Journal
SYNLETT
Volume -, Issue -, Pages -Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-2085-4195
Keywords
bimetallic; synergism; regioselectivity; difunctionalization; iron; titanium
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This article briefly discusses various methods for ortho difunctionalization of arenes and highlights a novel ortho-heterobimetallic arylene complex enabled by heterobimetallic synergism, which shows great potential in regioselective ortho difunctionalizations.
challenging in organic synthesis. Here, we briefly discuss various methods for ortho difunctionalization of arenes and highlight a novel ortho-heterobimetallic arylene complex enabled by heterobimetallic synergism, which shows great potential in regioselective ortho difunctionalizations. 1 Introduction 2 Distinct Reactivity of C-Fe and C-Ti Bonds 3 E/E' ODFs by Fe/Ti-Heterobimetallic Intermediate 4 Nu/E ODFs by Fe/Ti -Heterobimetallic Intermediate 5 Summary and Outlook
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