric air cathodes for high-performance rechargeable zinc-air batteries. The asymmetric interface is preconstructed by introducing immiscible organic-water diphases within the air cathode, at which the electrocatalysts are in situ formed to achieve an asymmetric configuration. The as-fabricated asymmetric air cathodes realize high working rates and long cycling stability.

ADVANCED MATERIALS (2022)

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Article Chemistry, Multidisciplinary

MOF Encapsulating N-Heterocyclic Carbene-Ligated Copper Single-Atom Site Catalyst towards Efficient Methane Electrosynthesis

Shenghua Chen et al.

Summary: This study introduces an efficient CO2RR electrocatalyst with NHC-coordinated Cu SAS embedded in MOF, which exhibits high CH4 FE and TOF, attributed to the σ donation of NHC and the porosity of the catalyst.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Physical

In situ produced Co9S8 nanoclusters/Co/Mn-S, N multi-doped 3D porous carbon derived from eriochrome black T as an effective bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries

Rui-Min Sun et al.

Summary: The study presents a method for preparing a high-efficiency, low-cost, and stable non-noble metal catalyst on the air cathode by implanting Co9S8 nanoclusters in porous carbon. The catalyst exhibits effective oxygen reduction and evolution reaction catalysis, outperforming commercial catalysts. This research provides guidance for developing bifunctional oxygen electrocatalysts in energy conversion and storage devices.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Chemistry, Physical

Pyrrolic N wrapping strategy to maximize the number of single-atomic Fe-Nx sites for oxygen reduction reaction

Gil-Seong Kang et al.

Summary: This study developed a strategy to increase the number of Fe-N-x active sites in Fe-N-C catalysts by enhancing the electrostatic interactions. By dispersing pyrrolic N-rich carbon (pNC) on the surface of a metal-organic framework (MOF), the number of active sites on the derived hollow carbon framework dramatically increased. The synthesized catalysts were applied in an anion exchange membrane fuel cell (AEMFC) and exhibited satisfactory performance in terms of current density and power density.

JOURNAL OF POWER SOURCES (2022)

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Article Materials Science, Multidisciplinary

An in-situ TEM characterization of electron beam induced dislocation motion in a single-crystalline gold thin film

Chi Xu et al.

Summary: The study observed in-situ dislocation motions in a single-crystalline gold thinfoil specimen driven by electron-beam illumination. Two types of dislocation motions were identified, with one leaving clear traces and the other leaving passage traces. The motions exhibit jerky behaviors and accelerate with increased beam intensity, leaving immobile trace structures identified as twin structures along the <111> crystal directions.

MATERIALS CHARACTERIZATION (2022)

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Article Energy & Fuels

High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes

Laidong Zhou et al.

Summary: A series of new lithium mixed-metal chlorospinels are reported as solid electrolytes for all-solid-state lithium batteries, which exhibit high ionic conductivity and low electronic conductivity, showing potential for high-performance all-solid-state lithium batteries.

NATURE ENERGY (2022)

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Article Chemistry, Physical

Elucidating the underlying surface chemistry of Sn/Al2O3 catalysts during the propane dehydrogenation in the presence of H2S co-feed

Lohit Sharma et al.

Summary: Initiated by incipient wetness impregnation, dispersed tin atoms were deposited on gamma-Al2O3. Various characterization techniques were used to analyze the morphology and structure of the catalysts, revealing isolated and well-dispersed Sn oxide sites at relatively high coverages. The study suggests that active catalytic sites during propane dehydrogenation involve Al2O3 rather than bulk sulfide and Sn atoms dispersed over alumina.

APPLIED SURFACE SCIENCE (2022)

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Review Chemistry, Multidisciplinary

Advances in the Development of Single-Atom Catalysts for High-Energy-Density Lithium-Sulfur Batteries

Ziwei Liang et al.

Summary: The practical applications of lithium-sulfur batteries face limitations due to issues like lithium dendrite growth and polysulfide shuttling, but these hurdles can be mitigated by using single-atom catalysts (SACs) to enhance electrode materials performance. This review systematically summarizes recent progress in SACs for Li-metal anodes, S cathodes, and separators, highlighting their potential to improve energy-storage devices.

ADVANCED MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Zero-Strain High-Capacity Silicon/Carbon Anode Enabled by a MOF-Derived Space-Confined Single-Atom Catalytic Strategy for Lithium-Ion Batteries

Bingjie Chen et al.

Summary: This study reports a new composite material with zero-strain property, consisting of ultrasmall Si nanodots within metal organic framework-derived nanoreactors. The material exhibits low strain, high theoretical lithium storage capacity, superior cycling stability, and high energy density.

ADVANCED MATERIALS (2022)

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Article Chemistry, Inorganic & Nuclear

One-pot hydrothermal synthesis of a mononuclear cobalt(II) complex and an organic-inorganic supramolecular adduct: Structures, properties and hirshfeld surface analyses

Jun-Xia Li et al.

Summary: Two cobalt(II) complexes have been co-synthesized through a hydrothermal reaction. The structures and properties of the complexes have been carefully analyzed and discussed.

JOURNAL OF SOLID STATE CHEMISTRY (2022)

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Review Chemistry, Multidisciplinary

Challenge and Strategies in Room Temperature Sodium-Sulfur Batteries: A Comparison with Lithium-Sulfur Batteries

Liang Lin et al.

Summary: Metal-sulfur batteries, including sodium-sulfur (Na-S) and lithium-sulfur (Li-S) batteries, have the potential to become next-generation rechargeable batteries. Na-S batteries are more feasible for long-term development in terms of technoeconomics and geopolitics than Li-S batteries. Although Na-S systems draw inspiration from the more mature Li-S systems, the microscopic differences between the two systems present unique challenges. This review discusses these challenges and reviews strategies for Na-S batteries, providing important insights for accelerating the development of Na-S batteries based on their dissimilarities.

SMALL (2022)

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Article Chemistry, Applied

The regulation of coordination structure between cobalt and nitrogen on graphene for efficient bifunctional electrocatalysis in Zn-air batteries

Xinxin Shu et al.

Summary: The coordination structure of cobalt with nitrogen atoms on reduced graphene oxide (rGO) sheets was successfully regulated by a bridging strategy involving interfacial complexation and thermal treatment. The well-dispersed cobalt-nitrogen coordination structure on rGO enables efficient oxygen reduction and evolution reactions, leading to the excellent performance of the fabricated Zn-air battery in terms of power density and long-term stability.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Physical

Single-atom catalysts for next-generation rechargeable batteries and fuel cells

Syed Shoaib Ahmad Shah et al.

Summary: The worldwide emission of greenhouse gases has sparked increased research interest in sustainable energy conversion and storage devices. Single-atom catalysts (SACs) as electrode materials have shown potential and play a role in solving the bottleneck problems of next-generation energy storage systems.

ENERGY STORAGE MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Regulating Lithium Salt to Inhibit Surface Gelation on an Electrocatalyst for High-Energy-Density Lithium-Sulfur Batteries

Xi-Yao Li et al.

Summary: This study identified that the commonly used lithium salt LiTFSI aggravates surface gelation on the MoS2 electrocatalyst. By introducing the Lewis basic salt LiI, the gelation is successfully inhibited, leading to a higher energy density in Li-S batteries.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Applied

A microporous 2D cobalt-based MOF with pyridyl sites and open metal sites for selective adsorption of CO2

Liang Qin et al.

Summary: A new microporous 2D Co-based MOF with high selectivity and adsorption capacity for CO2 has been synthesized, possibly attributed to the pyridyl sites on the ligands and open metal sites on the nodes of the framework.

MICROPOROUS AND MESOPOROUS MATERIALS (2022)

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Article Chemistry, Applied

Influence of different Fe doping strategies on modulating active sites and oxygen reduction reaction performance of Fe, N-doped carbonaceous catalysts

Yang Liu et al.

Summary: This study systematically investigates the influence of three different Fe doping strategies on the types of active sites formed and oxygen reduction reaction (ORR) performance. Fe-NC(Zn2+), synthesized through one-step pyrolysis, shows the highest Fe-N-x active sites and exhibits excellent ORR activity and stability in the entire pH range.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Cryo-EM Revealing the Origin of Excessive Capacity of the Se Cathode in Sulfide-Based All-Solid-State Li-Se Batteries

Baiyu Guo et al.

