Modified Bamboo Charcoal as a Bifunctional Material for Methylene Blue Removal

Biomass-derived raw bamboo charcoal (BC), NaOH-impregnated bamboo charcoal (BC-I), and magnetic bamboo charcoal (BC-IM) were fabricated and used as bio-adsorbents and Fenton-like catalysts for methylene blue removal. Compared to the raw biochar, a simple NaOH impregnation process significantly optimized the crystal structure, pore size distribution, and surface functional groups and increase the specific surface area from 1.4 to 63.0 m(2)/g. Further magnetization of the BC-I sample not only enhanced the surface area to 84.7 m(2)/g, but also improved the recycling convenience due to the superparamagnetism. The maximum adsorption capacity of BC, BC-I, and BC-IM for methylene blue at 328 K was 135.13, 220.26 and 497.51 mg/g, respectively. The pseudo-first-order rate constants k at 308 K for BC, BC-I, and BC-IM catalytic degradation in the presence of H2O2 were 0.198, 0.351, and 1.542 h(-1), respectively. A synergistic mechanism between adsorption and radical processes was proposed.

Automated summary

Bamboo charcoal was impregnated with NaOH and magnetized, leading to increased surface area and improved adsorption and catalytic degradation of methylene blue.