4.8 Review

Chiral Materials: Progress, Applications, and Prospects

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ADVANCED MATERIALS (2021)

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Engineering Homochiral MOFs in TiO2 Nanotubes as Enantioselective Photoelectrochemical Electrode for Chiral Recognition

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Nitrogen-Doped Chiral CuO/CoO Nanofibers: An Enhanced Electrochemiluminescence Sensing Strategy for Detection of 3,4-Dihydroxy-Phenylalanine Enantiomers

Yanxia Song et al.

Summary: In this study, nitrogen-doped chiral CuO/CoO nanofibers were constructed as a new catalyst with nanozyme activity and electrochemiluminescence property, for sensitive recognition and enantioselective catalysis of L-DOPA. The D-Cys@N-CuO/CoO NFs can selectively distinguish and sensitively detect L-DOPA through electrochemiluminescence signals, providing a robust pathway for chiral discrimination and detection of chiral molecules.

ANALYTICAL CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Transfer, Amplification, Storage, and Complete Self-Recovery of Supramolecular Chirality in an Achiral Polymer System

Tengfei Miao et al.

Summary: This study demonstrates that partially cross-linked azobenzene units, in combination with the self-assembly of Azo units and terminal hydroxyl groups in polymer side chains, can fully recover the destroyed helical superstructure in an achiral nematic polymer system. The stored chiral information can trigger perfect chiral self-recovery behavior even after being destroyed by UV light, heat, and solvents, paving the way for producing novel chiroptical materials with reversible chirality from achiral sources.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Chiral Arylated Amines via C-N Coupling of Chiral Amines with Aryl Bromides Promoted by Light

Geyang Song et al.

Summary: The article introduces a method based on molecular Ni catalysis driven by light, allowing stereoretentive C-N coupling of optically active amines, amino alcohols, and amino acid esters with aryl bromides without the need for any external photosensitizer. The method is effective for a wide variety of coupling partners with functional groups sensitive to bases and nucleophiles, providing a viable alternative for accessing synthetically important chiral N-aryl amines, amino alcohols, and amino acids esters, as shown by 92 examples with up to 99% ee.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Medicinal

Inherently chiral dialkyloxy-calix[4]arene acetic acids as enantiodiscriminating additives for high-performance liquid chromatography separation of d,l-amino acids

Olga Kalchenko et al.

Summary: In this study, inherently chiral dialkyloxy-calix[4]arene acetic acids were investigated as enantiodiscriminating additives in HPLC separations, showing a significant impact on the separation of d,l-alanine and d,l-valine. The study also revealed the dependence of enantio-binding properties on the position of alkyl groups within the macrocycle, with the highest resolution and enantioselectivity achieved with the 1,2-dipropyloxy-calix[4]arene acetic acid.

CHIRALITY (2021)

Review Chemistry, Inorganic & Nuclear

Asymmetric catalysis using metal-organic frameworks

Danil N. Dybtsev et al.

Summary: Researchers summarized the progress in the area of asymmetric catalysis using metal-organic frameworks, highlighting the promising applications of homochiral MOFs in stereoselective catalysis.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Biochemical Research Methods

Anhydride-linked β-cyclodextrin-bonded silica stationary phases with enhanced chiral separation ability in liquid chromatography

Xiaoping Wang et al.

Summary: In this study, a series of excellent chiral stationary phases were developed using anhydride modified beta-cyclodextrin for enantioseparation, demonstrating good resolution and repeatability. These new CSPs show great potential for chiral separation in actual applications.

JOURNAL OF CHROMATOGRAPHY A (2021)

Article Chemistry, Analytical

Self-assembled chitosan-sodium alginate composite material for electrochemical recognition of tyrosine isomers

Hebing Pei et al.

Summary: The CS-SA chiral composite sensing material was prepared using electrostatic self-assembly method, showing specific binding capability to L-tyrosine. The combination of chitosan with sodium alginate significantly improved the efficiency of chiral recognition, providing a new approach for chitosan combination with other materials in chiral recognition applications.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

Article Engineering, Chemical

Chiral separation of fl-cyclodextrin modified graphene oxide membranes with a complete enantioseparation performance

Xiaoxiao Li et al.

Summary: The study shows that membranes modified with fl-CD-GOM based on graphene oxide can achieve high permeation flux and enantioselectivity, displaying superior enantioselectivity and significantly higher flux compared to traditional enantioseparation membranes.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Chemistry, Multidisciplinary

Packing Biomolecules into Sierpinski Triangles with Global Organizational Chirality

Chao Li et al.

Summary: The study successfully constructed a series of Sierpinski triangles with global organizational chirality through the coassembly of L-tryptophan and 1,3-bi(4-pyridyl)benzene molecules on Ag(111), with the chirality changing when L-tryptophan is replaced by D-tryptophan. Density functional theory calculations revealed that intermolecular hydrogen bonds stabilize the Sierpinski triangles at the single-molecule level.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Assembly of Chiral Cluster-Based Metal-Organic Frameworks and the Chirality Memory Effect during their Disassembly

Guocheng Deng et al.