Summary: This study presents the performance of Li-Se all-solid-state batteries using a Li10Si0.3PS6.9Cl1.8 solid-state electrolyte and a Li-In anode. The Li-Se battery exhibits high reversible capacity and capacity retention at both room temperature and high temperature, making it a promising alternative to Li-S batteries.

ACS NANO (2022)

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Article Chemistry, Physical

Metal-organic framework (MOF) composites as promising materials for energy storage applications

Yi Peng et al.

Summary: Metal-organic framework (MOF) composites are considered important energy storage materials due to their high porousness, multifunction, various structures, and controllable chemical compositions, but they still face challenges and difficulties in batteries and supercapacitors.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Mesoporous N-rich Carbon with Single-Ni Atoms as a Multifunctional Sulfur Host for Li-S Batteries

Yunxiang Li et al.

Summary: In this study, a NH4Cl-assisted pyrolysis strategy is developed to fabricate highly mesoporous N-rich carbon (Ni-NC(p)) as a sulfur host for lithium-sulfur batteries. The Ni-NC(p) material exhibits favorable electron/ion transfer, high sulfur loading, and effective confinement of lithium polysulfides, resulting in improved battery performance including specific capacity, rate capability, and cycling stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Reconstruction of Highly Dense Cu-N4 Active Sites in Electrocatalytic Oxygen Reduction Characterized by Operando Synchrotron Radiation

Gengyu Xing et al.

Summary: This study presents a dual nitrogen source coordinated strategy to achieve high density Cu-N-4 SAS, which exhibits superior ORR activity and stability in alkaline media. The Cu-N-4 SAS supported on 3D N-doped carbon nanotubes/graphene structure shows promising performance in H-2/O-2 AEMFC.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Applied

Regeneration of single-atom catalysts deactivated under acid oxygen reduction reaction conditions

Chang-Xin Zhao et al.

Summary: The regeneration of single-atom catalysts, such as Fe-N-C, is feasible through a facile annealing regeneration strategy, allowing the recovered activity to surpass that of the deactivated catalyst. This pioneering approach of selfetching the surface carbon layer to expose buried single-atom sites shows promise in addressing rapid deactivation under working conditions.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Physical

Dual-functional hosts derived from metal-organic frameworks reduce dissolution of polyselenides and inhibit dendrite growth in a sodium-selenium battery

Peng Hu et al.

Summary: A novel approach using new materials for the cathode and anode of sodium-selenium batteries effectively addresses issues such as low reactivity of selenium in sodium batteries and the "shuttle effect", resulting in improved cycle stability and safety.

ENERGY STORAGE MATERIALS (2022)

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Article Chemistry, Physical

A stable anode-free Na-S full cell at room temperature

Maoning Geng et al.

Summary: This study presents the development of an anode-free Na-S full cell with extended cycling life and higher energy density. By inhibiting the production of soluble Na polysulfides and reducing the usage of Na metal, the incompatibility of FEC in Na-S batteries is overcome, achieving stable charge and discharge processes.

ENERGY STORAGE MATERIALS (2022)

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Article Chemistry, Multidisciplinary

In situ precise anchoring of Pt single atoms in spinel Mn3O4 for a highly efficient hydrogen evolution reaction

Jinxin Wei et al.

Summary: This study reports the synthesis of a Pt single atom catalyst (Pt-SA-Mn3O4) supported by a spinel Mn3O4. The strong interactions between Pt and Mn3O4 significantly modulate the electronic structures, resulting in optimized d-band center and binding strength of intermediates. This catalyst exhibits excellent performance for the hydrogen evolution reaction, outperforming traditional catalysts.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

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Article Chemistry, Physical

Presentation of gas-phase-reactant-accessible single-rhodium-atom catalysts for CO oxidation, via MOF confinement of an Anderson polyoxometalate

Qin Liu et al.

Summary: This study demonstrates that disk-like polyoxometalate clusters can be confined in a specific pore and orientation within a hierarchically porous Zr(iv)-based MOF, allowing for the isolation of each cluster and enhancing catalytic performance of single-metal-atom catalysts.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Multidisciplinary

Water vapour induced reversible switching between a 1-D coordination polymer and a 0-D aqua complex

Min Deng et al.

Summary: This article discusses the structural transformation process of a 1-D coordination polymer [Zn(3-tba)(2)], showing the formation of a nonporous form and a dimeric complex under specific conditions. Single-crystal-to-single-crystal phase changes can be achieved through heating and exposure to DMA under specific conditions.

CHEMICAL COMMUNICATIONS (2022)

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Article Electrochemistry

Surface strain-enhanced MoS2 as a high-performance cathode catalyst for lithium-sulfur batteries

Chao Yue Zhang et al.

Summary: This study proposes the use of strained MoS2 as a catalytically active sulfur host to improve the performance of lithium-sulfur batteries. The introduction of strain enhances the catalyst's ability to adsorb lithium polysulfides, accelerating its catalytic conversion and promoting lithium-ion transferability. The results show that strain engineering can significantly improve the capacity and cycling stability of the electrodes. This work not only provides a new strategy for the development of lithium-sulfur batteries, but also suggests the potential application of strain engineering in other energy storage and conversion fields.

ESCIENCE (2022)

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Article Electrochemistry

Tailoring the adsorption behavior of superoxide intermediates on nickel carbide enables high-rate Li-O2 batteries

Yun Liu et al.

Summary: This study reveals that the adsorption behaviors of superoxide species can be effectively regulated via a core-induced interfacial charge interaction. Moderate adsorption strength can enable superior rate capability in a Li-O2 battery. Operando X-ray absorption near-edge structure and surface-enhanced Raman spectroscopy provide tools to monitor in situ the evolution of the superoxide intermediates and the electronic states of the catalyst's metal sites during the discharge and charge processes, and correlate these with the surface adsorption states. The concept of tuning adsorption behavior through interfacial charge engineering could open up new opportunities to further advance the development of the Li-O2 battery and beyond.

ESCIENCE (2022)

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Review Materials Science, Multidisciplinary

Porous carbons for use in electro-Fenton and Fenton-like reactions

Zhe-lun Pan et al.

Summary: Electro-Fenton, photo-Fenton, and Fenton-like reactions are important advanced oxidation processes for waste water treatment. They have overcome the limitations of the classic Fenton reaction and received great attention in recent decades. Porous carbons play roles as catalyst carriers and adsorbents, improving the efficiency of contaminant removal. They also promote the production of hydrogen peroxide and inhibit electron/hole recombination. Recent developments in these fields are discussed.

NEW CARBON MATERIALS (2022)

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Article Electrochemistry

Sputtered MoN nanolayer as a multifunctional polysulfide catalyst for high-performance lithium-sulfur batteries

Xin-Yang Yue et al.

Summary: In this study, MoN nanolayer-decorated multilayer graphene was used as a layer material to suppress the shuttle effect of lithium polysulfides and enhance the redox kinetics in Li-S batteries. After the initial discharge process, the MoN layers break up into independent microreaction units consisting of MoN bodies and MoS2 edges, forming an in situ heterogeneous composite catalyst. The MoN bodies can trap LiPSs and enhance their redox kinetics, while the MoS2 edges weaken the mobility of LiPSs through the anchoring effect. Li-S cells using this interlayer exhibit excellent cycling stability under a high sulfur loading.

ESCIENCE (2022)

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Review Materials Science, Multidisciplinary

Single-atom catalysts supported on ordered porous materials: Synthetic strategies and applications

Kaiwen Xue et al.

Summary: Single-atom catalysts (SACs) have drawn extensive attention due to their high catalytic activity and selectivity, high utilization of metal atoms, and cost reduction. Ordered porous materials (OPMs) serve as promising carriers for stabilizing single atoms by tuning their geometric and electronic structures through interactions, enhancing the catalytic activity. The development of SACs based on OPMs such as zeolites, metal-organic frameworks, and ordered mesoporous materials has been rapidly advancing, providing opportunities and challenges for developing novel catalysts with superior catalytic performances in the future.

INFOMAT (2022)

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Review Electrochemistry

MXenes: Synthesis strategies and lithium-sulfur battery applications

Teng Zhang et al.

Summary: This review summarizes the recent advances in MXenes for lithium-sulfur batteries (LSBs), including their structural characterization, synthesis methods, and applications as cathodes, separators, and anodes. The challenges and future directions for research are also discussed.

