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Electrochemistry
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Summary: Water electrolysis technologies, especially anion exchange membrane water electrolysis, have played a significant role in hydrogen production from renewable energy. This review summarizes the recent achievements in anion exchange membrane water electrolysis, including improvements in conductivity and understanding of degradation mechanisms, as well as hot topics in electrocatalyst design. The review also discusses key factors affecting performance, challenges, opportunities, and future expectations for the development of anion exchange membrane water electrolysis devices.
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Yutong Fan et al.
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Jia Hui Chen et al.
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Zhen-Yu Wu et al.
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Iraj Moradpoor et al.
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RENEWABLE & SUSTAINABLE ENERGY REVIEWS
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Artem S. Pushkarev et al.
Summary: Low-cost anion exchange membrane (AEM) water electrolysis is a promising technology for producing green high-purity hydrogen using platinum group metal (PGM)-free catalysts. The performance of AEM electrolysis depends on different processes in the water electrolyzer and can be unraveled using electrochemical impedance spectroscopy. This study focuses on solving and quantifying the contributions to the total polarization resistance of the AEM water electrolyzer, including non-faradaic charge transfer resistance and ohmic resistance.
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Summary: A fluorination strategy is reported to create a phase-separated morphological structure in poly(aryl piperidinium) anion-exchange membranes (AEMs). The fluorinated AEMs possess high conductivity and dimensional stability, as well as excellent mechanical and chemical stability. AEMFCs using these fluorinated AEMs achieve outstanding peak power density and remain stable over extended operation.
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Haeryang Lim et al.
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Fanghui Wang et al.
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ACS APPLIED ENERGY MATERIALS
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Jinsheng Li et al.
Summary: Alkaline hydrogen-electricity energy conversion technologies, such as AEMFCs and AEMWEs, offer advantages over acidic counterparts, but face challenges in terms of AEM properties. This review examines the main obstacles of AEMs, including ion conductivity, stability, and device integration, and proposes strategies to address these challenges. The insights provided by this review can accelerate the commercialization of these promising hydrogen-electric energy conversion technologies.
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Daniela S. Falcao
Summary: Green hydrogen, produced through CO2-neutral electrolysis with renewable electricity, is gaining attention. Anion Exchange Membrane Water Electrolysis (AEMWE) is an innovative technology that combines the advantages of Proton Exchange Membrane (PEM) and alkaline electrolysis, with the potential to overcome their drawbacks. This paper addresses the development of AEMWE technology, including membrane and catalyst research, stability improvement, and alternative feeding solutions for fresh water scarcity.
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Jing Sang et al.
Summary: By synthesizing comb-shaped membranes, the well-designed structure improves ion conductivity and dimensional stability, demonstrating high efficiency in anion exchange membrane fuel cell applications.
ELECTROCHIMICA ACTA
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Yaojie Xu et al.
Summary: A series of tunable bis-pyridinium crosslinked PEEK-BiPy-x anion exchange membranes (AEMs) have been successfully prepared to improve the trade-off between ionic conductivity and alkaline stability. The PEEK-BiPy-x membranes exhibit distinct microphase separation patterns and possess adequate thermal, mechanical and dimensional stability. Among them, the PEEK-BiPy-0.5 membrane shows the highest tensile strength, IEC value, and excellent alkaline stability.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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Dengji Zhang et al.
Summary: Composite anion exchange membranes with superior conductivity are developed by cross-linking QPPO with NGO, showing low water uptake and swelling ratio, high ion conductivity and alkaline stability. The proposed composite membrane exhibits a hydroxide conductivity of 123 mS cm(-1) and retains a conductivity of 83 mS cm(-1) after immersion in KOH solution for 384 hours, outperforming pristine QPPO membrane.
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Abu Zafar Al Munsur et al.
Summary: The new hydrophilic-hydrophobic comb-type anion exchange membrane showed enhanced hydrophobicity compared to its non-fluorinated counterpart. It exhibited the highest hydroxide ion conductivity and improved mechanical properties. Its cell performance was significantly higher than other types of SEBS membranes.
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Xiaomeng Chu et al.
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Kyungwhan Min et al.
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(2022)
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Alaa Y. Faid et al.
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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
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