4.6 Article

In Situ Passivation of Two-Dimensional Perovskites by External Electric Field

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Low-Threshold, External-Cavity-Free Flexible Perovskite Lasers

Xuhui Cao et al.

Summary: A distinct advantage of halide perovskite semiconductors is their potential as gain media in high-performance, all-solution-processed flexible lasers. Low-threshold, external-cavity-free perovskite lasers, prepared with simple one-step spin-coating and low-temperature annealing, demonstrate excellent reproducibility and operational stability. The findings enable high-throughput, scalable fabrication of perovskite lasers for emerging applications.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Enhancement of Amplified Spontaneous Emission by Electric Field in CsPbBr3 Perovskites

Yang Li et al.

Summary: Perovskite gain materials can sustain continuous-wave lasing at room temperature. However, electrical stimulation supplementing optical has reduced gain performance in the past. In this study, researchers found that the addition of an electric field can turn on/off the amplified spontaneous emission (ASE) in a CsPbBr3 perovskite light-emitting diode (LED), and a positive bias voltage leads to a reduction in the optical ASE threshold.

NANO LETTERS (2023)

Article Optics

Gigantic suppression of recombination rate in 3D lead-halide perovskites for enhanced photodetector performance

Kwang Jin Lee et al.

Summary: Placing three-dimensional lead-halide perovskite films on hyperbolic metamaterials can significantly decrease the recombination rate and prolong the carrier lifetime. This decrease is attributed to the dominant in-plane transition dipole of the films. The insights gained from this study offer novel means to enhance the efficiency of perovskite-based optoelectronic and photonic devices.

NATURE PHOTONICS (2023)

Review Chemistry, Multidisciplinary

Recent Developments of Optoelectronic Synaptic Devices Based on Metal Halide Perovskites

Dandan Hao et al.

Summary: Massive data processing with high efficiency and low power consumption is needed for the development of artificial intelligence and information technology. The current computing systems with separated memory and processor consume a large amount of energy and have a slow running speed during massive data processing. To address this issue, the brain-inspired neuromorphic computing system has been developed, which provides hardware support for emulating biological synaptic functions and achieving highly intensive data processing with low power consumption. The optoelectronic synaptic device (OSD), as a neuromorphic device, is considered an ideal replacement for the von Neumann-based computer due to its ultrafast signal transmission, large bandwidth, low energy consumption, and wireless communication. Metal halide perovskites (MHPs), with their unique optoelectronic properties, have gained increasing attention as effective photosensitive materials in OSDs. This review introduces the recent progress on MHPs-based OSDs (MHPs-OSDs), including the structures and properties of MHPs, and the architectures and performance characteristics of MHPs-OSDs. The applications of MHPs-OSDs are also presented. Finally, the outlook and opportunities of MHPs-OSDs are discussed.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Pushing the Limit of Open-Circuit Voltage Deficit via Modifying Buried Interface in CsPbI3 Perovskite Solar Cells

Chenzhe Xu et al.

Summary: By modifying the interface molecules for CsPbI3 perovskite, the electron transfer barrier is reduced and the crystal quality is improved, resulting in a decrease of trap-assisted charge recombination and interfacial energetic loss. As a result, the devices achieve an impressive efficiency of 20.98% and a record-low V-OC deficit of 0.451 V.

ADVANCED MATERIALS (2023)

Review Materials Science, Multidisciplinary

Recent advances on two-dimensional metal halide perovskite x-ray detectors

Mingyue Han et al.

Summary: In recent years, two-dimensional metal halide perovskites have gained significant attention for radiation detection and imaging purposes due to their comparable efficiency to three-dimensional perovskites and superior stability. This review provides a comprehensive overview of the crystallographic structure, preparation methods, working principles, performance evaluation, and recent advances in two-dimensional perovskite x-ray detectors, while also highlighting the major obstacles that need to be overcome.

MATERIALS FUTURES (2023)

Article Chemistry, Multidisciplinary

Interpretation of Rubidium-Based Perovskite Recipes toward Electronic Passivation and Ion-Diffusion Mitigation

Chenzhe Xu et al.

Summary: The study utilized atomic models including grain boundaries to analyze the distribution of rubidium cations in perovskite structures, which was thoroughly identified using synchrotron-based grazing-incidence X-ray diffraction. This research sheds light on the subtle changes in Rb+ concentration and their impact on electronic defects, ion migration, and phase stability.

ADVANCED MATERIALS (2022)

Article Chemistry, Physical

2-CF3-PEAI to eliminate Pb0 traps and form a 2D perovskite layer to enhance the performance and stability of perovskite solar cells

Junjie Zhou et al.

Summary: This article discusses the design of a multifunctional trap deactivating reagent that effectively eliminates deep level metallic lead traps in perovskite optoelectronics. It shows improved device performance and stability.

NANO ENERGY (2022)

Article Optics

Ultrastable near-infrared perovskite light-emitting diodes

Bingbing Guo et al.

Summary: This study demonstrates ultrastable and efficient perovskite light-emitting diodes for near-infrared light source. The introduction of a dipolar molecular stabilizer enhances the stability by preventing phase transformation and decomposition of the perovskite.