ESCIENCE (2022)

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Article Chemistry, Multidisciplinary

Engineering d-p Orbital Hybridization in Single-Atom Metal-Embedded Three-Dimensional Electrodes for Li-S Batteries

Zhiyuan Han et al.

Summary: The study reveals that the d-p orbital hybridization between single-atom metals and sulfur species can serve as a descriptor for understanding the catalytic activity of SACs in Li-S batteries. Transition metals with lower atomic numbers, such as titanium, have been found to effectively bind lithium polysulfides and catalyze their electrochemical reaction. Single-atom metal catalysts embedded in three-dimensional electrodes prepared through a nitrogen coordination approach show high catalytic activity and low catalyst loading for improved sulfur utilization in Li-S batteries.

ADVANCED MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Single Atom Catalysts for Fuel Cells and Rechargeable Batteries: Principles, Advances, and Opportunities

Yuchao Wang et al.

Summary: This paper discusses the importance of developing efficient and robust electrochemical energy storage systems, as well as the role of single atom catalysts in improving device performance. Additionally, it summarizes the working principles and challenges of next-generation electrochemical energy storage and conversion devices.

ACS NANO (2021)

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Article Energy & Fuels

Hollow N-doped carbon sphere synthesized by MOF as superior oxygen electrocatalyst for Li-O2 batteries

Menglu He et al.

Summary: This study successfully improved the performance and stability of Li-O-2 batteries by preparing a novel hollow N-doped carbon sphere as an effective oxygen electrocatalyst. The hollow structure and N doping play crucial roles in enhancing the activity of carbon catalysts.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Semiconducting Metal-Organic Polymer Nanosheets for a Photoinvolved Li-O2 Battery under Visible Light

Qingliang Lv et al.

Summary: Li-O-2 batteries are considered as the ultimate energy storage technology with the potential to store large amounts of electrical energy. Catalytic intervention, particularly involving cobalt-tetramino-benzoquinone (Co-TABQ) nanosheets, plays a crucial role in improving the reversibility and kinetics of cathode reactions. Orbital interactions of metal ions with ligands in Co-TABQ nanosheets are critical for light harvesting and oxygen electrocatalysis in Li-O-2 batteries.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

Identification and quantification of distinct active sites in Hf-Beta zeolites for transfer hydrogenation catalysis

Blake A. Johnson et al.

Summary: This study developed a new method using infrared spectroscopy to reliably quantify the existence of framework Lewis acidic Hf4+ sites in Beta zeolites. The method was successfully validated in Sn-Beta and Hf-Beta zeolites, providing crucial data support for further research on the activity of Lewis acidic zeolites.

JOURNAL OF CATALYSIS (2021)

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Article Chemistry, Inorganic & Nuclear

Thermal desorption of trimethylphosphine (TMP) on the HY zeolite followed by FT-IR and 31P MAS NMR

Diego Rivera-Barrera et al.

Summary: Characterization of solid acid catalysts' acidic properties using trimethylphosphine as a probe molecule showed variations in type, concentration, and strength of acid with desorption temperature, providing detailed information on different acid sites and strengths. By analyzing P-31 ss-NMR chemical shifts, weak, medium, and strong acid sites were identified, demonstrating differences in acid concentrations and strengths in extra-framework aluminum species at different desorption temperatures.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids

Estefania Tiburcio et al.

Summary: Palladium single atoms can be spontaneously formed in neat benzyl alcohols and used for organic oxidation reactions without additives or solvents. By stabilizing Pd SACs within a metal-organic framework, a solid catalyst was successfully prepared and characterized.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Multidisciplinary Sciences

Sulfur-anchoring synthesis of platinum intermetallic nanoparticle catalysts for fuel cells

Cheng-Long Yang et al.

Summary: Atomically ordered intermetallic nanoparticles show promise for catalytic applications, with platinum intermetallics synthesized on porous sulfur-doped carbon supports demonstrating high activity and resistance to metal sintering. The intermetallic libraries of small nanoparticles exhibit high mass efficiency in proton-exchange-membrane fuel cells, achieving significant activity levels.

SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Single-Atom Catalysts Derived from Metal-Organic Frameworks for Electrochemical Applications

Lianli Zou et al.

Summary: This review summarizes the progress in the synthesis of MOF-derived SACs and their electrochemical applications. The synthetic approaches based on MOFs, characterization techniques for SACs, and their electrochemical applications including ORR, OER, HER, CO2RR, NRR, and other energy-related reactions are discussed. Insights into the current challenges and future prospects of this field are also briefly presented.

SMALL (2021)

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Article Multidisciplinary Sciences

Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution

Yamei Sun et al.

Summary: The research demonstrates the use of a single-atom strategy to construct high-performance electrocatalysts for hydrogen evolution reaction, showing excellent activity at all pH values and comparable performance to commercial Pt/C. Introducing single ruthenium atoms into metal-organic frameworks leads to improved binding strength for H2O and H*, enhancing HER performance.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

Metallic MoS2 Nanoflowers Decorated Graphene Nanosheet Catalytically Boosts the Volumetric Capacity and Cycle Life of Lithium-Sulfur Batteries

Zhibin Cheng et al.

Summary: This study systematically modifies FM@G material on both cathode and separator to improve the performance of lithium-sulfur batteries with high sulfur loading, achieving superior cyclability and high volumetric capacity. The electrochemical performance is comparable to or even superior to the state-of-the-art carbon-based sulfur batteries.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Polyoxometalate@Metal-Organic Framework Composites as Effective Photocatalysts

Yang Liu et al.

Summary: POM@MOF composites have been attracting attention in photocatalysis due to their enhanced performance, which benefits from the high specific surface area and long-range ordered structure of MOFs that ensure a uniform distribution of POMs and provide more active catalytic sites.

ACS CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

In Vivo Imaging and Tracking Carbon Monoxide-Releasing Molecule-3 with an NIR Fluorescent Probe

Enbo Zhou et al.

Summary: A near-infrared fluorescent probe CORM3-IR has been developed to effectively detect CORM-3 in living cells and in vivo, showing good water solubility and rapid, selective, and sensitive response to CORM-3. The probe can ratiometrically detect CORM-3 with fluorescence at 743 and 600 nm, and exhibits good NIR fluorescence bioimaging ability with low cytotoxicity, making it an effective tool for tracking and studying CORM-3 in the life system.

ACS SENSORS (2021)

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Review Nanoscience & Nanotechnology

Hydrogen production from water electrolysis: role of catalysts

Shan Wang et al.

Summary: Hydrogen is a promising substitute for fossil fuels as a clean and renewable energy source. Efficient hydrogen production is a key challenge, with catalysis and electrocatalysis playing a critical role in achieving this goal.

NANO CONVERGENCE (2021)

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Article Chemistry, Physical

O-, N-Coordinated single Mn atoms accelerating polysulfides transformation in lithium-sulfur batteries

Yanan Liu et al.

Summary: In this study, single manganese atoms implanted in oxygen and nitrogen double-doped hollow carbon sphere frameworks were prepared as electrocatalyst and anchoring sites for lithium sulfur batteries. The results demonstrated the importance of single atom in accelerating polysulfides transformation and suppressing the shuttle effect in lithium sulfur batteries, leading to enhanced cycling stability. The abundant pores in conductive carbon frameworks facilitated electrolyte diffusion and promoted dynamic protection of the cathode structure during cycling.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Boosting energy efficiency of Li-rich layered oxide cathodes by tuning oxygen redox kinetics and reversibility

Chong Yin et al.

Summary: This study focuses on the rational design of an energy-efficient Li-rich layered cathode with high energy, power density and cycling stability by tuning oxygen redox activity. The target material Li1.12Ni0.22Co0.13Mn0.52O2 shows ultra-high energy efficiency (90.6%) at 1C, high capacity (>200 mAh g(-1)) with 98.9% retention, and less than 150 mV of decay after 200 cycles. The compositional change greatly improves the oxygen redox kinetics and reversibility, leading to enhanced energy efficiency and narrowing the gap between scientific interest and practical application in oxygen-redox chemistry.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Recycling Biowaste to Synthesize Nitrogen-Doped Highly Porous Activated Carbon Scaffolds for Selenium Stuffing with Superior Electrochemical Properties

Muhammad Rashad et al.

Summary: The study focused on developing nitrogen-doped activated carbons from red onion waste and using them to synthesize selenium-carbon composites for Na-Se batteries. The composite electrodes effectively trapped polyselenides and showed good cycling performance.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Porphyrin Aerogel Catalysts for Oxygen Reduction Reaction in Anion-Exchange Membrane Fuel Cells

Noam Zion et al.

Summary: The study reports the synthesis, characterization, and utilization of heat-treated iron porphyrin aerogels as cathode catalysts in AEMFCs. The best performing aerogel reached a peak power density of 580 mW cm(-2) and a limiting current density of 2.0 A cm(-2), considered state-of-the-art for PGM-free based AEMFCs.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Energy & Fuels

Subnano-sized silicon anode via crystal growth inhibition mechanism and its application in a prototype battery pack

Jaekyung Sung et al.

Summary: Silicon-based anodes are a promising alternative to commonly used graphite anodes in commercial batteries. Researchers have developed a synthesis route for silicon anodes consisting of subnanometre-sized particles, enhancing cycling stability and Coulombic efficiency. The practical application of the fabricated energy storage system demonstrates high cycle life and calendar life retention percentages.

NATURE ENERGY (2021)

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Article Multidisciplinary Sciences

Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst

Zhen-Yu Wu et al.

Summary: The study reports a method for selectively converting nitrate to ammonia using an Fe single atom catalyst, which effectively prevents the formation of N-N coupling products while increasing the production rate of ammonia.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Applied

3D star-like atypical hybrid MOF derived single-atom catalyst boosts oxygen reduction catalysis

Lei Zhou et al.

Summary: A 3D hybrid MOF composed of cobalt doped ZIF-L and ZIF-8 was demonstrated as an advanced precursor for making Co SACs to greatly boost ORR. The newly synthesized Co-SA-N-C exhibited excellent ORR activity, outperforming commercial Pt/C and showing high performance in acidic medium.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Article Nanoscience & Nanotechnology

Vanadium Nitride Quantum Dots/Holey Graphene Matrix Boosting Adsorption and Conversion Reaction Kinetics for High-Performance Lithium-Sulfur Batteries

Fu Li et al.

Summary: The study proposed a novel solution by synthesizing VN quantum dots/holey graphene matrix to stabilize the sulfur cathode, achieving positive results in enhancing the adsorption capacity and transport pathways of the sulfur host towards lithium polysulfides and lithium sulfides. The sulfur cathode demonstrated excellent performance in various aspects, providing a feasible solution for practical utilization of shuttle-free Li-S batteries.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Single-Atom Zinc and Anionic Framework as Janus Separator Coatings for Efficient Inhibition of Lithium Dendrites and Shuttle Effect

Chun-Lei Song et al.

Summary: This study presents a Janus separator prepared with anionic metal-organic framework and single-atom zinc catalyst, which effectively inhibits the dendrite growth and shuttle effect of Li-S batteries. The results show stable cyclic performance and outstanding protection capability, making it suitable for various types of Li-S or Li-Se batteries.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

Advances in Lithium-Sulfur Batteries: From Academic Research to Commercial Viability

Yi Chen et al.

Summary: Lithium-sulfur (Li-S) batteries, with their high energy density, show great potential as an energy storage system. Significant progress has been made in the past few decades, and there are promising prospects for the future.

ADVANCED MATERIALS (2021)

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Article Chemistry, Physical

Double-layer honeycomb AlP as a promising catalyst for Li-O2 and Na-O2 batteries

Shuaiyu Yi et al.

Summary: The study investigates the potential of 2D AlP as a catalyst in nonaqueous Li-O2 and Na-O2 batteries, showing its ability to reduce the O2 dissociation barrier and minimize overpotentials, providing a promising avenue for improving battery energy efficiency.

APPLIED SURFACE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Modulating Coordination Environment of Single-Atom Catalysts and Their Proximity to Photosensitive Units for Boosting MOF Photocatalysis

Xing Ma et al.

Summary: A general and facile strategy for the construction of high-loading single-atom catalysts with a tunable coordination microenvironment has been developed based on metal-organic frameworks. The well-accessible and atomically dispersed metal sites possess close proximity to photosensitive units, greatly accelerating charge transfer and promoting photocatalysis. The optimized Ni-1-S/MOF with a unique Ni(I) microenvironment presents excellent photocatalytic H-2 production activity, surpassing other counterparts.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Multidisciplinary Sciences

Designing the next generation of proton-exchange membrane fuel cells

Kui Jiao et al.

Summary: The rapid growth of proton-exchange membrane fuel cell technology is driving the demand for clean and sustainable global energy applications. Increasing PEMFC power density is critical for commercialization, with ambitious goals set globally. Future high-power-density PEMFCs will focus on improving membrane electrode assembly components, water and thermal management, and materials.

NATURE (2021)

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Review Chemistry, Multidisciplinary

Strategies for Polysulfide Immobilization in Sulfur Cathodes for Room-Temperature Sodium-Sulfur Batteries

Jiahui Zhou et al.

Summary: Room-temperature sodium-sulfur batteries offer low cost and high energy density, but face challenges like the shuttle effect. Strategies such as physical confinement, chemical inhibition, and electrocatalysis have been employed to address the shuttle effect on sulfur electrodes. By summarizing mechanisms, clarifying remaining issues, and proposing research directions, advancements in sodium-sulfur batteries are being promoted.

SMALL (2021)

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Article Chemistry, Physical

Generating Short-Chain Sulfur Suitable for Efficient Sodium-Sulfur Batteries via Atomic Copper Sites on a N,O-Codoped Carbon Composite

Fengping Xiao et al.

Summary: A stable sulfur host with single-atom copper catalysts derived from a bimetallic Cu-Zn metal-organic framework is reported, which significantly improves the performance of sulfur-loaded carbon framework used as a cathode in sodium-sulfur batteries, exhibiting superior capacity and rate performance.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Applied

Multiscale structural engineering of atomically dispersed FeN4 electrocatalyst for proton exchange membrane fuel cells

Ruguang Wang et al.

Summary: The 3D metal-organic frameworks-derived Fe-N-C single-atom catalyst reported in this study enhances the site density of active Fe-N-4 moiety and facilitates mass transport, leading to excellent performance in the oxygen reduction reaction in proton exchange membrane fuel cells.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Review Chemistry, Multidisciplinary

Recent Insights on Catalyst Layers for Anion Exchange Membrane Fuel Cells

Junfeng Zhang et al.

Summary: The performance of anion exchange membrane fuel cells has significantly improved in the last decade, now comparable with proton exchange membrane fuel cells. Issues in the catalyst layer play important roles in performance, and the anion exchange ionomer is crucial in maximizing the utilization of electrocatalyst and fuel/oxygen transfer process.

ADVANCED SCIENCE (2021)

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Article Energy & Fuels

High-performing commercial Fe-N-C cathode electrocatalyst for anion-exchange membrane fuel cells

Horie Adabi et al.

Summary: This study presents a high-performing commercial oxygen reduction catalyst that can replace platinum group metal catalysts, resulting in improved performance and reduced cost for anion-exchange membrane fuel cells.

NATURE ENERGY (2021)

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Article Chemistry, Multidisciplinary

A pH-universal ORR catalyst with single-atom iron sites derived from a double-layer MOF for superior flexible quasi-solid-state rechargeable Zn-air batteries

Meiqi Zhao et al.

Summary: The Fe-1/d-CN catalyst demonstrates excellent ORR activity across different pH ranges, surpassing almost all reported non-noble electrocatalysts and commercial Pt/C catalyst. Its exceptional performance can be attributed to the regulation of Fe centers' electronic structure and remarkable electron/proton transport capability derived from defects and porous features. Moreover, the catalyst shows remarkable durability and performs well in quasi-solid-state Zn-air batteries, displaying high OCV and power density.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Electrochemistry

Promoting the sulfur redox kinetics by mixed organodiselenides in high-energy-density lithium-sulfur batteries

Meng Zhao et al.

Summary: The study introduces a mixed organodiselenides promoter to enhance the sulfur redox kinetics in lithium-sulfur batteries. This promoter enables high discharge capacity, energy density, and stability under practical working conditions, showcasing the potential for constructing high-energy-density Li-S batteries with improved performance.

ESCIENCE (2021)

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Article Chemistry, Physical

A MOF-derived carbon host associated with Fe and Co single atoms for Li-Se batteries

Yuqing Cao et al.

