Unraveling the Role of Nickel Nanoparticles Functionalization in the Electronic Properties and Structural Features of 2D Black Phosphorene Exposed to Ambient Conditions

Layered black phosphorus (BP) is endowed with peculiar chemico-physical properties that make it a highly promising candidate in the field of electronics. Nevertheless, as other 2D materials with atomic scale thickness, it suffers from easy degradation under ambient conditions. Herein, it is shown that the functionalization of BP with preformed and in situ grown Ni NPs, affects the electronic properties of the material. In particular, Ni functionalization performed in situ leads to a narrowing of the average BP band gap from 1.15 to 0.95 eV and to a marked shift in the conduction band maximum from -0.33 V to -0.07 V, which, in turn, improve the ambient stability. Structural studies carried out by XAS can well distinguish the two nanohybrids and reveal that once Ni NPs are grown on BP nanosheets, a Ni-P coordinative bond is formed, featuring a short Ni-P distance of 2.27 angstrom, which is not observed when preformed Ni NPs are immobilized on BP. Comparing the XANES and EXAFS spectra of fresh and aged samples of both nanohybrids, suggests that the interaction between Ni and P atoms results in a stabilization effect exerted via a dual electronic and redox mechanism, that infers a much superior ambient stability to BP, even if the surface functionalization is far to achieve a full coverage.

Automated summary

Layered black phosphorus (BP) shows potential as an excellent candidate for electronics due to its unique chemico-physical properties. However, like other 2D materials, it easily degrades under ambient conditions. By functionalizing BP with preformed and in situ grown Ni nanoparticles, the electronic properties of the material are affected. In particular, in situ Ni functionalization narrows the average BP band gap and shifts the conduction band maximum, leading to improved ambient stability. Structural studies using XAS reveal the formation of a Ni-P coordinative bond with a short distance when Ni nanoparticles are grown on BP nanosheets.