Summary: This study demonstrates an interesting assembly disassembly strategy to obtain optically pure crystals of metal clusters, which were synthesized as racemic mixtures. The metal-organic frameworks characterized by X-ray crystallography exhibit different structural features, reflecting the effectiveness and importance of the assembly disassembly strategy in constructing chiral materials.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Spectroscopy

A dual-channel colorimetric and ratiometric fluorescence chemosensor for detection of Hg2+ion and its bioimaging applications

Palanisamy Ravichandiran et al.

Summary: A new colorimetric and ratiometric fluorescence chemosensor 4-DBS was synthesized and investigated for selective detection of Hg2+. The sensor showed a ratiometric fluorescence turn-on response towards Hg2+, making it an effective probe for bioimaging applications.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2021)

Review Chemistry, Analytical

A disposable dual-signal enantioselective electrochemical sensor based on stereogenic porous chiral carbon nanotubes hydrogel

Yang Yang et al.

Summary: A disposable dual-signal enantioselective platform was fabricated based on stereoscopic porous chiral carbon nanotubes hydrogel modified screen printed electrode for discriminating enantiomers efficiently and practically.

TALANTA (2021)

Article Chemistry, Physical

Chiral Iron(II)-Catalysts within Valinol-Grafted Metal-Organic Frameworks for Enantioselective Reduction of Ketones

Neha Antil et al.

Summary: The development of efficient and enantioselective heterogeneous catalysts based on abundant elements and inexpensive ligands is crucial for environmentally friendly and cost-effective production of optically active compounds. This study demonstrates the synthesis of chiral amino alcohol-functionalized metal-organic frameworks as highly enantioselective base-metal catalysts for asymmetric organic transformations.

ACS CATALYSIS (2021)

Article Chemistry, Physical

Chiral and robust Zr(iv)-based metal-organic frameworks built from spiro skeletons

Wei Gong et al.

Summary: Chiral metal-organic frameworks with novel topologies and pore systems were successfully synthesized using enantiopure spiro-based tetracarboxylate linkers. The exceptional chemical stability of these CMOFs towards boiling water, aqueous acid and base solutions was validated, along with their potential applications in enantioselective catalysis and separation.

FARADAY DISCUSSIONS (2021)

Article Nanoscience & Nanotechnology

Self-Assembly of Ferrocenyl Phenylalanine into Nanohelical Arrays via Kinetic Control

Jiahui Wang et al.

Summary: This study presents the construction of highly ordered bioorganometallic nanohelical arrays based on the hierarchical chiral self-assembly of ferrocenyl L-phenylalanine. The formation of nanohelical arrays is under kinetic control and can be adjusted by changing growth time and vapor temperature. The chiral nanoarrays exhibit circularly polarized luminescence and enhanced electrical capacity, showing potential applications in optics, sensing, and energy storage.

ACS APPLIED BIO MATERIALS (2021)

Article Polymer Science

Multifunctional chiral cationic porous organic polymers: gas uptake and heterogeneous asymmetric organocatalysis

Zhenwei Zhang et al.

Summary: The study obtained a series of high-performance chiral cationic porous organic polymers, which have excellent pore structure and chemical stability, and exhibit good catalytic performance as organocatalysts in reactions.

POLYMER CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Chirality transfer of cysteine to the plasmonic resonance region through silver coating of gold nanobipyramids

Ye Wang et al.

Summary: In this study, a chirality transfer of cysteine was observed from gold nanobipyramids to Ag nanoshells with increasing Ag layers, highlighting the role of free Cys in Ag nanoshells. This finding is valuable for the development of new chiral plasmonic nanomaterials with optimized asymmetric properties.

CHEMICAL COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Homochiral metal-organic frameworks for enantioseparation

Juan Liu et al.

Summary: This review delves into the chiral pocket model in homochiral metal-organic frameworks (HMOFs) as a key to understanding enantioselective separation mechanisms. The discussion is classified into two main types of chiral pockets in HMOFs, and recent conceptual advances in the design of HMOFs for high enantioseparation performance are systematically categorized and discussed.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Multidisciplinary

Supramolecular Chiral 2D Materials and Emerging Functions

Bowen Shen et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Multidisciplinary

Emerging Cubic Chirality in γCD-MOF for Fabricating Circularly Polarized Luminescent Crystalline Materials and the Size Effect

Liangyu Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Light-Induced Chiral Iron Copper Selenide Nanoparticles Prevent β-Amyloidopathy In Vivo

Hongyu Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Enzymatic degradation of plant biomass and synthetic polymers

Chun-Chi Chen et al.

NATURE REVIEWS CHEMISTRY (2020)

Article Nanoscience & Nanotechnology

Light- and Humidity-Responsive Chiral Nematic Photonic Crystal Films Based on Cellulose Nanocrystals

Huanghuang Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Applied

Origin of vacuum-assisted chiral self-assembly of cellulose nanocrystals

Zhaolu Wang et al.

CARBOHYDRATE POLYMERS (2020)

Article Chemistry, Multidisciplinary

Synthesis of Chiral MOF-74 Frameworks by Post-Synthetic Modification by Using an Amino Acid

Andreea Gheorghe et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Nanoscience & Nanotechnology

Chiral Macroporous MOF Surfaces for Electroassisted Enantioselective Adsorption and Separation

Duangkamon Suttipat et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Review Chemistry, Multidisciplinary

Chiral Nanoceramics

Jinchen Fan et al.