Summary: In this study, a hierarchical porous carbon cathode with binuclear single-atom sites FeN4 and Co2N3 with a PDA shell (APPC/Se@PDA) was prepared for Li-Se batteries, showing excellent performance at high current densities. This novel strategy broadens the future research of Li-Se batteries and further applications of non-noble metal single atoms.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Multidisciplinary

Metal-organic frameworks as photoluminescent biosensing platforms: mechanisms and applications

Yifang Zhao et al.

Summary: Biosensing plays a crucial role in monitoring abnormalities in biological systems and advancing public health, with MOF materials offering immense feasibility in the construction of biosensing platforms.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Multidisciplinary

Single-atom catalysts for high-energy rechargeable batteries

Hao Tian et al.

Summary: This perspective paper summarizes recent advances in synthesis methods for single-atom catalysts (SACs) and highlights their applications in a new generation of rechargeable batteries. SACs have garnered extensive attention due to their maximum atom utilization efficiency, homogeneous active centers, and unique reaction mechanisms.

CHEMICAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Transition metal-based bimetallic MOFs and MOF-derived catalysts for electrochemical oxygen evolution reaction

Songsong Li et al.

Summary: Transition metal-based bimetallic MOFs show superior performance and stability in the oxygen evolution reaction, offering potential for enhancing efficiency in clean-energy production and energy storage. They can also serve as precursors for obtaining high surface area carbon materials or metal compounds, thereby improving catalytic activity.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Physical

A review of rechargeable aprotic lithium-oxygen batteries based on theoretical and computational investigations

Shengqi Ding et al.

Summary: Rechargeable lithium-oxygen (Li-O-2) batteries have attracted attention for their high theoretical energy density, but their practical performance is lower than expected due to the nature of discharge product Li2O2 and the high activity of the superoxide intermediate. Theoretical calculations and computational simulations have greatly contributed to understanding the reaction mechanisms and designing efficient materials for aprotic Li-O-2 batteries, highlighting the importance of further research in this area.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Hierarchically Ordered Porous Carbon with Atomically Dispersed FeN4 for Ultraefficient Oxygen Reduction Reaction in Proton-Exchange Membrane Fuel Cells

Mengfei Qiao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Nanoscience & Nanotechnology

Metal-Organic Framework Derived CoS2 Wrapped with Nitrogen-Doped Carbon for Enhanced Lithium/Sodium Storage Performance

Fengping Xiao et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

In Batteria Electrochemical Polymerization to Form a Protective Conducting Layer on Se/C Cathodes for High-Performance Li-Se Batteries

Seungmin Lee et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Single Atom Array Mimic on Ultrathin MOF Nanosheets Boosts the Safety and Life of Lithium-Sulfur Batteries

Yiju Li et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Space-Confined Atomic Clusters Catalyze Superassembly of Silicon Nanodots within Carbon Frameworks for Use in Lithium-Ion Batteries

Bingjie Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Physics, Applied

The preparation of Si/SiC composites by magnesium heat reduction of SiO2 aerogel and study on electrochemistry properties

Bowen Dong et al.

INTERNATIONAL JOURNAL OF MODERN PHYSICS B (2020)

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Article Chemistry, Physical

Revealing of Active Sites and Catalytic Mechanism in N-Coordinated Fe, Ni Dual-Doped Carbon with Superior Acidic Oxygen Reduction than Single-Atom Catalyst

Yaodan Zhou et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

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Article Chemistry, Multidisciplinary

Preparation of Nonprecious Metal Electrocatalysts for the Reduction of Oxygen Using a Low-Temperature Sacrificial Metal

Talha Al-Zoubi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Multidisciplinary Sciences

Self-assembled single-atom nanozyme for enhanced photodynamic therapy treatment of tumor

Dongdong Wang et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Physical

Catalytic Advantages, Challenges, and Priorities in Alkaline Membrane Fuel Cells

Horie Adabi Firouzjaie et al.

ACS CATALYSIS (2020)

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Review Chemistry, Physical

Carbon-Based Single-Atom Catalysts for Advanced Applications

Manoj B. Gawande et al.

ACS CATALYSIS (2020)

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Article Chemistry, Physical

Stabilizing Single-Atom Iron Electrocatalysts for Oxygen Reduction via Ceria Confining and Trapping

Jin-Cheng Li et al.

ACS CATALYSIS (2020)

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Review Chemistry, Physical

Molecular Design of Single-Atom Catalysts for Oxygen Reduction Reaction

Chengzhang Wan et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Ti3C2Tx MXene Nanosheets as a Robust and Conductive Tight on Si Anodes Significantly Enhance Electrochemical Lithium Storage Performance

Mengting Xia et al.

ACS NANO (2020)

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Review Chemistry, Multidisciplinary

Defect Engineering for Fuel-Cell Electrocatalysts

Wei Li et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Cobalt Single-Atom Catalysts with High Stability for Selective Dehydrogenation of Formic Acid

Xiang Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Inorganic & Nuclear

Applications of metal-organic framework-derived materials in fuel cells and metal-air batteries

Xudong Wen et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Multidisciplinary Sciences

Atomically dispersed cobalt catalyst anchored on nitrogen-doped carbon nanosheets for lithium-oxygen batteries

Peng Wang et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Physical

Engineering Local and Global Structures of Single Co Atoms for a Superior Oxygen Reduction Reaction

Xiao Hai et al.

ACS CATALYSIS (2020)

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Editorial Material Chemistry, Physical

Metal-Organic Frameworks as a Good Platform for the Fabrication of Single-Atom Catalysts

Haigen Huang et al.

ACS CATALYSIS (2020)

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Article Chemistry, Physical

Sequential Synthesis and Active-Site Coordination Principle of Precious Metal Single-Atom Catalysts for Oxygen Reduction Reaction and PEM Fuel Cells

Qingtao Liu et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

In Situ Phosphatizing of Triphenylphosphine Encapsulated within Metal-Organic Frameworks to Design Atomic Co1-P1N3 Interfacial Structure for Promoting Catalytic Performance

Jiawei Wan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Nanoscience & Nanotechnology

Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation

Yu Xiong et al.

NATURE NANOTECHNOLOGY (2020)

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Article Chemistry, Multidisciplinary

Dodecahedral Au/Pt Nanobowls as Robust Plasmonic Electrocatalysts for Methanol Oxidation under Visible-Light Illumination

Xiaoxiao Xu et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Article Chemistry, Physical

Cobalt single atoms supported on N-doped carbon as an active and resilient sulfur host for lithium-sulfur batteries

Yijuan Li et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Single Cobalt Sites Dispersed in Hierarchically Porous Nanofiber Networks for Durable and High-Power PGM-Free Cathodes in Fuel Cells

Yanghua He et al.

ADVANCED MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Single-Atom Catalysts across the Periodic Table

Selina K. Kaiser et al.

CHEMICAL REVIEWS (2020)

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Article Multidisciplinary Sciences

Nanocasting SiO2 into metal-organic frameworks imparts dual protection to high-loading Fe single-atom electrocatalysts

Long Jiao et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Physical

Dual-Functional Atomic Zinc Decorated Hollow Carbon Nanoreactors for Kinetically Accelerated Polysulfides Conversion and Dendrite Free Lithium Sulfur Batteries

Haodong Shi et al.

ADVANCED ENERGY MATERIALS (2020)

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Review Materials Science, Multidisciplinary

Recent progress on the design of hollow carbon spheres to host sulfur in room-temperature sodium-sulfur batteries

Jia-ying Yang et al.

NEW CARBON MATERIALS (2020)

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Correction Multidisciplinary Sciences

High-power lithium-selenium batteries enabled by atomic cobalt electrocatalyst in hollow carbon cathode (vol 11, 5025, 2020)

Hao Tian et al.

NATURE COMMUNICATIONS (2020)

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Review Chemistry, Physical

Recent Advances in the Development of Single-Atom Catalysts for Oxygen Electrocatalysis and Zinc-Air Batteries

Lishan Peng et al.

