Journal
SURFACE & COATINGS TECHNOLOGY
Volume 456, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2023.129255
Keywords
Ablation resistance; Thermal stability; High temperature phase; Carbon; carbon composites; (NbC-TaC); ZrC coating
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The ablation resistance of plasma-sprayed NbC-TaC coatings on ZrC/SiC doublelayer-coated C/C composites was tested using an oxyacetylene flame. The phase composition of ZrO2-Ta2O5 systems heat-treated at 2100 degrees C was determined. The formation of a Ta-O film extended the effective ablation time of the TaC coating, and the addition of 37.5 mol% TaC produced the best ablation property.
Herein, the ablation resistance of plasma-sprayed TaC-modified NbC (NbC-TaC) coatings on ZrC/SiC doublelayer-coated C/C composites was firstly tested using an oxyacetylene flame. Next, the phase composition of ZrO2-Ta2O5 (TaO2.5) systems heat-treated at 2100 degrees C in an argon atmosphere was determined. The results demonstrated the formation of a free-standing Ta-O film that extended the effective ablation time of the TaC coating to >90 s. Among the NbC-TaC coatings, the 37.5 mol% TaC-addition produced a continuous film, achieving the best ablation property. Multi-healing behavior, comprised of interfacial, in situ, and surficial healing, further improved ablation performance. At 2100 degrees C, the solubility of TaO2.5 in ZrO2 was 15 mol%, and the stable phases were tetragonal ZrO2 and Ta with face- and body-centered cubic structures. Furthermore, the interfacial bonding conditions of the heat-treated Zr-O-Ta system and the thermal stability mechanism of ZrO2 to Ta2O5 were discussed.
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