ADVANCED MATERIALS (2020)

Review Chemistry, Multidisciplinary

Three-Dimensional Covalent Organic Frameworks: From Topology Design to Applications

Bo Gui et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

Article Chemistry, Medicinal

Non-Covalent π-Stacking Interactions between Asphaltene and Porphyrin in Bitumen

Masoumeh Mousavi et al.

JOURNAL OF CHEMICAL INFORMATION AND MODELING (2020)

Article Chemistry, Physical

Increasing the Efficiency of Water Splitting through Spin Polarization Using Cobalt Oxide Thin Film Catalysts

Supriya Ghosh et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

Article Chemistry, Multidisciplinary

Catalytic Asymmetric Synthesis of Chiral Covalent Organic Frameworks from Prochiral Monomers for Heterogeneous Asymmetric Catalysis

Jian-Cheng Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Polymer Science

The Application of Covalent Organic Frameworks for Chiral Chemistry

Siqi Zhuo et al.

MACROMOLECULAR RAPID COMMUNICATIONS (2020)

Review Biochemistry & Molecular Biology

BODIPY- and Porphyrin-Based Sensors for Recognition of Amino Acids and Their Derivatives

Marco Farinone et al.

MOLECULES (2020)

Review Materials Science, Multidisciplinary

Chirality control of inorganic materials and metals by peptides or amino acids

Hyeohn Kim et al.

MATERIALS ADVANCES (2020)

Article Chemistry, Multidisciplinary

A chiral covalent organic framework (COF) nanozyme with ultrahigh enzymatic activity

Ya Zhou et al.

MATERIALS HORIZONS (2020)

Review Chemistry, Multidisciplinary

Chiral covalent organic frameworks: design, synthesis and property

Xing Han et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Inorganic & Nuclear

One-step electrodeposition of the MOF@CCQDs/NiF electrode for chiral recognition of tyrosine isomers

Ying Hou et al.

DALTON TRANSACTIONS (2020)

Article Nanoscience & Nanotechnology

β-Cyclodextrin-Self-Assembled Nanochannel Membrane for the Separation of Chiral Drugs

Siyun Zhang et al.

ACS APPLIED NANO MATERIALS (2020)

Article Chemistry, Inorganic & Nuclear

Synthesis of Chiral Nematic Mesoporous Metal and Metal Oxide Nanocomposites and their Use as Heterogeneous Catalysts

Christopher M. Walters et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2020)

Review Chemistry, Multidisciplinary

Covalent Organic Frameworks for Catalysis

Yusran Yusran et al.

ENERGYCHEM (2020)

Article Chemistry, Multidisciplinary

The formation of a chiral supramolecular structure acting as a template for chirality transfer

Misaki Kurata et al.

CHEMICAL COMMUNICATIONS (2020)

Review Chemistry, Multidisciplinary

Stereospecific interactions between chiral inorganic nanomaterials and biological systems

Xueli Zhao et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Multidisciplinary

Chirality induction on non-chiral dye-linked polysilsesquioxane in nanohelical structures

Naoya Ryu et al.

CHEMICAL COMMUNICATIONS (2020)

Review Multidisciplinary Sciences

Postsynthetic functionalization of covalent organic frameworks

Yusran Yusran et al.

NATIONAL SCIENCE REVIEW (2020)

Review Chemistry, Multidisciplinary

The luminescent and photophysical properties of covalent organic frameworks

W. Karl Haug et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Nanoscience & Nanotechnology

Chiral Selective Adhesion of Protein Droplets on Calix[4]arene-Enantiomer-Modified Surfaces

Yuxiao Mei et al.

ACS APPLIED BIO MATERIALS (2020)

Article Chemistry, Multidisciplinary

Chiral DHIP- and Pyrrolidine-Based Covalent Organic Frameworks for Asymmetric Catalysis

Jie Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Supramolecular Spheres Self-Assembled from Conical Dendrons Are Chiral

Daniela A. Wilson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Chiral BINOL-Based Covalent Organic Frameworks for Enantioselective Sensing

Xiaowei Wu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Helical Sulfono-γ-AApeptides with Aggregation-Induced Emission and Circularly Polarized Luminescence

Yan Shi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Homochiral Metal-Organic Frameworks for Enantioselective Separations in Liquid Chromatography

Nieves Corella-Ochoa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Synthesis, Characterization, and Electrochemical Applications of Chiral Imprinted Mesoporous Ni Surfaces

Sunpet Assavapanumat et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Transcription of Chirality from Metal-Organic Framework to Polythiophene

Takashi Kitao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Chiral Core-Shell Upconversion Nanoparticle@MOF Nanoassemblies for Quantification and Bioimaging of Reactive Oxygen Species in Vivo

Changlong Hao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Chiral Enantioselective Assemblies Induced from Achiral Porphyrin by L- and D-Lysine

Shanshan Wu et al.