ADVANCED ENERGY MATERIALS (2020)

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Review Chemistry, Multidisciplinary

From metal-organic frameworks to single/dual-atom and cluster metal catalysts for energy applications

Chun-Chao Hou et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Article Electrochemistry

Perspective-The Next Decade of AEMFCs: Near-Term Targets to Accelerate Applied R&D

Simon T. Thompson et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Establishing reactivity descriptors for platinum group metal (PGM)-free Fe-N-C catalysts for PEM fuel cells

Mathias Primbs et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Gas phase synthesis of amorphous silicon nitride nanoparticles for high-energy LIBs

Sujong Chae et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Article Chemistry, Physical

Inverse and highly selective separation of CO2/C2H2on a thulium-organic framework

Deyun Ma et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Iron single-atom catalyst anchored on nitrogen-rich MOF-derived carbon nanocage to accelerate polysulfide redox conversion for lithium sulfur batteries

Cunguo Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Synergistic effect between atomically dispersed Fe and Co metal sites for enhanced oxygen reduction reaction

Lulu Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

Generation of Nanoparticle, Atomic-Cluster, and Single-Atom Cobalt Catalysts from Zeolitic Imidazole Frameworks by Spatial Isolation and Their Use in Zinc-Air Batteries

Xiaopeng Han et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Ultrahigh-Loading Zinc Single-Atom Catalyst for Highly Efficient Oxygen Reduction in Both Acidic and Alkaline Media

Jia Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

A Single-Atom Nanozyme for Wound Disinfection Applications

Bolong Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Cobalt in Nitrogen-Doped Graphene as Single-Atom Catalyst for High-Sulfur Content Lithium-Sulfur Batteries

Zhenzhen Du et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal-Organic Framework

Ali M. Abdel-Mageed et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Physical

Stabilizing High Metal Loadings of Thermally Stable Platinum Single Atoms on an Industrial Catalyst Support

Deepak Kunwar et al.

ACS CATALYSIS (2019)

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Article Chemistry, Physical

In Situ/Operando Techniques for Characterization of Single-Atom Catalysts

Xuning Li et al.

ACS CATALYSIS (2019)

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Article Chemistry, Physical

Atomic Fe-Doped MOF-Derived Carbon Polyhedrons with High Active-Center Density and Ultra-High Performance toward PEM Fuel Cells

Yijie Deng et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Nature-Inspired Tri-Pathway Design Enabling High-Performance Flexible Li-O2 Batteries

Chaoji Chen et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Increase of Co 3d projected electronic density of states in AgCoO2 enabled an efficient electrocatalyst toward oxygen evolution reaction

Ruirui Zhang et al.

NANO ENERGY (2019)

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Review Chemistry, Multidisciplinary

Metal-Organic-Framework-Based Single-Atom Catalysts for Energy Applications

Long Jiao et al.

CHEM (2019)

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Article Chemistry, Multidisciplinary

Engineering Fe-Fe3C@Fe-N-C Active Sites and Hybrid Structures from Dual Metal-Organic Frameworks for Oxygen Reduction Reaction in H2-O2 Fuel Cell and Li-O2 Battery

Hao Wang et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Chemistry, Multidisciplinary

A Single-Atom Iridium Heterogeneous Catalyst in Oxygen Reduction Reaction

Meiling Xiao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Ultrathin Metal-Organic Framework Nanosheets with Ultrahigh Loading of Single Pt Atoms for Efficient Visible-Light-Driven Photocatalytic H2 Evolution

Quan Zuo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Co Nanoislands Rooted on Co-N-C Nanosheets as Efficient Oxygen Electrocatalyst for Zn-Air Batteries

Peng Yu et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Redox-Inert Fe3+ Ions in Octahedral Sites of Co-Fe Spinel Oxides with Enhanced Oxygen Catalytic Activity for Rechargeable Zinc-Air Batteries

Xiao-Tong Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Single-Atom Cr-N4 Sites Designed for Durable Oxygen Reduction Catalysis in Acid Media

Ergui Luo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Two-Step Carbothermal Welding To Access Atomically Dispersed Pd1 on Three-Dimensional Zirconia Nanonet for Direct Indole Synthesis

Yafei Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Editorial Material Chemistry, Physical

Catalysts for fuel cell transportation and hydrogen related uses

Bryan Pivovar

NATURE CATALYSIS (2019)

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Article Chemistry, Multidisciplinary

Boosting Performance of Na-S Batteries Using Sulfur-Doped Ti3C2Tx MXene Nanosheets with a Strong Affinity to Sodium Polysulfides

Weizhai Bao et al.

ACS NANO (2019)

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Review Chemistry, Physical

Recent Advances in Cathode Materials for Room-Temperature Sodium-Sulfur Batteries

Dezhong Liu et al.

CHEMPHYSCHEM (2019)

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Article Nanoscience & Nanotechnology

High temperature shockwave stabilized single atoms

Yonggang Yao et al.

NATURE NANOTECHNOLOGY (2019)

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Article Chemistry, Multidisciplinary

Tuning the Gate-Opening Pressure in a Switching pcu Coordination Network, X-pcu-5-Zn, by Pillar-Ligand Substitution

Ai-Xin Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Bismuth Single Atoms Resulting from Transformation of Metal-Organic Frameworks and Their Use as Electrocatalysts for CO2 Reduction

Erhuan Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

Engineering Energy Level of Metal Center: Ru Single-Atom Site for Efficient and Durable Oxygen Reduction Catalysis

Meiling Xiao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Review Multidisciplinary Sciences

Energy storage: The future enabled by nanomaterials

Ekaterina Pomerantseva et al.

SCIENCE (2019)

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Article Multidisciplinary Sciences

Directly transforming copper (I) oxide bulk into isolated single-atom copper sites catalyst through gas-transport approach

Zhengkun Yang et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Recent Progress in Electrically Rechargeable Zinc-Air Batteries

Jing Fu et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

The Comparability of Pt to Pt-Ru in Catalyzing the Hydrogen Oxidation Reaction for Alkaline Polymer Electrolyte Fuel Cells Operated at 80 °C

Qihao Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Physical

Frogspawn-Coral-Like Hollow Sodium Sulfide Nanostructured Cathode for High-Rate Performance Sodium-Sulfur Batteries

Chuanlong Wang et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Multidisciplinary Sciences

Disentangling the size-dependent geometric and electronic effects of palladium nanocatalysts beyond selectivity

Hengwei Wang et al.

SCIENCE ADVANCES (2019)

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Article Microscopy

Differential electron scattering cross-sections at low electron energies: The influence of screening parameter

M. Calkovsky et al.

ULTRAMICROSCOPY (2019)

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Article Chemistry, Multidisciplinary

Single-Atom Fe-Nx-C as an Efficient Electrocatalyst for Zinc-Air Batteries

Junxing Han et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Review Chemistry, Multidisciplinary

PGM-Free Cathode Catalysts for PEM Fuel Cells: A Mini-Review on Stability Challenges

Yuyan Shao et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Fabricating Single-Atom Catalysts from Chelating Metal in Open Frameworks

Yichao Lin et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Atomically Transition Metals on Self-Supported Porous Carbon Flake Arrays as Binder-Free Air Cathode for Wearable Zinc-Air Batteries

Dongxiao Ji et al.

ADVANCED MATERIALS (2019)

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Review Chemistry, Physical

Challenges and recent progress in the design of advanced electrode materials for rechargeable Mg batteries

Yufei Zhang et al.

ENERGY STORAGE MATERIALS (2019)

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Article Chemistry, Physical

Fe-N-C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells

Xin Wan et al.

NATURE CATALYSIS (2019)

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Review Chemistry, Physical

Electrospun nanostructures for conversion type cathode (S, Se) based lithium and sodium batteries

Arvinder Singh et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

Unraveling the enzyme-like activity of heterogeneous single atom catalyst

Chao Zhao et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Highly active atomically dispersed CoN4 fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy

Yanghua He et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

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Article Chemistry, Multidisciplinary

A 3-D nanoribbon-like Pt-free oxygen reduction reaction electrocatalyst derived from waste leather for anion exchange membrane fuel cells and zinc-air batteries

Roby Soni et al.

NANOSCALE (2019)

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Article Chemistry, Physical

A phenolic resin-assisted strategy for MOF-derived hierarchical Co/N-doped carbon rhombic dodecahedra for electrocatalysis

Ming Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites

Hanguang Zhang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

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Article Chemistry, Physical

A copper single-atom catalyst towards efficient and durable oxygen reduction for fuel cells

Liting Cui et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Physical

g-C3N4 promoted MOF derived hollow carbon nanopolyhedra doped with high density/fraction of single Fe atoms as an ultra-high performance non-precious catalyst towards acidic ORR and PEM fuel cells

Yijie Deng et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER

Hao Jiang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

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Article Chemistry, Physical

Selenium Impregnated Monolithic Carbons as Free-Standing Cathodes for High Volumetric Energy Lithium and Sodium Metal Batteries

Jia Ding et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Electrochemistry

An Asymmetric-Electrolyte Zn-Air Battery with Ultrahigh Power Density and Energy Density

Pingwei Cai et al.