NATURE PHOTONICS (2022)

Article Chemistry, Physical

Correlating the perovskite/polymer multi-mode reactions with deep-level traps in perovskite solar cells

Zhengjie Zhu et al.

Summary: By studying the different configurations and protonation states of amine groups in the PEI family, we discovered an in-situ protonation process that significantly reduces deep-level traps of minority carriers in p-i-n perovskite solar cells. This method can improve the power conversion efficiency of solar cells, and the cells showed no degradation in long-term testing.

JOULE (2022)

Article Multidisciplinary Sciences

Nanoscale localized contacts for high fill factors in polymer-passivated perovskite solar cells

Jun Peng et al.

Summary: This research introduces a nanopatterned electron transport layer that overcomes the trade-off between passivation quality and series resistance in traditional polymer passivation layers. Combining the nanopatterned electron transport layer with a dopant-free hole transport layer improves the efficiency and stability of perovskite solar cells.

SCIENCE (2021)

Editorial Material Nanoscience & Nanotechnology

Highly efficient perovskite LEDs

Giulia Pacchioni

NATURE REVIEWS MATERIALS (2021)

Article Chemistry, Multidisciplinary

Highly Tunable Enhancement and Switching of Nonlinear Emission from All-Inorganic Lead Halide Perovskites via Electric Field

Yan Gao et al.

Summary: In this study, a highly tunable enhancement and switching of nonlinear emission from metal halide perovskites were demonstrated using an asymmetrically biased metal-insulator-semiconductor structure. The enhancement of two-photon-pumped photoluminescence was achieved by electric-field-induced passivation/activation of Br vacancies, ranging from approximately 61.2-fold to 370.3-fold. Efficient modulation of two-photon-pumped lasing with a high on/off ratio of 67:1 was also demonstrated.

NANO LETTERS (2021)

Article Materials Science, Multidisciplinary

Elucidating the Structure and Photophysics of Layered Perovskites through Cation Fluorination

Eelco K. Tekelenburg et al.

Summary: Optoelectronic devices based on layered perovskites with fluorinated cations demonstrate improved stability and performance compared to non-fluorinated cations. This study investigates the impact of fluorination on crystal structure and photophysics, focusing on 3-fluorophenethylammonium lead iodide single crystals. The results show that the fluorinated cation leads to distortion of inorganic layers, resulting in blue-shifted absorbance and photoluminescence.

ADVANCED OPTICAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

Recent Advances in Perovskite Photodetectors for Image Sensing

Ludong Li et al.

Summary: This review provides a comprehensive overview of recent advances in metal halide perovskites for image sensing applications, including performance parameters, device types, applications of different dimensional materials, preparation methods, single-pixel imaging, and strategies for color discrimination.

SMALL (2021)

Article Materials Science, Multidisciplinary

In-Situ and Reversible Enhancement of Photoluminescence from CsPbBr3 Nanoplatelets by Electrical Bias

Ziming Wang et al.

Summary: This study demonstrates for the first time the reversible and giant enhancement of photoluminescence from inorganic halide perovskite nanoplatelets by electrical bias. The improved performance is attributed to the dynamic surface healing effect by bias-induced ion redistribution, showcasing a promising strategy for developing functional and integrated optoelectronic devices.

ADVANCED OPTICAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Thermally Assisted Rashba Splitting and Circular Photogalvanic Effect in Aqueously Synthesized 2D Dion-Jacobson Perovskite Crystals

Boxuan Zhou et al.

Summary: Through temperature- and polarization-dependent photoluminescence spectroscopy, we clarified that the giant Rashba effect originates from structural distortion, with valley polarization still preserved at high temperatures. The Rashba effect was further confirmed by the circular photogalvanic effect near the indirect bandgap.

NANO LETTERS (2021)

Article Multidisciplinary Sciences

Performance-limiting nanoscale trap clusters at grain junctions in halide perovskites

Tiarnan A. S. Doherty et al.

NATURE (2020)

Review Chemistry, Multidisciplinary

High-Efficiency Perovskite Solar Cells

Jin Young Kim et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Physical

Revealing Excitonic Phonon Coupling in (PEA)2(MA)n-1PbnI3n+1 2D Layered Perovskites

Joanna M. Urban et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

Article Multidisciplinary Sciences

Emerging photoluminescence from the dark-exciton phonon replica in monolayer WSe2

Zhipeng Li et al.

NATURE COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

From Lead Halide Perovskites to Lead-Free Metal Halide Perovskites and Perovskite Derivatives

Zewen Xiao et al.

ADVANCED MATERIALS (2019)

Review Chemistry, Multidisciplinary

Two-dimensional halide perovskite nanomaterials and heterostructures

Enzheng Shi et al.

CHEMICAL SOCIETY REVIEWS (2018)

Article Chemistry, Multidisciplinary

Direct Observation of Electron-Phonon Coupling and Slow Vibrational Relaxation in Organic-Inorganic Hybrid Perovskites

Daniel B. Straus et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Physical

Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite

Bert Conings et al.

ADVANCED ENERGY MATERIALS (2015)