Efficient photocatalytic degradation of organic pollutants over TiO2 nanoparticles modified with nitrogen and MoS2 under visible light irradiation

Investigate the use of visible light to improve photocatalytic degradation of organic pollutants in wastewater. Nitrogen-doped titania and molybdenum sulfide nanocomposites (NTM NCs) with different weight ratios of MoS2 (1, 2, and 3 wt.%) synthesized by a solid state method applied to the photodegradation of methylene blue(MB) under visible light irradiation. The synthesized NTM composites were characterized by SEM, TEM, XRD, FT-IR, UV-Vis, DRS and PL spectroscopy. The results showed enhanced activity of NTM hybrid nanocrystals in oxidizing MB in water under visible light irradiation compared to pure TiO2. The photocatalytic performance of NTM samples increased with MoS2 content. The results show that the photodegradation efficiency of the TiO2 compound improved from 13 to 82% in the presence of N-TiO2 and to 99% in the presence of MoS2 containing N-TiO2, which is 7.61 times higher than that of TiO2. Optical characterization results show enhanced nanocomposite absorption in the visible region with long lifetimes between e/h+ at optimal N-TiO2/MoS2 (NTM2) ratio. Reusable experiments indicated that the prepared NTM NCs photocatalysts were stable during MB photodegradation and had practical applications for environmental remediation.

Automated summary

This study investigates the use of visible light to enhance the photocatalytic degradation of organic pollutants in wastewater. Nitrogen-doped titania and molybdenum sulfide nanocomposites (NTM NCs) with varying weight ratios of MoS2 were synthesized and applied in the photodegradation of methylene blue under visible light irradiation. The results showed that the NTM hybrid nanocrystals exhibited higher activity in oxidizing methylene blue compared to pure titania, and the photocatalytic performance increased with the content of MoS2. The prepared NTM NCs photocatalysts were stable during methylene blue photodegradation and showed potential for environmental remediation.