Journal
CHEMCATCHEM
Volume 8, Issue 1, Pages 135-138Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201501116
Keywords
amines; ammonia; carbon dioxide; homogeneous catalysis; methylation
Categories
Funding
- Cluster of Excellence Tailor-Made Fuels from Biomass - Excellence Initiative by the German Federal and State Governments
- Erasmus Mundus Joint Doctorate SINCHEM [FPA 2013-0037]
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The synthesis of trimethylamine (TMA) through a multicomponent combination of ammonia with carbon dioxide and molecular hydrogen by using a homogeneous ruthenium catalyst was explored. The use of [Ru(triphos)(tmm)][triphos: 1,1,1-tris-(diphenylphosphinomethyl)ethane, tmm: trimethylene methane] together with aluminum trifluoromethanesulfonate as a co-catalyst resulted in high ammonia conversion and excellent selectivity for TMA in organic solvents. Aqueous solutions of ammonium chloride were methylated almost quantitatively to the corresponding hydrochloride salt (i.e., TMA center dot HCl) in a biphasic solvent system by using the same Ru complex without the need for any co-catalyst.
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