CHEMELECTROCHEM (2018)

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Article Nanoscience & Nanotechnology

Nitrogen-Doped Perovskite as a Bifunctional Cathode Catalyst for Rechargeable Lithium Oxygen Batteries

Jinbo Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Chemistry, Multidisciplinary

Vacuum Calcination Induced Conversion of Selenium/Carbon Wires to Tubes for High-Performance Sodium-Selenium Batteries

Xuming Yang et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Article Chemistry, Multidisciplinary

O-, N-Atoms-Coordinated Mn Cofactors within a Graphene Framework as Bioinspired Oxygen Reduction Reaction Electrocatalysts

Yang Yang et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Single Tungsten Atoms Supported on MOF-Derived N-Doped Carbon for Robust Electrochemical Hydrogen Evolution

Wenxing Chen et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Multidisciplinary

From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media

Long Jiao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Electrochemistry

Impact of carbonation processes in anion exchange membrane fuel cells

Ulrike Krewer et al.

ELECTROCHIMICA ACTA (2018)

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Progress in nanostructured (Fe or Co)/N/C non-noble metal electrocatalysts for fuel cell oxygen reduction reaction

Lei Zhang et al.

ELECTROCHIMICA ACTA (2018)

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Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs

Travis J. Omasta et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

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The critical relation between chemical stability of cations and water in anion exchange membrane fuel cells environment

Dario R. Dekel et al.

JOURNAL OF POWER SOURCES (2018)

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Review of cell performance in anion exchange membrane fuel cells

Dario R. Dekel

JOURNAL OF POWER SOURCES (2018)

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Direct observation of noble metal nanoparticles transforming to thermally stable single atoms

Shengjie Wei et al.

NATURE NANOTECHNOLOGY (2018)

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Porous Carbon-Hosted Atomically Dispersed Iron-Nitrogen Moiety as Enhanced Electrocatalysts for Oxygen Reduction Reaction in a Wide Range of pH

Shaofang Fu et al.

SMALL (2018)

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ZIF-8 with Ferrocene Encapsulated: A Promising Precursor to Single-Atom Fe Embedded Nitrogen-Doped Carbon as Highly Efficient Catalyst for Oxygen Electroreduction

Jinpeng Wang et al.

SMALL (2018)

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Evolution and stabilization of subnanometric metal species in confined space by in situ TEM

Lichen Liu et al.

NATURE COMMUNICATIONS (2018)

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Atmospheric CO2 effect on stable carbon isotope composition of terrestrial fossil archives

Vincent J. Hare et al.

NATURE COMMUNICATIONS (2018)

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Sodium and Sodium-Ion Batteries: 50 Years of Research

Claude Delmas

ADVANCED ENERGY MATERIALS (2018)

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Litchi-like porous Fe/N/C spheres with atomically dispersed FeNx promoted by sulfur as highly efficient oxygen electrocatalysts for Zn-air batteries

Qiliang Wei et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Advanced Architectures and Relatives of Air Electrodes in Zn-Air Batteries

Jing Pan et al.

ADVANCED SCIENCE (2018)

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Porous carbon supported atomic iron as electrocatalysts for acidic oxygen reduction reaction

Peiwen Yu et al.

SCIENCE BULLETIN (2018)

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Heterogeneous single-atom catalysis

Aiqin Wang et al.

NATURE REVIEWS CHEMISTRY (2018)

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Combined Electron and Structure Manipulation on Fe-Containing N-Doped Carbon Nanotubes To Boost Bifunctional Oxygen Electrocatalysis

Lei Zhao et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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InSitu Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts

Jian Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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A high-energy-density lithium-oxygen battery based on a reversible four-electron conversion to lithium oxide

C. Xia et al.

SCIENCE (2018)

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Single Co Atoms Anchored in Porous N-Doped Carbon for Efficient Zinc-Air Battery Cathodes

Wenjie Zang et al.

ACS CATALYSIS (2018)

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General Dimension-Controlled Synthesis of Hollow Carbon Embedded with Metal Singe Atoms or Core-Shell Nanoparticles for Energy Storage Applications

Xiaokai Song et al.

ADVANCED ENERGY MATERIALS (2018)

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CNT Interwoven Nitrogen and Oxygen Dual-Doped Porous Carbon Nanosheets as Free-Standing Electrodes for High-Performance Na-Se and K-Se Flexible Batteries

Yu Yao et al.

ADVANCED MATERIALS (2018)

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Coordination Network That Reversibly Switches between Two Nonporous Polymorphs and a High Surface Area Porous Phase

Ai-Xin Zhu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Ultralow-loading platinum-cobalt fuel cell catalysts derived from imidazolate frameworks

Lina Chong et al.

SCIENCE (2018)

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Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell

Yuanjun Chen et al.

NATURE COMMUNICATIONS (2018)

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Secondary building units as the turning point in the development of the reticular chemistry of MOFs

Markus J. Kalmutzki et al.

SCIENCE ADVANCES (2018)

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Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells

Jiazhan Li et al.

NATURE CATALYSIS (2018)

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Mechanistic Study of the Hydrogen Oxidation/Evolution Reaction over Bimetallic PtRu Catalysts

Jared Nash et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

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Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms

Yunteng Qu et al.

NATURE CATALYSIS (2018)

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Bimetallic Metal-Organic Frameworks as Efficient Cathode Catalysts for Li-O-2 Batteries

Su Hyun Kim et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Synchrotron-Based X-ray Absorption Fine Structures, X-ray Diffraction, and X-ray Microscopy Techniques Applied in the Study of Lithium Secondary Batteries

Weihan Li et al.

SMALL METHODS (2018)

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General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities

Huilong Fei et al.

NATURE CATALYSIS (2018)

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Recent Progress in MOF-Derived, Heteroatom-Doped Porous Carbons as Highly Efficient Electrocatalysts for Oxygen Reduction Reaction in Fuel Cells

Liu Yang et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Metal-Organic Frameworks as Platforms for Catalytic Applications

Long Jiao et al.

ADVANCED MATERIALS (2018)

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MoS2-Based All-Purpose Fibrous Electrode and Self-Powering Energy Fiber for Efficient Energy Harvesting and Storage

Jia Liang et al.

ADVANCED ENERGY MATERIALS (2017)

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Photocatalytic CO2 Reduction by Carbon-Coated Indium-Oxide Nanobelts

Yun-Xiang Pan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Catalyst Architecture for Stable Single Atom Dispersion Enables Site-Specific Spectroscopic and Reactivity Measurements of CO Adsorbed to Pt Atoms, Oxidized Pt Clusters, and Metallic Pt Clusters on TiO2

Leo DeRita et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Uncoordinated Amine Groups of Metal-Organic Frameworks to Anchor Single Ru Sites as Chemoselective Catalysts toward the Hydrogenation of Quinoline

Xin Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Improved Sodium-Ion Storage Performance of Ultrasmall Iron Selenide Nanoparticles

Feipeng Zhao et al.

NANO LETTERS (2017)

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New electrochemical energy storage systems based on metallic lithium anode-the research status, problems and challenges of lithium-sulfur, lithium-oxygen and all solid state batteries

Liangyu Li et al.

SCIENCE CHINA-CHEMISTRY (2017)

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Meta-Organic-Framework-Derived Fe-N/C Electrocatalyst with Five-Coordinated Fe-Nx), Sites for Advanced Oxygen Reduction in Acid Media

Qingxue Lai et al.

ACS CATALYSIS (2017)

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Recent Progress in Electrocatalyst for Li-O2 Batteries

Zhiwen Chang et al.

ADVANCED ENERGY MATERIALS (2017)

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Design Strategies toward Advanced MOF-Derived Electrocatalysts for Energy-Conversion Reactions

Jinlong Liu et al.

ADVANCED ENERGY MATERIALS (2017)

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An Improved Li-SeS2 Battery with High Energy Density and Long Cycle Life

Zhen Li et al.