LANGMUIR (2019)

Editorial Material Multidisciplinary Sciences

The structure of DNA

Georgina Ferry

NATURE (2019)

Article Chemistry, Analytical

Chiral galactose responsive S-phenethylamine calix [4] arene-based sensing surface

Xujie Zhang et al.

SENSORS AND ACTUATORS B-CHEMICAL (2019)

Article Chemistry, Inorganic & Nuclear

N-acetyl-L-cysteine modified CuFe2O4@SiO2 core-shell nanoparticles as chiral probes for recognition of chiral tyrosine

Shaokai Chen et al.

JOURNAL OF SOLID STATE CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Nanochannels of Covalent Organic Frameworks for Chiral Selective Transmembrane Transport of Amino Acids

Chen Yuan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Spectroscopy

Visual chiral recognition of D/L-leucine using cube-shaped gold nanoparticles as colorimetric probes

Xiaojuan Zhou et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2019)

Article Chemistry, Multidisciplinary

Chiral Polyaniline Hollow Nanotwists toward Efficient Enantioselective Separation of Amino Acids

Chuanqiang Zhou et al.

ACS NANO (2019)

Article Chemistry, Multidisciplinary

Investigation on the chirality mechanism of chiral carbon quantum dots derived from tryptophan

Yingying Wei et al.

RSC ADVANCES (2019)

Article Chemistry, Multidisciplinary

QCM sensors coated with calix[4]arenes bearing sensitive chiral moieties for chiral discrimination of 1-phenylethylamine enantiomers

Egemen Ozcelik et al.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY (2019)

Article Electrochemistry

Electrochemically Recognizing Tryptophan Enantiomers based on Carbon Black/Poly-l-Cysteine Modified Electrode

Odoom Jibrael Kingsford et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Chiral biomineralized structures and their biomimetic synthesis

Wenge Jiang et al.

MATERIALS HORIZONS (2019)

Review Chemistry, Multidisciplinary

Post-synthetic modification of covalent organic frameworks

Jose L. Segura et al.

CHEMICAL SOCIETY REVIEWS (2019)

Article Chemistry, Multidisciplinary

Alanine-Based Chiral Metallogels via Supramolecular Coordination Complex Platforms: Metallogelation Induced Chirality Transfer

Yue Sun et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Analytical

Chiral Sensing Platform Based on the Self-Assemblies of Diphenylalanine and Oxalic Acid

Lili Guo et al.

ANALYTICAL CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Chiral Recognition and Separation by Chirality-Enriched Metal-Organic Frameworks

Saikat Das et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Reactivity and Selectivity of Iminium Organocatalysis Improved by a Protein Host

Alexander R. Nodling et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Engineering, Chemical

Separation of D, L-amino acids using ligand exchange membranes

John J. Keating et al.

JOURNAL OF MEMBRANE SCIENCE (2018)

Article Chemistry, Multidisciplinary

Chiral 3D Covalent Organic Frameworks for High Performance Liquid Chromatographic Enantioseparation

Xing Hang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Nanoscience & Nanotechnology

Revolving supramolecular chiral structures powered by light in nanomotor-doped liquid crystals

Tetiana Orlova et al.

NATURE NANOTECHNOLOGY (2018)

Article Chemistry, Analytical

A novel electrochemical chiral sensor for tyrosine isomers based on a coordination-driven self-assembly

Yongxin Tao et al.

SENSORS AND ACTUATORS B-CHEMICAL (2018)

Article Chemistry, Multidisciplinary

Chiral Shell Core-Satellite Nanostructures for Ultrasensitive Detection of Mycotoxin

Jiarong Cai et al.

SMALL (2018)

Article Spectroscopy

Probing the stereoselective interaction of ofloxacin enantiomers with corresponding monoclonal antibodies by multiple spectrometry

Hongtao Mu et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2018)

Article Multidisciplinary Sciences

Chiral induction in covalent organic frameworks

Xing Han et al.

NATURE COMMUNICATIONS (2018)

Article Multidisciplinary Sciences

Single-molecule insights into surface-mediated homochirality in hierarchical peptide assembly

Yumin Chen et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

Macroscopic Chiral Recognition by Calix[4]arene-Based Host-Guest Interactions

Jiaxin Quan et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Article Multidisciplinary Sciences

Chiral self-sorted multifunctional supramolecular biocoordination polymers and their applications in sensors

Xiaobo Shang et al.

NATURE COMMUNICATIONS (2018)

Article Nanoscience & Nanotechnology

A DNA Origami-Based Chiral Plasmonic Sensing Device

Yike Huang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Covalent Organic Frameworks with Chirality Enriched by Biomolecules for Efficient Chiral Separation

Sainan Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Biochemical Research Methods

Enantioseparation of DPP-4 Inhibitors on Immobilized Crown Ether-Based Chiral Stationary Phase

Srinivasu Gunnam et al.

CHROMATOGRAPHIA (2018)

Article Chemistry, Multidisciplinary

Controlled Exchange of Achiral Linkers with Chiral Linkers in Zr-Based UiO-68 Metal-Organic Framework

Chunxia Tan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Materials Science, Multidisciplinary

3D graphene/hydroxypropyl-β-cyclodextrin nanocomposite as an electrochemical chiral sensor for the recognition of tryptophan enantiomers

Wenting Liang et al.

JOURNAL OF MATERIALS CHEMISTRY C (2018)

Article Pharmacology & Pharmacy

Lysine-Derived Carbon Dots for Chiral Inhibition of Prion Peptide Fibril Assembly

Elad Arad et al.

ADVANCED THERAPEUTICS (2018)

Article Chemistry, Multidisciplinary

Semiconductor Metal-Organic Frameworks: Future Low-Bandgap Materials

Muhammad Usman et al.

ADVANCED MATERIALS (2017)

Review Chemistry, Physical

Best Practices for the Synthesis, Activation, and Characterization of Metal-Organic Frameworks

Ashlee J. Howarth et al.

CHEMISTRY OF MATERIALS (2017)

Review Chemistry, Multidisciplinary

Light on Chirality: Absolute Asymmetric Formation of Chiral Molecules Relevant in Prebiotic Evolution

Iuliia Myrgorodska et al.

CHEMPLUSCHEM (2017)

Article Chemistry, Inorganic & Nuclear

The Promise of Self-Assembled 3D Supramolecular Coordination Complexes for Biomedical Applications

Angela Casini et al.

INORGANIC CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Multivariate Chiral Covalent Organic Frameworks with Controlled Crystallinity and Stability for Asymmetric Catalysis

Jie Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Chiral Covalent Organic Frameworks with High Chemical Stability for Heterogeneous Asymmetric Catalysis

Xing Han et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Biochemistry & Molecular Biology

Preparative Scale Resolution of Enantiomers Enables Accelerated Drug Discovery and Development

Hanna Leek et al.

MOLECULES (2017)

Review Multidisciplinary Sciences

Exploiting non-covalent π interactions for catalyst design

Andrew J. Neel et al.

NATURE (2017)

Editorial Material Chemistry, Multidisciplinary

Pasteur and the art of chirality

Joseph Gal

NATURE CHEMISTRY (2017)

Review Nanoscience & Nanotechnology

Transmission of chirality through space and across length scales

Sarah M. Morrow et al.

NATURE NANOTECHNOLOGY (2017)

Article Chemistry, Multidisciplinary

The construction of electrochemical chiral interfaces using hydroxypropyl chitosan

Zhenliang Li et al.

RSC ADVANCES (2017)

Article Chemistry, Multidisciplinary

Chiral Amplification by L-Cysteine-Capped Gold Nanoparticles in Lyotropic Chromonic Liquid Crystals

Leah Bergquist et al.

CHEMNANOMAT (2017)

Article Multidisciplinary Sciences

Chiral plasmonics

Mario Hentschel et al.

SCIENCE ADVANCES (2017)

Review Pharmacology & Pharmacy

The modification of natural products for medical use

Zongru Guo

ACTA PHARMACEUTICA SINICA B (2017)

Review Chemistry, Multidisciplinary

Enantiomer surface chemistry: conglomerate versus racemate formation on surfaces

Soham Dutta et al.

CHEMICAL SOCIETY REVIEWS (2017)

Article Chemistry, Inorganic & Nuclear

A pair of 3D enantiotopic zinc(II) complexes based on two asymmetric achiral ligands

Ming-Dao Zhang et al.

DALTON TRANSACTIONS (2017)

Article Chemistry, Multidisciplinary

Strong circularly polarized luminescence induced from chiral supramolecular assembly of helical nanorods

Yuxiang Wang et al.

CHEMICAL COMMUNICATIONS (2017)

Article Electrochemistry

Enantiorecognition of Tyrosine Based on a Novel Magnetic Electrochemical Chiral Sensor

Xueyan Shi et al.

ELECTROCHIMICA ACTA (2017)

Review Chemistry, Multidisciplinary

Chiral Inorganic Nanostructures

Wei Ma et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Multidisciplinary

Chiral Selective Transport of Proteins by Cysteine-Enantiomer-Modified Nanopores

Fan Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Multidisciplinary

Chiral metallosupramolecular architectures

Li-Jun Chen et al.

CHEMICAL SOCIETY REVIEWS (2017)

Article Chemistry, Multidisciplinary

Plasmonic Chirality Imprinting on Nucleobase-Displaying Supramolecular Nanohelices by Metal-Nucleobase Recognition

Yiyang Lin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Control of bulk homochirality and proton conductivity in isostructural chiral metal-organic frameworks

Bai-Qiao Song et al.

CHEMICAL COMMUNICATIONS (2017)

Article Chemistry, Analytical

Electrochemical Enantioselective Recognition in a Highly Ordered Self-Assembly Framework

Yongxin Tao et al.

ANALYTICAL CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Chiral Graphene Quantum Dots

Nozomu Suzuki et al.

ACS NANO (2016)

Review Chemistry, Multidisciplinary

Synthesis of Chiral Cyclopentenones

Svilen P. Simeonov et al.

CHEMICAL REVIEWS (2016)

Article Chemistry, Multidisciplinary

Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis

Xiuren Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Review Multidisciplinary Sciences

Unravelling biological macromolecules with cryo-electron microscopy

Rafael Fernandez-Leiro et al.

NATURE (2016)

Article Chemistry, Multidisciplinary

Molecular docking sites designed for the generation of highly crystalline covalent organic frameworks

Laura Ascherl et al.

NATURE CHEMISTRY (2016)

Article Chemistry, Physical

A new insight into π-π stacking involving remarkable orbital interactions

Rundong Zhao et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

Article Multidisciplinary Sciences

Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation

Hai-Long Qian et al.

NATURE COMMUNICATIONS (2016)

Article Multidisciplinary Sciences

L-proline: a highly effective cryoprotectant for mouse oocyte vitrification

Lu Zhang et al.

SCIENTIFIC REPORTS (2016)

Article Multidisciplinary Sciences

Molecular Recognition of Biomolecules by Chiral CdSe Quantum Dots

Maria V. Mukhina et al.

SCIENTIFIC REPORTS (2016)

Article Chemistry, Physical

Kinetically controlled ammonia vapor diffusion synthesis of a Zn(II) MOF and its H2O/NH3 adsorption properties

Yang Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

Article Biochemistry & Molecular Biology

The role of proline substitutions within flexible regions on thermostability of luciferase

Haoran Yu et al.

BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS (2015)

Article Biochemical Research Methods

Highly selective separation of enantiomers using a chiral porous organic cage

Jun-Hui Zhang et al.

JOURNAL OF CHROMATOGRAPHY A (2015)

Article Chemistry, Physical

Circularly Polarized Luminescence in Chiral Molecules and Supramolecular Assemblies

Jatish Kumar et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

Article Chemistry, Multidisciplinary

Heparin versus DNA: Chiral Preferences in Polyanion Binding to Self-Assembled Multivalent (SAMul) Nanostructures

Stephen M. Bromfield et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Symmetry Breaking in the Supramolecular Gels of an Achiral Gelator Exclusively Driven by π-π Stacking

Zhaocun Shen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Analytical

Highly sensitive chiral sensing by calix[4]arene-modified silver nanoparticles via dynamic light scattering

Yue Sun et al.

SENSORS AND ACTUATORS B-CHEMICAL (2015)

Review Pharmacology & Pharmacy

Health Benefits of Theanine in Green Tea: A Review

Yue-Rong Liang et al.

TROPICAL JOURNAL OF PHARMACEUTICAL RESEARCH (2015)

Review Chemistry, Organic

Rational Strategies for the Selective Functionalization of Calixarenes

Roy Lavendomme et al.

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2015)

Article Chemistry, Physical

Chirality from substitution: enantiomer separation via a modified metal-organic framework

Jingshu Zhao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

Review Chemistry, Multidisciplinary

Dynamic Supramolecular Complexes Constructed by Orthogonal Self-Assembly

Xiao-Yu Hu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

Review Chemistry, Multidisciplinary

Suprannolecular Chemistry of p-Sulfonatocalix[n]arenes and Its Biological Applications

Dong-Sheng Guo et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

Article Chemistry, Multidisciplinary

CdS Quantum Dots Encapsulated in Chiral Nematic Mesoporous Silica: New Iridescent and Luminescent Materials

Thanh-Dinh Nguyen et al.

ADVANCED FUNCTIONAL MATERIALS (2014)

Article Chemistry, Analytical

Chiral metal-organic framework used as stationary phases for capillary electrochromatography

Zhi-Xin Fei et al.

ANALYTICA CHIMICA ACTA (2014)

Article Chemistry, Multidisciplinary

Chiral Metal-Organic Frameworks Bearing Free Carboxylic Acids for Organocatalyst Encapsulation

Yan Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Review Chemistry, Multidisciplinary

Review: A History of Cyclodextrins

Gregorio Crini

CHEMICAL REVIEWS (2014)

Review Chemistry, Medicinal

Synthesis of Single-enantiomer Bioactive Molecules: A Brief Overview

Abdul Rouf et al.

CHIRALITY (2014)

Article Multidisciplinary Sciences

Enantioselective control of lattice and shape chirality in inorganic nanostructures using chiral biomolecules

Assaf Ben-Moshe et al.

NATURE COMMUNICATIONS (2014)

Article Materials Science, Multidisciplinary

Chiral-nematic liquid crystals as one dimensional photonic materials in optical sensors

D. J. Mulder et al.

JOURNAL OF MATERIALS CHEMISTRY C (2014)

Review Chemistry, Multidisciplinary

Energy Component Analysis of π Interactions

C. David Sherrill

ACCOUNTS OF CHEMICAL RESEARCH (2013)

Review Chemistry, Multidisciplinary

Chiral Iron Catalysts for Asymmetric Synthesis

Kovuru Gopalaiah

CHEMICAL REVIEWS (2013)

Review Chemistry, Multidisciplinary

Covalent organic frameworks (COFs): from design to applications

San-Yuan Ding et al.

CHEMICAL SOCIETY REVIEWS (2013)

Article Biochemical Research Methods

ENANTIOSELECTIVE ACYLATION OF β-PHENYLALANINE ACID AND ITS DERIVATIVES CATALYZED BY PENICILLIN G ACYLASE FROM Alcaligenes faecalis

Dengchao Li et al.

