Vertically Aligned Nanowires and Quantum Dots: Promises and Results in Light Energy Harvesting

The synthesis of crystals with a high surface-to-volume ratio is essential for innovative, high-performance electronic devices and sensors. The easiest way to achieve this in integrated devices with electronic circuits is through the synthesis of high-aspect-ratio nanowires aligned vertically to the substrate surface. Such surface structuring is widely employed for the fabrication of photoanodes for solar cells, either combined with semiconducting quantum dots or metal halide perovskites. In this review, we focus on wet chemistry recipes for the growth of vertically aligned nanowires and technologies for their surface functionalization with quantum dots, highlighting the procedures that yield the best results in photoconversion efficiencies on rigid and flexible substrates. We also discuss the effectiveness of their implementation. Among the three main materials used for the fabrication of nanowire-quantum dot solar cells, ZnO is the most promising, particularly due to its piezo-phototronic effects. Techniques for functionalizing the surfaces of nanowires with quantum dots still need to be refined to be effective in covering the surface and practical to implement. The best results have been obtained from slow multi-step local drop casting. It is promising that good efficiencies have been achieved with both environmentally toxic lead-containing quantum dots and environmentally friendly zinc selenide.

Automated summary

The synthesis of crystals with a high surface-to-volume ratio is crucial for advanced electronic devices and sensors. Vertical nanowires aligned with the substrate surface are the easiest way to achieve this. Wet chemistry methods for growing aligned nanowires and functionalizing their surfaces with quantum dots have been studied, and the best results in terms of photoconversion efficiencies have been obtained through slow multi-step local drop casting. Among the materials used, ZnO shows the most promise due to its piezo-phototronic effects.