4.8 Article

Selective and Stable CO2 Electroreduction to CH4 via Electronic Metal-Support Interaction upon Decomposition/Redeposition of MOF

Related references

Note: Only part of the references are listed.
Article Multidisciplinary Sciences

Surface charge as activity descriptors for electrochemical CO2 reduction to multi-carbon products on organic-functionalised Cu

Carina Yi Jing Lim et al.

Summary: The authors report a histidine-functionalized Cu catalyst for CO2 reduction to multi-carbon products and reveal the correlation between catalyst surface charge and catalytic performance. The histidine-functionalized Cu exhibits high and stable selectivity for multi-carbon products across a wide potential range. The results provide important insights for explaining CO2 reduction activity and discovering new catalysts.

NATURE COMMUNICATIONS (2023)

Article Nanoscience & Nanotechnology

Experimental Validation and Computational Predictions Join Forces to Map Catalytic C-H Activation in Ferrocene Metalated Porous Organic Polymers

Bishal Boro et al.

Summary: In this study, a unique metalated porous organic polymer was synthesized using a cost-effective approach, and it exhibited superior catalytic performance for low-temperature reactions in water. The polymer addressed some drawbacks of conventional catalytic systems.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Multidisciplinary

Modulation of *CHXO Adsorption to Facilitate Electrocatalytic Reduction of CO2 to CH4 over Cu-Based Catalysts

Jing Zhao et al.

Summary: This paper presents a controllable electrodeposition approach to alloying Cu with an oxophilic metal to steer the CO2 reduction reaction towards methane production. The optimized La5Cu95 electrocatalyst exhibits a high CH4 Faradaic efficiency of 64.5%, with a partial current density of 193.5 mA cm-2. The introduction of oxophilic La assists in lowering the energy barrier for *CO hydrogenation and promotes the formation of CH4.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Chemistry, Physical

Perspective on Theoretical Models for CO2 Electrochemical Reduction

Xu Zhang et al.

Summary: This perspective summarizes recent progress in simulating CO2RR, including both thermodynamic and kinetic aspects, as well as the application of machine learning for catalyst design. It highlights the importance of theoretical computations and simulations in electrochemical reduction of CO2.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

Article Chemistry, Multidisciplinary

Elucidating Reaction Pathways of the CO2 Electroreduction via Tailorable Tortuosities and Oxidation States of Cu Nanostructures

Guanyu Liu et al.

Summary: Copper-based fractal nanostructures with optimal tortuosity and oxidation state exhibit high selectivity and efficiency for electrochemical CO2 reduction, with a Faradaic efficiency of 65% toward C2+ products. The findings demonstrate the influential effects of tortuosity and oxidation state on the reaction pathways and selectivity during CO2 reduction.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

What is the Real Origin of the Activity of Fe-N-C Electrocatalysts in the O2 Reduction Reaction? Critical Roles of Coordinating Pyrrolic N and Axially Adsorbing Species

Xu Hu et al.

Summary: Through simulations, we found that coordinating pyrrolic N contributes to a higher activity than pyridinic N in the oxygen reduction reaction (ORR), and pyrrolic FeN4C exhibits the highest activity in acidic media. Meanwhile, the in situ transformation of active sites also explains the higher activity of Fe-N-C in alkaline media.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Multidisciplinary

Ultrasonic-assisted oxidation of cellulose to oxalic acid over gold nanoparticles supported on iron-oxide

Prince Nana Amaniampong et al.

Summary: The study demonstrated a base-free strategy for the selective oxidation of microcrystalline cellulose to oxalic acid using low frequency ultrasound and Au/Fe2O3 catalyst. The combination of low frequency ultrasound and catalyst led to enhanced catalytic oxidation of cellulose particles, resulting in a significant yield of oxalic acid. Density functional theory and X-ray photoelectron spectroscopy confirmed the charge transfer from Au nanoparticles to Fe2O3, forming active catalytic species for cellulose oxidation.

GREEN CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

Oxidation State and Surface Reconstruction of Cu under CO2 Reduction Conditions from In Situ X-ray Characterization

Soo Hong Lee et al.

Summary: This study demonstrates the structural evolution of Cu catalyst surfaces during the CO2RR and reveals the surface reconstruction of Cu towards (100) facets in the presence of CO2. The findings highlight the dynamic nature of Cu electrocatalysts surface during CO2RR process and the importance of in situ characterization in understanding the role of surface structure in electrocatalysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Multidisciplinary Sciences

Insights on forming N,O-coordinated Cu single-atom catalysts for electrochemical reduction CO2 to methane

Yanming Cai et al.