ADVANCED ENERGY MATERIALS (2017)

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Functionalised metal-organic frameworks: a novel approach to stabilising single metal atoms

P. A. Szilagyi et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Surface functionalization of ZIF-8 with ammonium ferric citrate toward high exposure of Fe-N active sites for efficient oxygen and carbon dioxide electroreduction

Yifan Ye et al.

NANO ENERGY (2017)

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Atomically Dispersed Fe/N-Doped Hierarchical Carbon Architectures Derived from a Metal-Organic Framework Composite for Extremely Efficient Electrocatalysis

Qi-Long Zhu et al.

ACS ENERGY LETTERS (2017)

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Mesoporous Carbon@Titanium Nitride Hollow Spheres as an Efficient SeS2 Host for Advanced Li-SeS2 Batteries

Zhen Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Hollow Co3O4 Nanosphere Embedded in Carbon Arrays for Stable and Flexible Solid-State Zinc-Air Batteries

Cao Guan et al.

ADVANCED MATERIALS (2017)

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Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction

Siwei Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Metal-organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis

Qihao Yang et al.

CHEMICAL SOCIETY REVIEWS (2017)

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Zn Single Atom Catalyst for Highly Efficient Oxygen Reduction Reaction

Ping Song et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

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Recent Progress in the Design of Advanced Cathode Materials and Battery Models for High-Performance Lithium-X (X = O2, S, Se, Te, I2, Br2) Batteries

Jiantie Xu et al.

ADVANCED MATERIALS (2017)

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Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction

Yuanjun Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Graphene with Atomic-Level In-Plane Decoration of h-BN Domains for Efficient Photocatalysis

Mengzhu Li et al.

CHEMISTRY OF MATERIALS (2017)

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A novel peptide-based fluorescence chemosensor for selective imaging of hydrogen sulfide both in living cells and zebrafish

Peng Wang et al.

BIOSENSORS & BIOELECTRONICS (2017)

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Metal-organic frameworks-derived porous carbon/Co3O4 composites for rechargeable lithium-oxygen batteries

Myeong Jun Song et al.

ELECTROCHIMICA ACTA (2017)

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Postsynthetic Tuning of Metal-Organic Frameworks for Targeted Applications

Timur Islamoglu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2017)

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Nanostructured material-based biofuel cells: recent advances and future prospects

Cui-e Zhao et al.

CHEMICAL SOCIETY REVIEWS (2017)

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Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts

Peiqun Yin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Stabilizing a Platinum1 Single-Atom Catalyst on Supported Phosphomolybdic Acid without Compromising Hydrogenation Activity

Bin Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Recent Advances in Electrocatalysts for Oxygen Reduction Reaction

Minhua Shao et al.

CHEMICAL REVIEWS (2016)

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Highly efficient nonprecious metal catalysts towards oxygen reduction reaction based on three-dimensional porous carbon nanostructures

Chengzhou Zhu et al.

CHEMICAL SOCIETY REVIEWS (2016)

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Porous Materials as a Platform for Highly Uniform Single-Atom Catalysts: Tuning the Electronic Structure for the Low-Temperature Oxidation of Carbon Monoxide

Sippakorn Wannakao et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

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Tracking Rh Atoms in Zeolite HY: First Steps of Metal Cluster Formation and Influence of Metal Nuclearity on Catalysis of Ethylene Hydrogenation and Ethylene Dimerization

Dong Yang et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2016)

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Thermal Stabilization of Metal-Organic Framework-Derived Single Site Catalytic Clusters through Nanocasting

Camille D. Malonzo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Photochemical route for synthesizing atomically dispersed palladium catalysts

Pengxin Liu et al.

SCIENCE (2016)

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Advances in lithium-sulfur batteries based on multifunctional cathodes and electrolytes

Quan Pang et al.

NATURE ENERGY (2016)

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A Stable Single-Site Palladium Catalyst for Hydrogenations

Gianvito Vile et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions

Yan Jiao et al.

CHEMICAL SOCIETY REVIEWS (2015)

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Isolated Metal Active Site Concentration and Stability Control Catalytic CO2 Reduction Selectivity

John C. Matsubu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Selective hydrogenation of 1,3-butadiene on platinum-copper alloys at the single-atom limit

Felicia R. Lucci et al.

NATURE COMMUNICATIONS (2015)

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High rate and stable cycling of lithium metal anode

Jiangfeng Qian et al.

NATURE COMMUNICATIONS (2015)

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A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature

Dehui Deng et al.

SCIENCE ADVANCES (2015)

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Graphene/Graphene-Tube Nanocomposites Templated from Cage-Containing Metal-Organic Frameworks for Oxygen Reduction in Li-O2 Batteries

Qing Li et al.

ADVANCED MATERIALS (2014)

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Metal-organic framework membranes: from synthesis to separation application

Shilun Qiu et al.

CHEMICAL SOCIETY REVIEWS (2014)

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Metal-free catalysts for oxygen reduction in alkaline electrolytes: Influence of the presence of Co, Fe, Mn and Ni inclusions

Justus Masa et al.

ELECTROCHIMICA ACTA (2014)

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Recent advances in lithium-sulfur batteries

Lin Chen et al.

JOURNAL OF POWER SOURCES (2014)

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Effect of Transition Metals on the Structure and Performance of the Doped Carbon Catalysts Derived From Polyaniline and Melamine for ORR Application

Hongliang Peng et al.

ACS CATALYSIS (2014)

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Efficient and Durable Au Alloyed Pd Single-Atom Catalyst for the Ullmann Reaction of Aryl Chlorides in Water

Leilei Zhang et al.

ACS CATALYSIS (2014)

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An efficient Ag-ionomer interface for hydroxide exchange membrane fuel cells

Shuang Gu et al.

CHEMICAL COMMUNICATIONS (2013)

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Theoretical evidence for low kinetic overpotentials in Li-O2 electrochemistry

J. S. Hummelshoj et al.

JOURNAL OF CHEMICAL PHYSICS (2013)

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Vapor-Phase Metalation by Atomic Layer Deposition in a Metal-Organic Framework

Joseph E. Mondloch et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts

Anatoly I. Frenkel

CHEMICAL SOCIETY REVIEWS (2012)

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Metal organic frameworks for electrochemical applications

Adina Morozan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

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Size effect of silver nanoclusters on their catalytic activity for oxygen electro-reduction

Yizhong Lu et al.

JOURNAL OF POWER SOURCES (2012)

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Strong and Dynamic CO2 Sorption in a Flexible Porous Framework Possessing Guest Chelating Claws

Pei-Qin Liao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Electrocatalyst approaches and challenges for automotive fuel cells

Mark K. Debe

NATURE (2012)

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Li-O2 and Li-S batteries with high energy storage

Peter G. Bruce et al.

NATURE MATERIALS (2012)

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Non-Aqueous and Hybrid Li-O2 Batteries

Robert Black et al.

ADVANCED ENERGY MATERIALS (2012)

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Advanced Electron Microscopy of Metal-Support Interactions in Supported Metal Catalysts

Jingyue (Jimmy) Liu

CHEMCATCHEM (2011)

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Mesoporous α-MnO2/Pd catalyst air electrode for rechargeable lithium-air battery

Arjun Kumar Thapa et al.

JOURNAL OF POWER SOURCES (2011)

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Single-atom catalysis of CO oxidation using Pt1/FeOx

Botao Qiao et al.

NATURE CHEMISTRY (2011)

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Electrical Energy Storage for the Grid: A Battery of Choices

Bruce Dunn et al.

SCIENCE (2011)

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Can a Single Atom Serve as the Active Site in Some Heterogeneous Catalysts?

John Meurig Thomas et al.

TOPICS IN CATALYSIS (2011)

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Cross-Laboratory Experimental Study of Non-Noble-Metal Electrocatalysts for the Oxygen Reduction Reaction

Frederic Jaouen et al.

ACS APPLIED MATERIALS & INTERFACES (2009)

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Building better batteries

M. Armand et al.

NATURE (2008)

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Single-site heterogeneous catalysts

JM Thomas et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

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Article Chemistry, Multidisciplinary

Single-Atom Yttrium Engineering Janus Electrode for Rechargeable Na-S Batteries

Erhuan Zhang et al.

Summary: In this study, a novel Janus site composed of rare-earth metal yttrium (Y)-N4 unit has been introduced into a nitrogen-doped carbon host, showing promising electrochemical performance in Na-S full cells.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

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Metal-organic frameworks based single-atom catalysts for advanced fuel cells and rechargeable batteries

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