Journal
POLYMERS
Volume 15, Issue 7, Pages -Publisher
MDPI
DOI: 10.3390/polym15071745
Keywords
Poly(furfuryl alcohol); furan resin; ring opening; NMR; carbonyls
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Poly(furfuryl alcohol) is a thermostable biobased thermoset that can be modified through the opening of the furan ring and derivatization. This study compares the structural differences between PFA prepared in neat conditions and PFA prepared in aqueous conditions. The results show that the aqueous PFA has a more heterogeneous structure with the presence of ketonic derivatives, while the neat PFA exhibits terminal lactones instead of aldehydes.
Poly(furfuryl alcohol) is a thermostable biobased thermoset. The polymerization of furfuryl alcohol (FA) is sensitive to a number of side reactions, mainly the opening of the furan ring into carbonyl species. Such carbonyls can be used to introduce new properties into the PFA materials through derivatization. Hence, better understanding of the furan ring opening is required to develop new applications for PFA. This article studies the structural discrepancies between a PFA prepared in neat conditions versus a PFA prepared in aqueous conditions, i.e., with more carbonyls, through NMR and MALDI ToF. Overall, the PFA prepared in water exhibited a structure more heterogeneous than the PFA prepared in neat conditions. The presence of ketonic derivatives such as enols and ketals were highlighted in the case of the aqueous PFA. In this line, the addition of water at the beginning of the polymerization stimulated the production of aldehydes by a factor two. Finally, the PFA prepared in neat conditions showed terminal lactones instead of aldehydes.
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