☆ 4.5 Article

Synthesis of Boronates with a Protoilludane Skeleton

SYNTHESIS-STUTTGART (2023)

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Diastereo- and enantioselective rhodium(iii)-catalyzed reductive cyclization of cyclohexadienone-containing 1,6-dienes

Yun-Xuan Tan et al.

Summary: This study reports a diastereo- and enantioselective rhodium(iii)-catalyzed reductive cyclization of cyclohexadienone-tethered terminal alkenes and (E)-1,2-disubstituted alkenes, resulting in cis-bicyclic products with three contiguous stereocenters in good yields and high selectivities. The kinetic resolution of the racemic precursor is also achieved efficiently, along with subgram-scale experiment, several transformations of the cyclization product, and one-pot preparation of bridged polycyclic frameworks.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary