Journal
ACS CATALYSIS
Volume 13, Issue 9, Pages 6261-6267Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.3c00959
Keywords
KEYWORDS; vinylcyclopropane; carboxylic acid; asymmetric catalysis; iridium catalyst; ring opening
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An efficient method for highly selective allylic substitution of vinylcyclopropanes using carboxylic acids via iridium catalysis has been developed, providing a high yield of synthetically useful chiral building blocks. The practical application of the products in useful transformations demonstrates its utility.
An efficient method for a highly regio-and enantioselective allylic substitution of vinylcyclopropanes using carboxylic acids as oxygen nucleophile via iridium catalysis has been developed. This represents a highly atom-economic approach for the synthesis of synthetically useful chiral building blocks in high yields. The practical utility of this method is demonstrated by the application of the products in useful transformations.
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