Journal
ADVANCED ENERGY MATERIALS
Volume 13, Issue 24, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202300394
Keywords
density of states; disorder; non-equilibrium; organic photovoltaics; relaxation
Ask authors/readers for more resources
The presence of strong energetic disorder in organic photovoltaics (OPVs) challenges the notion of quasi-equilibrium. Modulation electroluminescence (EL) spectroscopy reveals different frequency responses of charge transfer (CT) states on the high energy and low energy sides, providing unambiguous proof that the distribution of CT states formed by electrical injection is not in quasi-equilibrium. These findings caution against analyzing OPV cells based on reciprocity models that assume quasi-equilibrium and offer a new method to study this unusual aspect of OPV operation.
The notion of quasi-equilibrium is central to most solar cells; however, it has been questioned in organic photovoltaics (OPVs) owing to strong energetic disorder that frustrates efficient relaxation of electrons and holes within their respective density of states (DOS). Here, modulation electroluminescence (EL) spectroscopy is applied to OPVs and it is found that the frequency response of charge transfer (CT) state EL on the high energy side of the spectrum differs from that of the low energy side. This observation confirms that static disorder contributes substantially to the linewidth of the steady-state EL spectrum and is unambiguous proof that the distribution of CT states formed by electrical injection in the dark is not in quasi-equilibrium. These results emphasize the need for caution when analyzing OPV cells on the basis of reciprocity models that assume quasi-equilibrium holds, and highlight a new method to study this unusual aspect of OPV operation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available