Understanding the Effect of Triazole on Crosslinked PPO-SEBS-Based Anion Exchange Membranes for Water Electrolysis

For anion exchange membrane water electrolysis (AEMWE), two types of anion exchange membranes (AEMs) containing crosslinked poly(phenylene oxide) (PPO) and poly(styrene ethylene butylene styrene) (SEBS) were prepared with and without triazole. The impact of triazole was carefully examined. In this work, the PPO was crosslinked with the non-aryl ether-type SEBS to take advantage of its enhanced chemical stability and phase separation under alkaline conditions. Compared to their triazole-free counterpart, the crosslinked membranes made with triazole had better hydroxide-ion conductivity because of the increased phase separation, which was confirmed by X-ray diffraction (XRD) and atomic force microscopy (AFM). Moreover, they displayed improved mechanical and alkaline stability. Under water electrolysis (WE) conditions, a triazole-containing crosslinked PPO-SEBS membrane electrode assembly (MEA) was created using IrO2 as the anode and a Pt/C catalyst as the cathode. This MEA displayed a current density of 0.7 A/cm(2) at 1.8 V, which was higher than that of the MEA created with the triazole-free counterpart. Our study indicated that the crosslinked PPO-SEBS membrane containing triazoles had improved chemo-physical and electrical capabilities for WE because of the strong hydrogen bonding between triazole and water/OH-.

Automated summary

In this study, two types of anion exchange membranes (AEMs) containing crosslinked poly(phenylene oxide) (PPO) and poly(styrene ethylene butylene styrene) (SEBS), with and without triazole, were prepared. The addition of triazole improved the hydroxide-ion conductivity and mechanical/alkaline stability of the crosslinked membranes. X-ray diffraction (XRD) and atomic force microscopy (AFM) confirmed the increased phase separation caused by the triazole. Under water electrolysis conditions, a triazole-containing crosslinked PPO-SEBS membrane electrode assembly (MEA) exhibited higher current density compared to the triazole-free counterpart, due to the strong hydrogen bonding between triazole and water/OH-.