Summary: Single-atom catalysts are promising for catalyzing CO2 reduction to produce high value hydrocarbons, but most reactions yield CO. In this study, a low-temperature calcining process was used to fabricate a carbon-dots-based SAC which efficiently converts CO2 to methane.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

2D Copper Tetrahydroxyquinone Conductive Metal-Organic Framework for Selective CO2 Electrocatalysis at Low Overpotentials

Leily Majidi et al.

Summary: A 2D copper-based conductive MOF, Cu-THQ, exhibits excellent catalytic activity for aqueous CO2 reduction reaction (CO2RR) with low overpotentials. The material shows high CO production rate and current density at low overpotentials, making it a promising candidate for practical applications in CO2RR.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Assembly of a Metal-Organic Framework (MOF) Membrane on a Solid Electrocatalyst: Introducing Molecular-Level Control Over Heterogeneous CO2 Reduction

Subhabrata Mukhopadhyay et al.

Summary: Metal-Organic Frameworks play a crucial role in solar fuel production by enhancing electrocatalytic activity and selectivity through modulating the chemical environment. This concept can be applied to a wide range of proton-coupled electrochemical reactions, offering new means for precise manipulation of heterogeneous solar fuels systems at a molecular level.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Enhanced Electrochemical Methanation of Carbon Dioxide at the Single-Layer Hexagonal Boron Nitride/Cu Interfacial Perimeter

Shaohua Chen et al.

Summary: The study successfully improved the selectivity of CH4 and achieved efficient electrochemical conversion by designing the interface of monolayer hexagonal boron nitride/copper. Experimental and theoretical calculations both demonstrated that the h-BN/Cu interfacial perimeters provide specific chelating sites to accelerate the conversion of CO.

NANO LETTERS (2021)

Review Chemistry, Physical

Metal-support interactions in designing noble metal-based catalysts for electrochemical CO2 reduction: Recent advances and future perspectives

Zhao Li et al.

Summary: The review highlights the advantages and roles of noble metal nanomaterials as catalysts for CO2RR, focusing on different support materials interacting with noble metals and discussing the significant impact of strong metal-support interaction on CO2RR performance.

NANO RESEARCH (2021)

Review Chemistry, Multidisciplinary

Nanoengineering Metal-Organic Framework-Based Materials for Use in Electrochemical CO2 Reduction Reactions

Yingji Zhao et al.

Summary: Using metal-organic frameworks (MOFs) for electrochemical CO2 reduction reaction (CO2RR) processes has attracted considerable research attention due to their atomically dispersed active sites, large surface area, high porosity, controllable morphology, and remarkable tunability. The improvement of conductivity, introduction of active centers, and formation of carbon-based single-atom catalysts (SACs) from well-defined MOFs have been explored for the development of CO2 conversion. The review summarizes the progress on pristine MOFs, MOF hybrids, and MOF-derived carbon-based SACs for the electrocatalytic reduction of CO2, and discusses the limitations and potential improvement directions in this field of research.

SMALL (2021)

Article Chemistry, Multidisciplinary

Strong Metal-Support Interaction for 2D Materials: Application in Noble Metal/TiB2 Heterointerfaces and their Enhanced Catalytic Performance for Formic Acid Dehydrogenation

Renhong Li et al.

Summary: In the study of strong metal-support interaction (SMSI) between noble metal and 2D TiB2 supports, direct evidence of encapsulating metal nanoparticles with TiB2 overlayers to form sintering-resistant core-shell structures is reported. This newly created TiB2-based SMSI promotes catalytic activity and stability simultaneously, optimizing hydrogen production and selectivity. The theoretical and experimental results suggest that the interaction between transition metals and TiB2 overlayers plays a crucial role in creating thermally stable and catalytically active metal/support interfaces for scalable chemical and energy applications.

ADVANCED MATERIALS (2021)

Article Multidisciplinary Sciences

Electrokinetic and in situ spectroscopic investigations of CO electrochemical reduction on copper

Jing Li et al.

Summary: This study investigates the kinetics of CO reduction reaction without mass transport limitation using a gas-diffusion electrode and explores the dependence of copper surface speciation on electrolyte pH.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Manipulating Intermediates at the Au-TiO2 Interface over InP Nanopillar Array for Photoelectrochemical CO2 Reduction

Guanyu Liu et al.

Summary: The nanostructuring and interface design of InP photocathodes with Au-TiO2 interfaces can enhance photoresponse and selectivity, providing insights into the development of III-V semiconductor-based PEC systems for solar fuel generation.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Investigating the Origin of Enhanced C2+ Selectivity in Oxide-/Hydroxide-Derived Copper Electrodes during CO2 Electroreduction

Qiong Lei et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Engineering, Environmental

Enhancing the Fenton-like Catalytic Activity of nFe2O3 by MIL-53(Cu) Support: A Mechanistic Investigation

Yi Ren et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

Review Chemistry, Multidisciplinary

MOF-based materials for photo- and electrocatalytic CO2 reduction

Xiaofang Li et al.

ENERGYCHEM (2020)

Review Chemistry, Multidisciplinary

MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions

Hao-Fan Wang et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Physical

Size effects and active sites of Cu nanoparticle catalysts for CO2 electroreduction

Shangguo Liu et al.

APPLIED SURFACE SCIENCE (2019)

Review Chemistry, Multidisciplinary

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

Stephanie Nitopi et al.

CHEMICAL REVIEWS (2019)

Article Multidisciplinary Sciences

Static and dynamical isomerization of Cu38 cluster

Chuanchuan Zhang et al.

SCIENTIFIC REPORTS (2019)

Article Chemistry, Multidisciplinary

Synergistic Effect of High-Frequency Ultrasound with Cupric Oxide Catalyst Resulting in a Selectivity Switch in Glucose Oxidation under Argon

Prince N. Arnaniampong et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Metal-organic framework-derived materials for electrochemical energy applications

Zibin Liang et al.

ENERGYCHEM (2019)

Article Chemistry, Multidisciplinary

Catalysis of Cu Cluster for NO Reduction by CO: Theoretical Insight into the Reaction Mechanism

Nozomi Takagi et al.

ACS OMEGA (2019)

Article Nanoscience & Nanotechnology

Investigating the Role of Copper Oxide in Electrochemical CO2 Reduction in Real Time

Lily Mandal et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Dopant-induced electron localization drives CO2 reduction to C-2 hydrocarbons

Yansong Zhou et al.

NATURE CHEMISTRY (2018)

Article Chemistry, Physical

Synergistic Application of XPS and DFT to Investigate Metal Oxide Surface Catalysis

Quang Thang Trinh et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2018)

Article Chemistry, Multidisciplinary

Stability of Residual Oxides in Oxide-Derived Copper Catalysts for Electrochemical CO2 Reduction Investigated with 18O Labeling

Yanwei Lum et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Green & Sustainable Science & Technology

A Review of Metal- and Metal-Oxide-Based Heterogeneous Catalysts for Electroreduction of Carbon Dioxide

Guanyu Liu et al.

ADVANCED SUSTAINABLE SYSTEMS (2018)

Article Multidisciplinary Sciences

Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K

Tao Cheng et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2017)

Article Chemistry, Physical

Advanced analysis of copper X-ray photoelectron spectra

Mark C. Biesinger

SURFACE AND INTERFACE ANALYSIS (2017)

Article Multidisciplinary Sciences

Understanding trends in electrochemical carbon dioxide reduction rates

Xinyan Liu et al.

NATURE COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

Theoretical Investigations of the Electrochemical Reduction of CO on Single Metal Atoms Embedded in Graphene

Charlotte Kirk et al.

ACS CENTRAL SCIENCE (2017)

Article Chemistry, Physical

Effect of the size of Cu clusters on selectivity and activity of acetylene selective hydrogenation

Bo Zhao et al.

APPLIED CATALYSIS A-GENERAL (2017)

Article Chemistry, Multidisciplinary

Metal-Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide

Nikolay Kornienko et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Preparation of multi-walled carbon nanotube incorporated MIL-53-Cu composite metal-organic framework with enhanced methane sorption

Mansoor Anbia et al.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2013)

Article Chemistry, Physical

In Situ XRD, XPS, TEM, and TPR Study of Highly Active in CO Oxidation CuO Nanopowders

Dmitry A. Svintsitskiy et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

Article Chemistry, Applied

Synthesis of nanoporous copper terephthalate [MIL-53(Cu)] as a novel methane-storage adsorbent

Mansoor Anbia et al.

JOURNAL OF NATURAL GAS CHEMISTRY (2012)

Article Chemistry, Multidisciplinary

How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels

Andrew A. Peterson et al.

ENERGY & ENVIRONMENTAL SCIENCE (2010)

Article Chemistry, Multidisciplinary

Carbon dioxide hydrogenation on Ni(110)

Erik Vesselli et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Article Chemistry, Physical

Origin of the overpotential for oxygen reduction at a fuel-cell cathode

JK Norskov et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2004)

Article Materials Science, Multidisciplinary

Dynamical effects in the formation of magic cluster structures

F Baletto et al.

PHYSICAL REVIEW B (2004)

Article Engineering, Environmental

Production of ultrahigh purity copper using waste copper nitrate solution

JY Choi et al.

JOURNAL OF HAZARDOUS MATERIALS (2003)