PREPARATIVE BIOCHEMISTRY & BIOTECHNOLOGY (2013)

Review Chemistry, Multidisciplinary

Functional DNA Nanostructures for Photonic and Biomedical Applications

Zhen-Gang Wang et al.

SMALL (2013)

Review Chemistry, Multidisciplinary

Chiral biointerface materials

Mingxi Zhang et al.

CHEMICAL SOCIETY REVIEWS (2012)

Review Biochemical Research Methods

Chiral Recognition Mechanisms in Analytical Separation Sciences

Gerhard K. E. Scriba

CHROMATOGRAPHIA (2012)

Article Chemistry, Multidisciplinary

Chiral Ligand?Induced Circular Dichroism in Excitonic Absorption of Colloidal Quantum Dots

Assaf Ben Moshe et al.

ISRAEL JOURNAL OF CHEMISTRY (2012)

Review Biochemical Research Methods

Recent developments on polysaccharide-based chiral stationary phases for liquid-phase separation of enantiomers

Bezhan Chankvetadze

JOURNAL OF CHROMATOGRAPHY A (2012)

Review Biochemical Research Methods

Recent development of cyclodextrin chiral stationary phases and their applications in chromatography

Yin Xiao et al.

JOURNAL OF CHROMATOGRAPHY A (2012)

Article Chemistry, Analytical

Chiral recognition of dapoxetine enantiomers with methylated-gamma-cyclodextrin: A validated capillary electrophoresis method

Gabor Neumajer et al.

JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS (2012)

Article Chemistry, Multidisciplinary

Calixarene-Based Surfactants: Evidence of Structural Reorganization upon Micellization

Nuno Basilio et al.

LANGMUIR (2012)

Review Biochemistry & Molecular Biology

Chiral lipidomics of E-series resolvins: Aspirin and the biosynthesis of novel mediators

Sungwhan F. Oh et al.

BIOCHIMICA ET BIOPHYSICA ACTA-MOLECULAR AND CELL BIOLOGY OF LIPIDS (2011)

Review Chemistry, Multidisciplinary

New sensing mechanisms for design of fluorescent chemosensors emerging in recent years

Jiasheng Wu et al.

CHEMICAL SOCIETY REVIEWS (2011)

Article Chemistry, Medicinal

The Significance of Chirality in Drug Design and Development

W. H. Brooks et al.

CURRENT TOPICS IN MEDICINAL CHEMISTRY (2011)

Article Chemistry, Inorganic & Nuclear

Microwave-Assisted Synthesis of Metal-Organic Frameworks

Jacek Klinowski et al.

DALTON TRANSACTIONS (2011)

Article Biochemical Research Methods

Analysis of chiral amino acids in cerebrospinal fluid samples linked to different stages of Alzheimer disease

Shorena Samakashvili et al.

ELECTROPHORESIS (2011)

Review Biochemistry & Molecular Biology

Inherently Chiral Calixarenes: Synthesis, Optical Resolution, Chiral Recognition and Asymmetric Catalysis

Shao-Yong Li et al.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2011)

Article Chemistry, Physical

Hot Exciton Relaxation Dynamics in Semiconductor Quantum Dots: Radiationless Transitions on the Nanoscale

Patanjali Kambhampati

JOURNAL OF PHYSICAL CHEMISTRY C (2011)

Article Chemistry, Multidisciplinary

Unraveling the Mechanism of Nanotube Formation by Chiral Self-Assembly of Amphiphiles

Lior Ziserman et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Multidisciplinary

Chiral inorganic nanoparticles: origin, optical properties and bioapplications

Yunsheng Xia et al.

NANOSCALE (2011)

Article Chemistry, Multidisciplinary

Asymmetric catalytic reactions by NbO-type chiral metal-organic frameworks

Kyung Seok Jeong et al.

CHEMICAL SCIENCE (2011)

Review Chemistry, Multidisciplinary

Rational Approaches toward the Design and Synthesis of Zeolitic Inorganic Open-Framework Materials

Jihong Yu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2010)

Review Chemistry, Multidisciplinary

Functional Materials: From Hard to Soft Porous Frameworks

Arne Thomas

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Review Chemistry, Multidisciplinary

DNA as a Versatile Chemical Component for Catalysis, Encoding, and Stereocontrol

Scott K. Silverman

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Article Chemistry, Multidisciplinary

Multidimensional nanoarchitectures based on cyclodextrins

Yong Chen et al.

CHEMICAL COMMUNICATIONS (2010)

Review Chemistry, Multidisciplinary

Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications

Youssef Habibi et al.

CHEMICAL REVIEWS (2010)

Article Chemistry, Multidisciplinary

The Conversion of L-Phenylalanine to (S)-2-Hydroxy-3-phenylpropanoic Acid: A Simple, Visual Example of a Stereospecific S(N)2 Reaction

Nanine A. Van Draanen et al.

JOURNAL OF CHEMICAL EDUCATION (2010)

Article Multidisciplinary Sciences

Controlling the growth and shape of chiral supramolecular polymers in water

Pol Besenius et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2010)

Editorial Material Engineering, Chemical

Developing Chiral Surfaces for Enantioselective Chemical Processing

David S. Sholl et al.

AICHE JOURNAL (2009)

Review Chemistry, Physical

Self-assembly of organic molecules at metal surfaces

Angelika Kuehnle

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE (2009)

Article Chemistry, Analytical

Electrochemical Chiral Sensors and Biosensors

Marek Trojanowicz et al.

ELECTROANALYSIS (2009)

Review Pharmacology & Pharmacy

Emerging trends of nanomedicine - an overview

Selvarajan Sandhiya et al.

FUNDAMENTAL & CLINICAL PHARMACOLOGY (2009)

Article Chemistry, Physical

Synthesis and hydrogen-storage behavior of metal-organic framework MOF-5

Jinping Li et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2009)

Article Chemistry, Multidisciplinary

Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal-Organic Porous Materials

Mainak Banerjee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Review Toxicology

Chiral Toxicology: It's the Same Thing...Only Different

Silas W. Smith

TOXICOLOGICAL SCIENCES (2009)

Review Chemistry, Multidisciplinary

Reticular chemistry of metal-organic polyhedra

David J. L. Tranchemontagne et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Review Chemistry, Multidisciplinary

Chiral HPLC for efficient resolution of enantiomers

Yoshio Okamoto et al.

CHEMICAL SOCIETY REVIEWS (2008)

Article Astronomy & Astrophysics

Some properties of the Alday-Maldacena minimum

A. Mironov et al.

PHYSICS LETTERS B (2008)

Review Chemistry, Inorganic & Nuclear

Enantioselective self-assembly of chiral bimetallic oxalate-based networks

Michel Gruselle et al.

COORDINATION CHEMISTRY REVIEWS (2006)

Review Chemistry, Analytical

Impact of immobilized polysaccharide chiral stationary phases on enantiomeric separations

I Ali et al.

JOURNAL OF SEPARATION SCIENCE (2006)

Review Marine & Freshwater Biology

Ecotoxicology of human pharmaceuticals

K Fent et al.

AQUATIC TOXICOLOGY (2006)

Review Chemistry, Applied

Recent progress in chiral Bronsted acid catalysis

Takahiko Akiyama et al.

ADVANCED SYNTHESIS & CATALYSIS (2006)

Article Optics

Polarization-dependent filters based on chiral photonic structures with defects

JY Chen et al.

JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS (2005)

Article Chemistry, Multidisciplinary

Catalytic asymmetric cyanosilylation of ketones by a chiral amino acid salt

XH Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

Article Chemistry, Multidisciplinary

Chiral supramolecular polymers formed by host-guest interactions

M Miyauchi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

Article Chemistry, Multidisciplinary

Magnetic alignment of the chiral nematic phase of a cellulose microfibril suspension

F Kimura et al.

LANGMUIR (2005)

Review Chemistry, Multidisciplinary

Crown ethers: Sensors for ions and molecular scaffolds for materials and biological models

GW Gokel et al.

CHEMICAL REVIEWS (2004)

Article Chemistry, Multidisciplinary

Oligomer-assisted synthesis of chiral polyaniline nanofibers

WG Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)

Review Chemistry, Multidisciplinary

Fluorescence of organic molecules in chiral recognition

L Pu

CHEMICAL REVIEWS (2004)

Article Chemistry, Multidisciplinary

Detection and amplification of chirality by helical polymers

E Yashima et al.

CHEMISTRY-A EUROPEAN JOURNAL (2004)

Article Chemistry, Multidisciplinary

Self-assembly of chiral DNA nanotubes

JC Mitchell et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)

Article Chemistry, Multidisciplinary

Homochirality and life

N Fujii et al.

CHEMICAL RECORD (2004)

Article Multidisciplinary Sciences

Structure-based carbon nanotube sorting by sequence-dependent DNA assembly

M Zheng et al.

SCIENCE (2003)

Review Biochemical Research Methods

Separation of drug enantiomers by liquid chromatography and capillary electrophoresis, using immobilized proteins as chiral selectors

MC Millot

JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES (2003)

Article Chemistry, Physical

DNA interaction with single-walled carbon nanotubes: a SEIRA study

GI Dovbeshko et al.

CHEMICAL PHYSICS LETTERS (2003)

Article Education & Educational Research

Promoting understanding of chemical bonding and spontaneity through student explanation and integration of ideas

MA Teichert et al.

JOURNAL OF RESEARCH IN SCIENCE TEACHING (2002)

Article Chemistry, Multidisciplinary

From local adsorption stresses to chiral surfaces:: (R,R)-tartaric acid on Ni(110)

V Humblot et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)

Article Multidisciplinary Sciences

An enantiomerically pure hydrogen-bonded assembly

LJ Prins et al.

NATURE (2000)

Review Chemistry, Multidisciplinary

Blue-shifting hydrogen bonds

P Hobza et al.

CHEMICAL REVIEWS (2000)

Review Biochemical Research Methods

Enantiomer separation of drugs by capillary electrophoresis using proteins as chiral selectors

J Haginaka

JOURNAL OF CHROMATOGRAPHY A (2000)

Article Chemistry, Organic

A chiral sensor for arginine and lysine

M Wehner et al.

ORGANIC LETTERS (2000)